Low-freezing-point nitric oxide reducing agent and preparation method thereof
A nitrogen oxide and reducing agent technology, applied in chemical instruments and methods, separation methods, mechanical equipment, etc., can solve problems such as increasing production difficulty, environmental air pollution, affecting product quality, etc., to solve the problems of low temperature crystallization and freezing , Improve antifreeze performance, good antifreeze effect
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[0026] The preparation method of the low freezing point nitrogen oxide reducing agent of the present invention comprises the following specific steps:
[0027] (1) Align the raw materials according to the stated components and mass percentages, and fully stir at a temperature of 10-30°C until all the raw materials are completely dissolved into an aqueous solution and mixed evenly. Specifically: since ammonium amides, ammoniums, low-molecular alcohols and dimethyl sulfoxide are all liquids and are easily soluble in water; therefore, in the actual preparation process, the stirring can be stopped after all the urea solids are dissolved.
[0028] (2) Using a filter element with a filtration accuracy of 0.5-5 μm and under a pressure of 0.2-1 MPa, the raw material aqueous solution obtained in step (1) is filtered to obtain a low-freezing point nitrogen oxide reducing agent solution.
Embodiment 1
[0030] Use 325kg of urea components that meet the requirements, 100kg of analytically pure and above-grade dimethyl sulfoxide, 100kg of methanol, and 475kg of pure water. Mix the components evenly, stir until the urea is completely dissolved, and use a filter element with a filtration accuracy of 0.5μm. After filtering under the pressure of 0.2Mpa, it is the composition solution of the present invention.
[0031] After measurement, the freezing point of the mixture solution is -27°C, with a slight ammonia smell, and the appearance is clear and transparent. Metal ions, biurets, aldehydes, phosphates, insolubles, alkalinity and other indicators all meet the requirements. ﹣No crystals are precipitated at a temperature above 25°C, and after sealed storage at room temperature for 6 months, there is no perceptible change in appearance and smell, and the reduction performance meets the requirements.
[0032] The product has been tested under ETC and ESC conditions on a diesel engine...
Embodiment 2
[0034]Use 200kg of urea components that meet the requirements, 50kg of analytically pure and above-grade dimethyl sulfoxide, 200kg of ammonium, amides, and low-molecular alcohols (including: 50kg of ammonium formate, 150kg of formamide), and 550kg of pure water. Mix evenly, stir until the urea is completely dissolved, and use a filter element with a filtration accuracy of 2.5 μm to filter under a pressure of 0.6 Mpa to obtain the composition solution of the present invention.
[0035] After measurement, the freezing point of the mixture solution is -25°C, with a slight ammonia smell, and the appearance is clear and transparent. Metal ions, biurets, aldehydes, phosphates, insolubles, alkalinity and other indicators all meet the requirements. ﹣No crystals are precipitated at a temperature above 25°C, and after sealed storage at room temperature for 6 months, there is no perceptible change in appearance and smell, and the reduction performance meets the requirements.
[0036] Th...
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