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A kind of recycling method of waste polyester/polyurethane blended fabric

A blended fabric and polyurethane technology, applied in recycling technology, educts, plastic recycling, etc., can solve the problems of non-productive polyester/polyurethane separation, difficult separation of polyester polymerization intermediates, complicated operation process, etc., and the cost is achieved. Low, inhibition of thermal degradation, short process flow effect

Active Publication Date: 2017-12-26
ELITE COLOR ENVIRONMENTAL RESOURCES SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For the recovery of waste polyester / cotton blended fabrics, the invention patent CN 102558779A uses ethylene glycol to alcoholly decompose polyester into soluble polymerization intermediates and separate them from cotton, and then repolymerize to prepare recycled polyester. Although this method can achieve polyester and Separation of cotton, but no separation of polyester / polyurethane, because ethylene glycol will also react with polyurethane at high temperature to produce non-polyester polymerization monomer impurities, and it is not easy to separate from polyester polymerization intermediates
Invention patent CN 1585798A uses amide-based solvents to dissolve polyester components in waste to realize the separation of polyester from other types of high polymers, but this method has complicated operation process, low efficiency and high cost

Method used

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  • A kind of recycling method of waste polyester/polyurethane blended fabric

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] 1) the waste polyester / polyurethane blended fabric (wherein polyester is polyethylene terephthalate, its content is 70% (mass fraction), polyurethane is the content of polyester polyurethane is 30% (mass fraction) ) were crushed, cleaned and vacuum-dried to obtain polyester / polyurethane blended fabric fragments with a water content of 98ppm;

[0030] 2) the polyester / polyurethane blended fabric fragments and the styrene-maleic anhydride copolymer (wherein the maleic anhydride unit content is 10% (molar ratio)) powder (powder diameter is 0.3mm) accounting for 10% of its mass fraction, The antioxidant YIPHOS3010, which accounts for 0.25% of its mass fraction, is fully mixed and uniformly pre-melted and agglomerated in a polyester foam granulator at a temperature of 205°C. The time should be controlled within 2 minutes, and the modified polyester / polyurethane foam will be obtained after this process;

[0031] 3) The modified polyester / polyurethane foam is vacuum-dried to ...

Embodiment 2

[0035] 1) the waste polyester / polyurethane blended fabric (wherein polyester is polyethylene terephthalate, its content is 60% (mass fraction), polyurethane is the content of polyether type polyurethane is 40% (mass fraction) ) were crushed, cleaned and vacuum-dried to obtain polyester / polyurethane blended fabric fragments with a water content of 96 ppm;

[0036] 2) the polyester / polyurethane blended fabric fragments and the styrene-maleic anhydride copolymer (wherein the maleic anhydride unit content is 25% (molar ratio)) powder (the powder diameter is 0.05mm) accounting for its mass fraction of 25%, The antioxidant Irgafos168, which accounts for 0.4% of its mass fraction, is fully mixed and uniformly pre-melted and agglomerated in a polyester foam granulator at a temperature of 180°C. The agglomeration process is assisted by nitrogen protection, and the raw materials stay in the foam machine The time should be controlled within 3 minutes, after which the modified polyester / p...

Embodiment 3

[0041] 1) waste old polyester / polyurethane blended fabric (wherein polyester is polyethylene terephthalate, and its content is 99% (mass fraction), polyurethane is polyester polyurethane, and its content is 1% (mass fraction) )) crushing, cleaning and vacuum drying to obtain polyester / polyurethane blended fabric fragments with a moisture content of 97ppm;

[0042] 2) polyester / polyurethane blended fabric fragments and styrene-maleic anhydride copolymer (wherein the maleic anhydride unit content is 5% (molar ratio)) powder (powder diameter is 0.5 mm) accounting for 5% of its mass fraction, The antioxidant Irgafos168, which accounts for 0.02% of its mass fraction, is fully mixed and uniformly pre-melted and agglomerated in a polyester foam granulator at a temperature of 220°C. The time should be controlled within 1min, after which the modified polyester / polyurethane foam is obtained;

[0043] 3) The modified polyester / polyurethane foam is vacuum-dried to ensure a moisture conte...

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Abstract

The invention relates to a recycling method of waste polyester / polyurethane blended fabric. Polyester / polyurethane blended textile waste is taken as a raw material, a styrene-maleic anhydride copolymer is added to the waste blended fabric, the mixture is subjected to granule pre-melting at 180-220 DEG C, and injection molding is performed after direct melt blending. Serious thermal degradation of the waste polyester / polyurethane blended fabric in a co-melting process is inhibited effectively, and high-quality blended regenerated melt with the modest cross-linked structure and reasonable phase distribution can be obtained, injection molding requirements can be met, and a regenerated plastic product has good dimensional stability, impact resistance and mechanical strength. The whole regeneration process has the significant advantages of simple technology, short flow, low cost and high efficiency.

Description

technical field [0001] The invention belongs to the technical field of regeneration of waste polyester textiles, and relates to a regeneration method of waste polyester / polyurethane blended fabrics, in particular to a method of adding styrene-maleic anhydride copolymer to polyester / polyurethane blended waste. After pre-melting pellets, melt blending injection molding can be directly carried out. Background technique [0002] Polyethylene terephthalate (referred to as polyester, PET) is a thermoplastic semi-crystalline polymer material with excellent wear resistance and dimensional stability. It is widely used in chemical fiber and packaging fields. Its fiber products are commonly known as Polyester is currently the largest synthetic fiber variety, and its output accounts for 70% of the total synthetic fiber output. With the improvement of living standards, the characteristics of pure polyester fabrics can no longer meet people's needs. Therefore, multi-style blended fabrics...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J11/04C08L67/02C08L75/06C08L75/08C08L35/06B29C45/78B29C45/77
CPCY02P20/143Y02W30/62
Inventor 戴泽新王华平王少博王朝生戴梦茜冯小林蒲党锋邹跃青沈琴珍
Owner ELITE COLOR ENVIRONMENTAL RESOURCES SCI & TECH CO LTD