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Copper nanometer wire-based copper-copper bonding process

A technology of copper nanowires and copper-copper bonding, applied in semiconductor devices, electrical components, circuits, etc., can solve problems such as damage to devices, high thermal stress and thermal deformation, and achieve protection of devices, lower temperature and pressure, and controllability strong effect

Inactive Publication Date: 2015-05-20
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in order to promote the diffusion of copper atoms and obtain higher bonding strength, it is necessary to provide higher temperature and pressure, which may introduce higher thermal stress and thermal deformation, and even damage the bonded device

Method used

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  • Copper nanometer wire-based copper-copper bonding process
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  • Copper nanometer wire-based copper-copper bonding process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The copper-copper bonding process based on copper nanowires includes the following steps:

[0044] (1) Using magnetron sputtering to sequentially sputter a layer of adhesion layer Ti and seed layer Au on the clean wafer surface, the thicknesses are 20nm and 50nm respectively.

[0045] (2) Spin-coat PR1-4000A positive photoresist with a thickness of 5 μm on the surface of the seed layer, use a pattern mask containing an area-array circular hole, the circular hole area is transparent, the diameter of the circular hole is 5 μm, and the center distance of the circular hole 10 μm, use MA6 contact photolithography machine for photolithography, and use RD6 developer for development, rinse with deionized water and blow dry with nitrogen gun.

[0046] (3) Put the pattern obtained by photolithography into the copper plating solution for electroplating. The copper plating solution is SYSB2210 bump copper plating solution from Xinyang Company. The electroplating current density is ...

Embodiment 2

[0053] The copper-copper bonding process based on copper nanowires includes the following steps:

[0054] (1) Using magnetron sputtering to sequentially sputter a layer of adhesion layer TiW and seed layer Au on the clean wafer surface, the thicknesses are 50nm and 100nm respectively.

[0055] (2) Spin-coat PR1-12000A positive photoresist with a thickness of 20 μm on the surface of the seed layer, use a pattern mask containing an area-array circular hole, the circular hole area is transparent, the diameter of the circular hole is 20 μm, and the center distance of the circular hole 80 μm, use MA6 contact photolithography machine for photolithography, and use RD6 developer for development, rinse with deionized water and blow dry with nitrogen gun.

[0056] (3) Put the pattern obtained by photolithography into the copper plating solution for electroplating. The copper plating solution selects SYSB2210 bump copper plating solution from Xinyang Company, and the electroplating curre...

Embodiment 3

[0063] The copper-copper bonding process based on copper nanowires includes the following steps:

[0064] (1) Using magnetron sputtering to sequentially sputter an adhesion layer Ti and a seed layer Cu on a clean wafer surface, the thicknesses are 100nm and 200nm respectively.

[0065] (2) Spin-coat NR26-25000P negative photoresist with a thickness of 30 μm on the surface of the seed layer, use a pattern mask containing a round hole around the hole, the hole area is opaque, the diameter of the hole is 50 μm, and the center of the hole The distance is 200 μm, and the MA6 contact photolithography machine is used for photolithography, and the RD6 developer is used for development, and then rinsed with deionized water and blown dry with a nitrogen gun.

[0066] (3) Put the pattern obtained by photolithography into the copper plating solution for electroplating. The copper plating solution is SYSB2210 bump copper plating solution from Xinyang Company. The electroplating current den...

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Abstract

The invention discloses a copper nanometer wire-based copper-copper bonding process. An adhesion layer and a seed layer are sequentially precipitated on the surface of a substrate; a layer of photoresist is prepared on the seed layer, and a round hole is formed in the photoresist; copper is electroplated in the round hole to obtain a copper convex point; a Cu(OH)2 nanometer wire is grown on the surface of the copper convex point by a hydrothermal method; the residual photoresist is removed; the Cu(OH)2 nanometer wire is subjected to thermal decomposition to obtain a CuO nanometer wire; the CuO nanometer wire is reduced to obtain a copper nanometer wire; the copper nanometer wire is prepared on two substrates respectively by the steps, and the copper nanometer wires on the two substrates are bonded in a hot pressing way. The copper nanometer wires are prepared by reduction and are directly applied to subsequent bonding, an additional oxide layer removing step is avoided, a compact bonding layer can be obtained at relatively low temperature and pressure, the preparation process is simple, complex equipment is not required, the cost is low, and the bonding process has very high application value.

Description

technical field [0001] The invention belongs to the technical field of micro-nano manufacturing, and more specifically relates to a copper-copper bonding process based on copper nanowires. Background technique [0002] The continuous development of microelectronics has followed Moore's Law for the past few decades. However, with the reduction of the feature size of electronic devices and the improvement of chip integration, the chip feature size has approached the physical limit, and the products produced by traditional two-dimensional integration technology can no longer solve the problems of interconnection delay and power consumption increase. Resulting performance and cost issues. With the continuous improvement of IC chip performance requirements, such as function enhancement, size reduction, energy consumption and cost reduction, etc., microelectronic packaging technology is developing towards high density and high I / O pin count, based on TSV via holes and high-densit...

Claims

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Application Information

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IPC IPC(8): H01L21/60H01L21/603
CPCH01L24/83H01L2224/11
Inventor 廖广兰独莉史铁林谭先华宿磊陈鹏飞沈俊杰汤自荣
Owner HUAZHONG UNIV OF SCI & TECH
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