Fiber-reinforced pure inorganic flame retardant foam composite and preparation method thereof

An inorganic flame-retardant and fiber-reinforced technology, which is applied in ceramic products, other household appliances, applications, etc., can solve the problems that the designability of composite materials cannot be fully utilized, the uniformity of dispersion is not easy to be guaranteed, and the use range of foam boards is limited. , to achieve the effect of strong designability, low cost, and orderly arrangement of fibers

Inactive Publication Date: 2015-09-02
AVIC COMPOSITES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The biggest disadvantage of this method is that it is limited by the viscosity of the components. The amount of fiber added cannot be too large, generally not more than 15% by mass, otherwise the viscosity of the components is too high, and the process operability will deteriorate, resulting in a decline in the final foam quality.
Secondly, the length of the fiber is limited, because the longer the fiber, the less likely it is to disperse evenly during the stirring process, and the easier it is to wrap around the stirring rod, causing difficulty in dispersing, making it difficult to ensure the uniformity of dispersion.
Third, in this method, the chopped fibers are distributed in a disordered state in the system, and the foam boards produced are all the same, which cannot take advantage of the strong designability of composite materials
[0005] The common feature of the above-mentioned patents is that organic polymers are used as adhesives. The presence of organic polymers makes the use temperature of this type of board lower (less than 500 ° C), and the flame retardancy level is lower (the highest can only reach S4 of DIN5110 standard. level, that is, self-extinguishing from the fire), which greatly limits the scope of use of this type of foam board

Method used

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  • Fiber-reinforced pure inorganic flame retardant foam composite and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Adopt 8mm thick glass fiber needle-punched felt as reinforcement phase, cut into 150mm * 200mm rectangle; Take 20g microcapsule foaming agent with starting temperature at 120 ℃, add 200g solid phase mass content to be 40% water glass solution, Mix the two evenly to form a suspension and put the impregnating agent in a rectangular container; place the above-mentioned glass fiber needle felt in the suspension and take it out after fully infiltrating, and use a double-roller extrusion device to drain the excess resin on the fiber felt to obtain the density. The fiber mat-impregnating agent homogeneous body that does not change; hang the glass fiber needle felt-impregnating agent composite vertically in a high-temperature blast drying oven at 140°C for 30 minutes for foaming expansion and dehydration curing, and then dry at 700 ℃ high-temperature furnace treatment for 1 h to obtain a quartz glass fiber reinforced quartz-based foam composite material plate. The thickness of ...

Embodiment 2

[0034]Use 8mm thick basalt fiber needle felt as the reinforcing phase, cut into 200mm×200mm square; weigh 25g of microcapsule foaming agent with an initiation temperature of 140°C, add 250g of aluminum dihydrogen phosphate solution with a solid phase mass content of 40% , mix the two evenly to form a suspension impregnating agent and place it in a rectangular container; put the above-mentioned basalt fiber needle felt in the suspension and fully infiltrate it, then take it out, use twin-roll extrusion equipment to drain the excess resin on the fiber felt, Obtain a fiber mat-impregnating agent homogeneous body with no change in density; hang the basalt fiber needle felt-impregnating agent composite vertically in a high-temperature blast drying oven at 160°C for 30 minutes, perform foaming expansion and dehydration curing, and then Treat it in a high-temperature furnace at 600°C for 1 hour to obtain a basalt fiber-reinforced aluminum phosphate-based foam composite sheet. The thi...

Embodiment 3

[0036] Adopt 5mm thick alumina fiber felt as reinforcement phase, cut into 200mm×200mm rectangle; Weigh 25g microcapsule foaming agent with starting temperature at 120°C, add 250g of silica sol with solid phase mass content of 40%, mix the two Mix evenly to form a suspension impregnating agent and place it in a rectangular container; place the above-mentioned alumina fiber felt in the microcapsule-silica sol suspension and fully infiltrate it, then take it out, and use a double-roller extrusion device to drain the excess resin on the fiber felt. Obtain a fiber mat-impregnating agent homogeneous body with no change in density; hang the aluminum oxide fiber mat-impregnating agent composite vertically in a high-temperature blast drying oven at 140°C for 30 minutes for foaming expansion and dehydration curing, and then After being treated in a high-temperature furnace at 700°C for 1 hour, a quartz glass fiber reinforced quartz-based foam composite material plate is obtained. The t...

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Abstract

The invention belongs to the technical field of composite preparation, and relates to a method for preparing a fiber-reinforced pure inorganic flame retardant foam composite. A glass fiber mat, a basalt fiber mat, an aluminum silicate fiber mat, an alumina fiber mat or a mullite fiber mat is used as a reinforcement, inorganic sol or solution, such as silica sol, alumina sol, water glass or an aluminum dihydrogen phosphate solution is used as an impregnating agent, and a microcapsule foaming method is used to prepare a low-density pure inorganic flame retardant foam composite plate. The method avoids the defects that the fiber content is low, the fiber dispersion is uneven, and the mechanical properties resulting therefrom are poor; the fiber in the composite is uniformly arranged, and the fiber mass content can reach 40-60%; the composite is good in mechanical property and formability; the density of the foam composite can be flexibly adjusted through adjusting the proportion of a microcapsule inflating agent added; the combustion level can reach the DIN5510 S5 grade.

Description

technical field [0001] The invention belongs to the technical field of composite material preparation, and relates to a preparation method of a fiber-reinforced pure inorganic flame-retardant foam composite material. Background technique [0002] Due to the low relative density, high specific strength, high specific stiffness, good energy absorption, heat insulation, excellent damping and vibration reduction and noise reduction performance of foam materials, it is easy to realize lightweight and multi-functional structural materials. In engineering applications, it is often used as a sandwich material to reduce the weight of parts, and it is very suitable for the interior of railways, ships and luxury yachts. However, due to the low mechanical properties of pure foam, fiber reinforcement is often used to improve its mechanical properties in practical applications. [0003] The traditional fiber-reinforced foam composite is to mix a certain proportion of chopped fibers into ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B38/02C04B35/80C04B35/82C04B35/14C04B35/447
Inventor 焦春荣仝建峰纪双英王岭
Owner AVIC COMPOSITES
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