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Carrier, inferior oil hydrogenation catalyst based on same and preparing method thereof

A technology for hydrogenation catalysts and low-quality oils, which is applied in the direction of catalyst carriers, chemical instruments and methods, metal/metal oxides/metal hydroxide catalysts, etc., and can solve problems such as high cost, inability to convert hydrogenation, and low hydrogenation activity problem, to achieve the effect of improving the conversion rate of inferior oil

Active Publication Date: 2015-10-28
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is that the residual oil hydrogenation catalyst in the prior art has low hydrogenation activity and cannot effectively convert heavy components such as asphaltenes and colloids in the residual oil, and the cost is relatively high , thus proposing a low-quality oil hydrogenation catalyst catalyst with high hydrogenation activity, high conversion rate of low-quality oil and low cost and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] This embodiment provides a low-quality oil hydrogenation catalyst, and the raw materials used to prepare the low-quality oil hydrogenation catalyst include:

[0031] Inferior oil hydrogenation catalyst carrier, 10 parts by weight;

[0032] Active metal Mo, 0.45 parts by weight (as Mo 2 o 3 count);

[0033] Sublimed sulfur, 3.5 parts by weight.

[0034] Wherein, the inferior oil hydrogenation catalyst carrier is prepared by the following method:

[0035] (1) Weighing 30 parts by weight of natural bauxite with a particle size of 10 meshes and roasting at 600° C. for 6 hours in an air atmosphere;

[0036] (2) Immerse the roasted bauxite in 500mL of hydrochloric acid solution with a concentration of 4mol / L, carry out acid treatment at 70°C for 4h, then wash with distilled water until neutral, and dry at 110°C for 5h to obtain the obtained The low-quality oil hydrogenation catalyst carrier mentioned above.

[0037] Further, the inferior oil hydrogenation catalyst is pr...

Embodiment 2

[0041] This embodiment provides a low-quality oil hydrogenation catalyst, and the raw materials used to prepare the low-quality oil hydrogenation catalyst include:

[0042] Inferior oil hydrogenation catalyst carrier, 5 parts by weight;

[0043] Active metal W, 0.4 parts by weight (in WO 3 count);

[0044] Sublimed sulfur, 1.8 parts by weight.

[0045] Wherein, the inferior oil hydrogenation catalyst carrier is prepared by the following method:

[0046] (1) Weighing 40 parts by weight of natural bauxite with a particle size of 20 meshes and roasting at 500° C. for 8 hours in an air atmosphere;

[0047] (2) Immerse the roasted bauxite in 500mL nitric acid solution with a concentration of 4mol / L, carry out acid treatment at 40°C for 8h, then wash with distilled water until neutral, and dry at 90°C for 8h to obtain the obtained The low-quality oil hydrogenation catalyst carrier mentioned above.

[0048] Further, the inferior oil hydrogenation catalyst is prepared by the foll...

Embodiment 3

[0052] This embodiment provides a low-quality oil hydrogenation catalyst, and the raw materials used to prepare the low-quality oil hydrogenation catalyst include:

[0053] Inferior oil hydrogenation catalyst carrier, 20 parts by weight;

[0054] Active metal Co, 1.6 parts by weight (as Co 2 o 3 count);

[0055] Sublimed sulfur, 7.2 parts by weight.

[0056] Wherein, the inferior oil hydrogenation catalyst carrier is prepared by the following method:

[0057] (1) Weighing 50 parts by weight of natural bauxite with a particle size of 40 meshes and roasting at 800° C. for 2 hours in an air atmosphere;

[0058] (2) Immerse the roasted bauxite in 500mL of phosphoric acid solution with a concentration of 6mol / L, carry out acid treatment at 150°C for 2h, then wash with distilled water until neutral, and dry at 150°C for 2h to obtain the obtained The low-quality oil hydrogenation catalyst carrier mentioned above.

[0059] Further, the inferior oil hydrogenation catalyst is prep...

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Abstract

The invention relates to an inferior oil hydrogenation catalyst carrier. According to a preparing method, modified natural bauxite is adopted, namely natural bauxite is roasted at high temperature in the air atmosphere and immersed in acid liquor for acid treatment to obtain the modified natural bauxite, by means of the treatment, aluminum oxide, silicon oxide and ferric oxide contained in the natural bauxite are purified, the crystallization degree is improved to form the catalyst carrier which contains aluminum, silicon and ferric and has certain cracking and hydrogenation performance, the acid activity centers of the treated natural bauxite are distributed again, and the specific area and the pore capacity are substantially increased. According to the bauxite modified and treated through the method, pore channel and pore diameter distribution in the structure are optimized, after the bauxite serves as the inferior oil hydrogenation catalyst carrier, the hydrogenation conversion performance of macromolecules such as asphaltene and colloid in inferior oil can be improved easily, and then the light distillate yield can be increased easily while the hydrogenation activity of the catalyst is improved.

Description

technical field [0001] The invention relates to a carrier, a low-quality oil hydrogenation catalyst based on the carrier and a preparation method thereof, belonging to the technical field of low-quality oil hydrogenation catalysis. Background technique [0002] With the rapid economic development, China has become the world's largest energy consumer. The market demand for petroleum products is increasing day by day, crude oil is becoming heavier and inferior, environmental protection regulations are becoming more stringent, unconventional oil resources are huge, and the efficient processing and full utilization of heavy oil and inferior oil have become the focus of the world's oil refining industry. At present, the processing technologies of low-quality oil mainly include solvent deasphalting, visbreaking, coking, catalytic cracking and hydrogenation, among which the hydrogenation technology of low-quality oil is the only important technical means that can realize the clean ...

Claims

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Application Information

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IPC IPC(8): B01J32/00B01J23/28B01J23/30B01J23/75B01J23/755B01J23/745C10G49/04
Inventor 鲍晓军牛鹏丽江莉龙曹彦宁林科马永德
Owner FUZHOU UNIV
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