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A kind of activated carbon with graded pores and preparation method thereof

A technology of activated carbon and channels, which is applied in the field of activated carbon and its preparation, can solve the problems of strong corrosion and high activation cost of potassium hydroxide, and achieve the effects of high specific capacity, good power characteristics and high specific surface area

Active Publication Date: 2017-05-24
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to improve the added value of heavy carbon sources such as petroleum coke, coal and other raw materials, and solve the problems of high activation cost of potassium hydroxide and strong corrosion in the process of industrial scale-up, the present invention provides a kind of heavy carbon source as raw material, potassium carbonate As a pore-forming agent, a method of preparing activated carbon with hierarchical pores is featured by this method, which is environmentally friendly. At the same time, the carbon electrode material prepared by using the prepared activated carbon has the characteristics of high capacity and good power performance.

Method used

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  • A kind of activated carbon with graded pores and preparation method thereof
  • A kind of activated carbon with graded pores and preparation method thereof
  • A kind of activated carbon with graded pores and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0042] According to the production method of activated carbon for supercapacitors of the present embodiment, using Panjin Zhongyou Liaohe Petroleum Coke as the carbon source, the following steps are successively included:

[0043] (1), petroleum coke is pulverized and sieved, and sieved to obtain 200 mesh petroleum coke powder (PC), and its electron microscope is as follows: figure 1 As shown in .a-c, it is a smooth block with a size of about 100um.

[0044] (2) Petroleum coke powder (PC) was ball milled for 2 hours to obtain PC-2B; in addition, PC and potassium carbonate were mixed at a mass ratio of 1:3, and ball milled for 2 hours to obtain a mixed powder (PC-2B-3), a part of the mixed powder (PC-2B-3) was acid-washed with HCl, washed with water, neutralized, and dried to obtain activated carbon powder (PC-2B-3-W) from which potassium carbonate was removed.

[0045] (3) Another part of the mixed powder (PC-2B-3) was placed in a carbonization furnace at 800°C, and activated f...

Embodiment 2

[0051] According to the production method of activated carbon for supercapacitors of the present embodiment, using Panjin Zhongyou Liaohe Petroleum Coke as the carbon source, the following steps are successively included:

[0052] (1), the petroleum coke is pulverized and sieved, and sieved to obtain a 200-mesh powder.

[0053] (2) Mix petroleum coke powder and potassium carbonate at a mass ratio of 1:0.5, and ball mill for 2 hours to obtain a mixed powder.

[0054] (3) Put the mixed powder in a carbonization furnace at 800°C, and activate it for 2 hours under the protection of an inert gas.

[0055] (4), cooling activator, pickling with 0.2mol / L HCl, washing with water puts neutrality, drying, obtains activated carbon (PC-2B-0.5-800-W) for supercapacitor, and its structural parameters are as shown in table 3:

[0056] Table 3: Structural parameters of activated carbon prepared from petroleum coke

[0057]

[0058] (5) The activated carbon PC-2B-0.5-800-W is made into an ...

Embodiment 3

[0060] According to the production method of activated carbon for supercapacitors of the present embodiment, using Panjin Zhongyou Liaohe Petroleum Coke as the carbon source, the following steps are successively included:

[0061] (1), the petroleum coke is pulverized and sieved, and sieved to obtain a 200-mesh powder.

[0062] (2) Mix petroleum coke powder and potassium carbonate at a mass ratio of 1:6, and ball mill for 2 hours to obtain mixed powder.

[0063] (3) Put the mixed powder in a carbonization furnace at 800°C, and activate it for 2 hours under the protection of an inert gas.

[0064] (4), cooling activator, 0.2mol / L HCl pickling, washing put neutral, dry, obtain supercapacitor active carbon (PC-2B-6-800-W), its structural parameters are as shown in table 4:

[0065] Table 4: Structural parameters of activated carbon prepared from petroleum coke

[0066]

[0067] (5) The activated carbon PC-2B-6-800-W is made into an electrode sheet, and a three-electrode test...

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Abstract

The invention relates to an activated carbon comprising a hierarchical hole channel structure and a production method thereof and belongs to the novel carbon material production field. The production method is based on the activation of the mechanical force auxiliary potassium carbonate on heavy carbon sources such as petroleum coke, coal, or phenolic resin. The production method comprises the specific steps of mixing the screened heavy carbon source powder with the potassium carbonate and obtaining the activated carbon for a super capacitor through the ball-milling, activation, washing and drying process. According to the activated carbon comprising the hierarchical hole channel structure and the production method thereof, the activated carbon is large in specific surface area, is of a hierarchical hole channel structure, and the like; the technical route that the potassium carbonate serves as a pore forming agent to produce the activated carbon is implemented and the problem that raw materials such as the petroleum coke and the coal cannot be activated by the potassium carbonate is solved; compared with potassium hydroxide and other activation methods, the corrosion is low, the adaptability to the raw materials is high, the specific surface area is large, the mesoporous pore capacity is large, the enlargement is easy, and the like; the novel activated carbon can be widely applied to the adsorption, catalysis, electrochemical energy storage and other fields and accordingly the application prospect is wide.

Description

technical field [0001] The invention relates to an activated carbon and a preparation method thereof, in particular to an activated carbon with hierarchical pores and a preparation method thereof. Background technique [0002] With the widespread popularity of portable electronic devices, the increasing importance of electric vehicles, and the depletion of non-renewable fossil energy, especially from the perspective of power, people urgently need a green and high-quality energy storage device. At present, in terms of energy storage, lithium-ion batteries and super capacitors are two relatively advanced energy storage technologies. Due to the advantages of high density, fast charging rate and long cycle life, it is widely used in electric vehicles and mobile electronic devices. However, the core component that restricts the development of supercapacitors is the high price of carbon electrode materials. At this stage, commercial supercapacitor carbon electrode materials—acti...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/348C01B32/324C01B32/33
Inventor 李文翠邢超
Owner DALIAN UNIV OF TECH
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