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High-impact-resistant polypropylene composite material for bumpers of automobiles and method for manufacturing polypropylene composite material

A technology for automobile bumpers and high impact resistance, applied in the field of composite materials, can solve the problems of poor material flow properties, poor toughness and impact resistance of polypropylene materials, decreased rigidity and strength, etc., to enhance physical and mechanical properties, improve Impact resistance, the effect of improving compatibility

Inactive Publication Date: 2015-09-09
李子健
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It has the advantages of good comprehensive strength, easy processing and molding, and recyclability, but the toughness and impact resistance of polypropylene materials are poor, so it needs to be modified when used in automobile insurance
The traditional modification method is to toughen polypropylene with elastomers, such as ethylene propylene rubber, POE, SBS, etc. The technology is relatively mature, but the main disadvantage is that the flow properties of the material are not good, and the rigidity and strength also decrease.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A high-impact polypropylene composite material for automobile bumpers, prepared from the following raw materials in parts by weight (kg): polypropylene 90, polyethylene terephthalate-1,4-cyclohexanedimethanol Ester 15, Didodecyl Alcohol Ester 5, Liquid Nitrile Rubber 7, Graphene 3, Zirconium Boride 4, Tribasic Lead Sulfate 2, Zinc Stearate 6, Dipropyl Maleate 6, Thermoplastic Polyurethane elastomer 5, rosin glyceride 4, white wax 4, epoxy soybean oil 9, glass fiber 8, gypsum whisker 10, strong powder 6, zinc molybdate 4, antimony trioxide 7, nano diamond 13.

[0016] A preparation method for a polypropylene composite material for a high impact-resistant automobile bumper, comprising the following steps:

[0017] (1) Weigh polypropylene, polyethylene terephthalate-1,4-cyclohexanedimethanol ester, dodecyl alcohol ester, liquid nitrile rubber, graphene, boron Zirconium, tribasic lead sulfate, zinc stearate, dipropyl maleate, thermoplastic polyurethane elastomer, rosin ...

Embodiment 2

[0021] A high-impact polypropylene composite material for automobile bumpers, prepared from the following raw materials in parts by weight (kg): polypropylene 100, polyethylene terephthalate-1,4-cyclohexanedimethanol Ester 20, double dodecyl alcohol ester 6, liquid nitrile rubber 8, graphene 4, zirconium boride 5, tribasic lead sulfate 2.5, zinc stearate 8, dipropyl maleate 7, thermoplastic Polyurethane elastomer 6.5, rosin glyceride 5, insect white wax 4.5, epoxy soybean oil 10, glass fiber 9, gypsum whisker 12, Qianwei powder 7.5, zinc molybdate 5, antimony trioxide 8, nano-diamond 14.

[0022] The preparation method is the same as in Example 1.

Embodiment 3

[0024] A high-impact polypropylene composite material for automobile bumpers, prepared from the following raw materials in parts by weight (kg): polypropylene 110, polyethylene terephthalate-1,4-cyclohexanedimethanol Ester 25, Didodecyl Alcohol Ester 7, Liquid Nitrile Rubber 9, Graphene 5, Zirconium Boride 6, Tribasic Lead Sulfate 3, Zinc Stearate 10, Dipropyl Maleate 8, Thermoplastic Polyurethane elastomer 8, rosin glyceride 6, insect white wax 5, epoxy soybean oil 11, glass fiber 10, gypsum whisker 14, strong powder 9, zinc molybdate 6, antimony trioxide 9, nano-diamond 15.

[0025] The preparation method is the same as in Example 1.

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PUM

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Abstract

The invention discloses a high-impact-resistant polyethylene composite material for bumpers of automobiles and a method for manufacturing the high-impact-resistant polyethylene composite material. The high-impact-resistant polyethylene composite material comprises, by weight, 90-110 parts of polyethylene, 15-25 parts of polyethylene glycol terephthalate-1, 4-cyclohexanedimethanol terephthalate, 5-7 parts of bi-12-carbon alcohol ester, 7-9 parts of liquid nitrile rubber, 3-5 parts of graphene, 4-6 parts of zirconium boride, 2-3 parts of lead sulfate tribasic, 6-10 parts of zinc stearate, 6-8 parts of dipropyl maleate, 5-8 parts of thermoplastic polyurethane elastomers, 4-6 parts of rosin glycerin ester, 6-9 parts of Chinese insect wax, 9-11 parts of epoxidized soybean oil, 8-10 parts of glass fibers, 10-14 parts of gypsum whiskers, 6-9 parts of stronWiNTC, 4-6 parts of zinc molybdate, 7-9 parts of antimony trioxide and 13-15 parts of nanometer diamond. The high-impact-resistant polyethylene composite material and the method have the advantages that the high-impact-resistant polyethylene composite material manufactured by the aid of the method is excellent in impact-resistant performance and high in tensile strength and impact strength.

Description

technical field [0001] The invention relates to a composite material, in particular to a polypropylene composite material for a high impact-resistant automobile bumper and a preparation method thereof. Background technique [0002] The front and rear ends of the car are equipped with bumpers, which not only have decorative functions, but more importantly, are safety devices that absorb and ease external impact, protect the body and protect the occupants. Many years ago, the front and rear bumpers of automobiles were mainly made of metal materials. They were stamped into U-shaped channel steel with a thickness of more than 3 mm, and the surface was chrome-plated. Large gaps, like an added part, look very unsightly. With the development of the automobile industry and the extensive application of engineering plastics in the automobile industry, automobile bumpers, as an important safety device, are also on the road of innovation. At present, in addition to maintaining the or...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L67/02C08L9/02C08L75/04C08L93/04C08L91/06C08K13/04C08K7/14C08K5/10C08K3/04C08K3/38C08K3/30C08K5/098C08K5/11C08K3/34C08K3/22C08K3/24
CPCC08L23/12C08K2201/014C08L2205/035C08L2207/04C08L67/02C08L9/02C08L75/04C08L93/04C08L91/06C08K13/04C08K7/14C08K5/10C08K3/04C08K3/38C08K2003/3045C08K5/098C08K5/11C08K3/34C08K3/2279C08K3/24
Inventor 李子健任浩楠陈逸涵金林墨
Owner 李子健
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