A kind of high-density polyethylene microporous foam pipe and its preparation method

A technology of high-density polyethylene and microcellular foaming, applied in the field of pipe preparation, can solve the problems of high cost, unfavorable, complicated extrusion process of polyethylene pipes, etc., achieve high melt strength and prevent excessive expansion

Active Publication Date: 2017-05-10
CHONGQING WEIXING NEW BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the process selection of polyethylene microcellular foaming, physical foaming requires special equipment for transporting physical foaming agents, or a very cumbersome process is added, and the cost is high
The chemical microcellular foaming equipment is simple, but the heat absorption and release during the foaming process is not conducive to the stability of extrusion processing, which will cause uneven cell size and unstable performance.
In addition, the extrusion process of polyethylene pipes is complicated and the process control is difficult. At present, there are few research reports on the application of chemical microcellular foaming technology on polyethylene pipes.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A high-density polyethylene microporous foam pipe is composed of the following components in parts by weight: 100 parts of PE100 pipe material, 6 parts of linear low-density polyethylene 6201RQ, 4 parts of sodium bicarbonate, 2 parts of citric acid, 2 parts of zinc oxide 2 parts of calcium sulfate whiskers, 0.1 part of 3-aminopropyltriethoxysilane, 0.5 part of vinyl distearoyl, antioxidant 330 (1,3,5-trimethyl-2,4, 0.5 parts of 6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene), 1 part of antioxidant 168 (tris(2,4-di-tert-butylphenyl)phosphite), this The invented linear low density polyethylene is ExxonMobil powder, its grade is 6201RQ, which is mainly used as a dispersion carrier for powder additives.

[0030] Specific implementation:

[0031] Step 1: Mix 4 parts of sodium bicarbonate and 2 parts of foaming aid zinc oxide in a powder maker for 3 minutes, then add 2 parts of citric acid, stir for 2 minutes, and release the material evenly to obtain a composite foaming a...

Embodiment 2

[0037] A high-density polyethylene microcellular foam pipe is composed of the following components in parts by weight: 100 parts of high-density polyethylene 5000S, 5 parts of linear low-density polyethylene 6201RQ, 4 parts of sodium bicarbonate, and 2 parts of triethyl citrate 2 parts of zinc oxide, 2 parts of calcium sulfate whiskers, 0.1 part of 3-aminopropyltriethoxysilane, 0.5 part of vinyl distearoyl, antioxidant 330 (1,3,5-trimethyl -2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene) 0.5 parts, antioxidant 168 (tris(2,4-di-tert-butylphenyl)phosphite ) 1 part.

[0038] Specific implementation:

[0039] Step 1: Mix 4 parts of sodium bicarbonate and 2 parts of foaming aid zinc oxide in a powder machine for 3 minutes, then add 2 parts of triethyl citrate, stir for 2 minutes, release the material after uniformity, and obtain a composite foam foaming agent;

[0040] Step 2: Mix 5 parts of linear low density polyethylene 6201RQ powder, 2 parts of calcium sulfate whiskers, ...

Embodiment 3

[0044] A high-density polyethylene microporous foam pipe is composed of the following components in parts by weight: 100 parts of high-density polyethylene PE100, 5 parts of linear low-density polyethylene 6201RQ, 4 parts of sodium bicarbonate, and 2 parts of triethyl citrate 2 parts, 2 parts of azodicarbonamide, 2 parts of zinc oxide, 2 parts of calcium sulfate whiskers, 0.1 part of 3-aminopropyltriethoxysilane, 0.5 part of vinyl distearoyl, antioxidant 330 (1 ,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene) 0.5 parts, antioxidant 168 (tris(2,4-di-tert Butylphenyl) phosphite) 1 part.

[0045] Specific implementation:

[0046] Step 1: Mix 4 parts of sodium bicarbonate and 2 parts of foaming aid zinc oxide in a powder machine for 3 minutes, then add 2 parts of triethyl citrate and 2 parts of azodicarbonamide, stir for 2 minutes, and mix well The material is discharged to obtain a composite blowing agent;

[0047] Step 2: Mix 5 parts of linear low density ...

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Abstract

The invention relates to a high-density polyethylene microporous foamed tube and a preparation method thereof, belonging to the technical field of tube preparation. The high-density polyethylene microporous foamed tube is prepared by mixing and extruding the following components in parts by weight: 100 parts of high-density polyethylene, 5-10 parts of linear low-density polyethylene, 1-8 parts of main foaming agent, 0.5-4 parts of auxiliary foaming agent, 0.5-4 parts of foaming assistant, 1-5 parts of nucleating agent, 0.1-0.5 part of coupling agent, 0.2-1 part of dispersing agent and 0.5-2 parts of antioxidant. By addopting the composite foaming system, the heat absorption-release balance is achieved in the extrusion process, the technique is stable, and the obtained microporous foamed tube has favorable mechanical properties and is suitable for low-pressure water supply and rigid load bearing; and the preparation process is highly continuous, stable, safe and pollution-free, and is suitable for industrial large-scale production.

Description

technical field [0001] The invention belongs to the technical field of pipe preparation, and in particular relates to a high-density polyethylene microporous foam pipe and a preparation method thereof. Background technique [0002] The foaming technology of polyethylene has been greatly developed in recent years, and its foamed products have the advantages of light weight, corrosion resistance, heat insulation, and insulation. Low-density polyethylene has good foaming performance, and the expansion ratio can reach 45 times, and it is widely used in heat preservation and packaging materials. Compared with low-density polyethylene, high-density polyethylene has poor foaming performance, but high-density polyethylene foam products have better strength, rigidity, and heat resistance, and can be used to produce some low-pressure water supply and exterior products. Sheath tubing. [0003] However, usually high-density polyethylene foam cells are relatively large, resulting in a ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L23/08C08J9/08C08J9/10B29C47/92B29C48/92
CPCB29C48/92C08J9/08C08J9/103C08J2203/02C08J2203/04C08J2203/18C08J2323/06C08L23/06C08L2203/18C08L2205/02C08L2207/062C08L23/0815C08K13/04C08K7/08C08K5/544C08K5/526
Inventor 胡正华张伟娇冯金茂赵相盈
Owner CHONGQING WEIXING NEW BUILDING MATERIALS
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