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Surface spray fusing anti-corrosion anti-abrasion heat superconducting nano-graphene alloy powder and manufacturing method thereof

A nano-graphite and superconducting technology, applied in pressure inorganic powder coating and other directions, can solve the problems of low heat transfer coefficient, accelerated corrosion rate, low efficiency, etc., and achieve the effects of high bonding strength, extended life and high hardness

Inactive Publication Date: 2015-07-22
南京美瑞耐磨材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the coolers used in coal-fired power plants are all bare tube or finned tube economizers. The disadvantages are: 1) Most of the bare tube or finned tube economizers use welded wound fins or expanded tube fins. It is easy to separate from the tube to create a gap, which will cause a large thermal resistance at the root of the fin and accelerate the corrosion rate, thereby affecting the heat transfer effect
Tubular regenerators have low compactness, poor heat transfer capacity, and low efficiency. They need to consume a large amount of tubes, occupy a large area, and have high production costs. Moreover, on the side of the finned tubes, since the medium is in vertical contact with the heat exchange tubes, It leads to increased flow resistance, easy to accumulate dust (or scale) and easy to corrode with steam flushing, which affects the life of the regenerator
2) The structure of the finned tube heat exchanger is easy to accumulate dust
Since the heat exchanger adopts a tube structure, the flue gas is in vertical contact with the tube, which will inevitably increase the side resistance drop of the flue gas, and the fins and tube walls are prone to dust accumulation.
3) Due to the influence of low-temperature dew point acid corrosion on the heat exchanger, it may cause rapid corrosion of the heat exchange tube and affect the safe operation of the power plant
Spraying ceramic material on the surface of the tube can solve the life problem of the cooler, but the heat transfer coefficient of the ceramic material is extremely low, only about 1W / (m·k), which affects the heat transfer performance of the cooler

Method used

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  • Surface spray fusing anti-corrosion anti-abrasion heat superconducting nano-graphene alloy powder and manufacturing method thereof
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  • Surface spray fusing anti-corrosion anti-abrasion heat superconducting nano-graphene alloy powder and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. Surface spraying, corrosion-resistant, wear-resistant and superconducting thermally conductive nano-graphene alloy powder consists of nano-graphene powder, ultra-fine iron powder, yttrium oxide, cerium oxide powder, neutral zirconia sol, light magnesium oxide powder, nickel 50% chromium alloy powder component composition, wherein the percentage by weight of each component is:

[0026]

[0027]

[0028] 2. The method of manufacturing the superconducting heat-conducting nano-graphene alloy powder of surface spray melting, corrosion resistance and wear resistance: the steps are:

[0029] 1. Mix the above components with nano-graphene powder, superfine iron powder, yttrium oxide, cerium oxide powder, neutral zirconia sol, light magnesium oxide powder, nickel 50% chromium alloy powder, and alcohol with ceramic balls, The speed is 60-120 revolutions per minute, forward rotation for 6 hours, reverse rotation for 6 hours, mixing for a total of 48 hours, keeping the pow...

Embodiment 2

[0032] 1. Surface spraying, corrosion-resistant, wear-resistant and superconducting thermally conductive nano-graphene alloy powder consists of nano-graphene powder, ultra-fine iron powder, yttrium oxide, cerium oxide powder, neutral zirconia sol, light magnesium oxide powder, nickel 50% chromium alloy powder component composition, wherein the percentage by weight of each component is:

[0033]

[0034] 2. The method of manufacturing the superconducting heat-conducting nano-graphene alloy powder of surface spray melting, corrosion resistance and wear resistance: the steps are:

[0035] Same as Example 1

Embodiment 3

[0037] 1. Surface spraying, corrosion-resistant, wear-resistant and superconducting thermally conductive nano-graphene alloy powder consists of nano-graphene powder, ultra-fine iron powder, yttrium oxide, cerium oxide powder, neutral zirconia sol, light magnesium oxide powder, nickel 50% chromium alloy powder component composition, wherein the percentage by weight of each component is:

[0038]

[0039] Two, the manufacture method of superconducting heat-conducting nano-graphene alloy powder of surface spray melting corrosion resistance and wear resistance: its steps are the same as embodiment 1.

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Abstract

The invention provides surface spray fusing anti-corrosion anti-abrasion heat superconducting nano-graphene alloy powder and a manufacturing method thereof. The surface spray fusing anti-corrosion anti-abrasion heat superconducting nano-graphene alloy powder is composed of nano-graphene powder, superfine iron powder, yttrium oxide, cerium oxide powder, neutral zirconium dioxide sol, light magnesium oxide powder and nickel 50% chromium alloy powder. Ceramic balls are placed and mixed for 48 hours, copious cooling is conducted for 48 hours at the temperature of -196 DEG C, the mixture is heated to 200 DEG C lasting for 12 hours and is destressed, the superfine iron powder forms a partial semi-amorphous material, the powder cannot be cracked in the cladding process, meshes are better formed, nano-graphene fully exerts the heat conduction performance, and after the powder is copiously cooled and heated, 10% to 15% of resin is added, 5% to 15% of ethyl alcohol is then added, and stirring is conducted for 13 hours. Compared with 316 stainless steel, the powder is more resistant to corrosion and abrasion, service life is prolonged by more than five times, hardness is higher, rigidity is better, the bonding strength and the hardness of a coating are high, stress is small, no deformation or disengagement exists in the high-temperature cladding process, and the powder is denser after surface cladding.

Description

technical field [0001] The invention relates to core components used in the manufacture of drums, burners, water-cooled wall superheaters, economizers, air preheaters, reheaters, etc. in large-scale coal-fired power plants, and can also be widely used in petrochemical corrosion-resistant and wear-resistant pipes Workpiece production materials, especially a superconducting heat-conducting nano-graphene alloy powder and a manufacturing method thereof. Background technique [0002] At present, the coolers used in coal-fired power plants are all bare tube or finned tube economizers. The disadvantages are: 1) Most of the bare tube or finned tube economizers use welded wound fins or expanded tube fins. It is easy to separate from the tube to create a gap, which will cause a large thermal resistance at the root of the fin and accelerate the corrosion rate, thereby affecting the heat transfer effect. Tubular regenerators have low compactness, poor heat transfer capacity, and low ef...

Claims

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Application Information

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IPC IPC(8): B22F1/00C23C24/04
Inventor 吴俐俊戴亚洲
Owner 南京美瑞耐磨材料科技有限公司
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