Low-freezing-point nitric oxide reducing agent and preparation method thereof

A nitrogen oxide and reducing agent technology, applied in chemical instruments and methods, separation methods, mechanical equipment, etc., can solve problems such as increasing production difficulty, environmental air pollution, affecting product quality, etc., to solve the problems of low temperature crystallization and freezing , Improve antifreeze performance, good antifreeze effect

Inactive Publication Date: 2015-06-03
SICHUAN MEIFENG CHEM IND
View PDF5 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Compared with this patent, the composition of this patent is more complex, which increases the difficulty of production
In addition, most of the alcohol reagents are volatile, and the product is not tightly sealed or placed in the open for a long time, which will not only affect the product quality, but also cause certain pollution to the ambient air

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0026] The preparation method of the low freezing point nitrogen oxide reducing agent of the present invention comprises the following specific steps:

[0027] (1) Align the raw materials according to the stated components and mass percentages, and fully stir at a temperature of 10-30°C until all the raw materials are completely dissolved into an aqueous solution and mixed evenly. Specifically: since ammonium amides, ammoniums, low-molecular alcohols and dimethyl sulfoxide are all liquids and are easily soluble in water; therefore, in the actual preparation process, the stirring can be stopped after all the urea solids are dissolved.

[0028] (2) Using a filter element with a filtration accuracy of 0.5-5 μm and under a pressure of 0.2-1 MPa, the raw material aqueous solution obtained in step (1) is filtered to obtain a low-freezing point nitrogen oxide reducing agent solution.

Embodiment 1

[0030] Use 325kg of urea components that meet the requirements, 100kg of analytically pure and above-grade dimethyl sulfoxide, 100kg of methanol, and 475kg of pure water. Mix the components evenly, stir until the urea is completely dissolved, and use a filter element with a filtration accuracy of 0.5μm. After filtering under the pressure of 0.2Mpa, it is the composition solution of the present invention.

[0031] After measurement, the freezing point of the mixture solution is -27°C, with a slight ammonia smell, and the appearance is clear and transparent. Metal ions, biurets, aldehydes, phosphates, insolubles, alkalinity and other indicators all meet the requirements. ﹣No crystals are precipitated at a temperature above 25°C, and after sealed storage at room temperature for 6 months, there is no perceptible change in appearance and smell, and the reduction performance meets the requirements.

[0032] The product has been tested under ETC and ESC conditions on a diesel engine...

Embodiment 2

[0034]Use 200kg of urea components that meet the requirements, 50kg of analytically pure and above-grade dimethyl sulfoxide, 200kg of ammonium, amides, and low-molecular alcohols (including: 50kg of ammonium formate, 150kg of formamide), and 550kg of pure water. Mix evenly, stir until the urea is completely dissolved, and use a filter element with a filtration accuracy of 2.5 μm to filter under a pressure of 0.6 Mpa to obtain the composition solution of the present invention.

[0035] After measurement, the freezing point of the mixture solution is -25°C, with a slight ammonia smell, and the appearance is clear and transparent. Metal ions, biurets, aldehydes, phosphates, insolubles, alkalinity and other indicators all meet the requirements. ﹣No crystals are precipitated at a temperature above 25°C, and after sealed storage at room temperature for 6 months, there is no perceptible change in appearance and smell, and the reduction performance meets the requirements.

[0036] Th...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention provides a low-freezing-point nitric oxide reducing agent and a preparation method thereof. The low-freezing-point nitric oxide reducing agent consists of, by mass, 20%-32.5% of urea, 5%-10% of dimethyl sulfoxide, 40%-55% of pure water and one or more of 10%-20% of acid amide, amides and low molecular alcohols. The preparation method comprises the following steps of preparing raw materials, performing full mixing at the temperature ranging from 10 DEG C to 30 DEG C till all raw materials are completely dissolved into a water solution and mixed evenly, using a filter element with the filter accuracy ranging from 0.5 mum to 5 mum and filtering the raw material water solution under the pressure of 0.2-1 MPa to obtain a finished product. The anti-freezing agent raw materials have the advantages of being safe and easy to obtain, good in anti-freezing effect, non-toxic, harmless and the like. The freezing point of the reducing agent is greatly reduced, the problems of low-temperature crystallization and icing are solved, the anti-freezing performance of the nitric oxide reducing agent can be remarkably improved, and the freezing point can be lower than subzero 25 DEG C. A test shows that after engine exhaust gas is filled into an SCR aftertreatment system of the low-freezing-point nitric oxide reducing agent to be treated, the exhaust gas emission can be up to the national IV standard.

Description

Technical field [0001] The present invention involves the field of dairy engine at the post -processing of diesel engines. It is specifically a low -free nitrogen oxide reducing agent and its preparation method. Background technique [0002] In recent years, with the frequent emergence of haze weather across my country, the environmental pressure of my country's government has increased.The control of motor vehicle emissions, which has contributed to the haze weather pollution sources, is also accelerating. Following Beijing in March 2008, Beijing, Shenzhen, Guangzhou, Xi'an and other cities have successively implemented motor vehicle countries IV IV.standard.In the past two years, cities that have been implemented in the country's fourth emission standards have increased. It is expected that the state will comprehensively implement the IV emissions standards of motor vehicle countries in 2015. [0003] According to the current production technology of diesel engines, if diesel v...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): F01N3/20B01D53/94
Inventor 赵曙光陶家明万兴智
Owner SICHUAN MEIFENG CHEM IND
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products