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A method for preparing ticn composition gradient hard coating by plasma assisted arc technology

A composition gradient, hard coating technology, applied in coating, ion implantation plating, metal material coating process, etc., can solve the problems of good wear resistance of TiNTiC, and achieve excellent coating adhesion and mechanical properties, The effect of fast arc movement, improving processing efficiency and service life

Active Publication Date: 2018-04-13
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The former has no gradient change in composition, and the overall TiCN coating obtained does not take advantage of the good adhesion strength of TiN and the good wear resistance of TiC; the latter is essentially a mechanical superposition of TiC and TiN layers, rather than a true C solid Solid solution in TiN

Method used

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  • A method for preparing ticn composition gradient hard coating by plasma assisted arc technology
  • A method for preparing ticn composition gradient hard coating by plasma assisted arc technology
  • A method for preparing ticn composition gradient hard coating by plasma assisted arc technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Example 1: Preparation of TiCN composition gradient hard coating on the surface of YG6 cemented carbide

[0036] 1. Substrate surface pretreatment: (1) Grinding and polishing: The substrate is fully coarsely ground and finely ground on 800 mesh and 1500 mesh diamond grinding wheel discs respectively, and the time of coarse and fine grinding is controlled at 15 minutes. And after fine grinding, the sample is ultrasonically cleaned to remove the abrasive debris and oil stains generated during the grinding process. The ultrasonic cleaning time is 10 minutes and dried in an oven. After the sample is ground, it is polished with W2.0 diamond polishing powder. The polishing time is 20 minutes. After polishing, the surface roughness of the sample is about 0.25±0.03μm. (2) Ultrasonic cleaning: The polished substrate was ultrasonically cleaned with acetone alcohol mixed solution for 30 minutes, and then vacuum-dried.

[0037] 2. Ion cleaning and etching of substrate surface. Be...

Embodiment 2

[0045] Example 2: Preparation of TiCN composition gradient hard coating on the surface of M2 high speed steel

[0046] 1. Substrate surface pretreatment: with embodiment 1

[0047] 2. Ion cleaning and etching on the surface of the substrate: the flow rate of Ar gas is 300 sccm, and the other parameters are the same as in Example 1.

[0048] 3. Coating evaporation deposition: the working current of arc target A and B is 125A; 2 The flow rate is 600sccm, through C 2 h 2 The flow rate is 40 sccm; after 20 minutes of evaporation and deposition, it enters the second stage. In the second stage, on the basis of other process parameters remaining unchanged, the C 2 h 2 The flow rate is increased to 100sccm, and at the same time, the N 2 The flow rate was reduced to 500sccm, and the evaporation deposition time of the second stage was 40min. All the other experimental parameters are the same as in Example 1.

[0049] . Tissue characterization: the characterization method is the ...

Embodiment 3

[0053] Example 3: TiCN Gradient Hard Coating Prepared on the Surface of GCr15 Bearing Steel

[0054] 1. Substrate surface pretreatment: with embodiment 1

[0055] 2. Ion cleaning and etching on the substrate surface: same as in Example 1.

[0056] 3. Evaporation deposition: the working current of arc target A and B is 100A; 2 The flow rate is 500sccm, through C 2 h 2 The flow rate is 5 sccm; after 15 minutes of evaporation and deposition, it enters the second stage. In the second stage, on the basis of other process parameters remaining unchanged, the C 2 h 2 The flow rate is increased to 100sccm, and at the same time, the N 2 The flow rate is reduced to 300sccm, and the evaporation deposition time of the second stage is 30min. All the other experimental parameters are the same as in Example 1.

[0057] . Tissue characterization: the characterization method is the same as in Example 1, Figure 4 and Figure 7 They are the surface and cross-sectional SEM spectra of th...

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Abstract

The invention discloses a method for preparing a TiCN composition gradient hard coating by plasma-assisted electric arc technology. In this method, the substrate is ground, polished, ultrasonically cleaned, supplemented by ion cleaning and etching, and then advanced plasma-assisted arc technology (APA-Arc) is used to change the reaction rate under certain negative bias, deposition temperature, and gas pressure conditions. The gas flow deposits a TiCN hard coating with a composition gradient structure on the surface of the substrate. Compared with the TiCN coating prepared by the traditional method, the present invention significantly and effectively improves the hardness of the TiCN coating and the bonding ability of the film base, reduces the surface roughness, improves the wear resistance, and effectively improves the processing of coated tools and mechanical parts. efficiency and service life. Moreover, the coating process is simple and easy to implement, and is more suitable for industrial production.

Description

technical field [0001] The invention relates to the field of preparation of surface hard coatings, in particular to a method for preparing TiCN composition gradient hard coatings by plasma-assisted electric arc technology. Background technique [0002] With the advancement of manufacturing and processing technology, machining continues to develop in the direction of high precision and high speed. The coating puts forward higher requirements in terms of cutting performance, hardness, oxidation resistance and surface finish. Cemented carbide and high-speed steel tools have been widely used in engineering due to their inherent excellent characteristics. In order to further improve the cutting performance and service life of cemented carbide tools, more than 80% of cemented carbide tools in industrially developed countries have been surface-coated. Override processing. Coating technology has become the three key technologies of cutting tools together with tool materials, tool ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C14/06C23C14/32C23C14/02
Inventor 匡同春谭超林蔡盼盼李雪萍邓阳周克崧雷淑梅钟喜春曾德长
Owner SOUTH CHINA UNIV OF TECH