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64results about How to "Inhibition of thermal degradation" patented technology

Bamboo charcoal profiled fiber and preparation method thereof

The invention discloses bamboo charcoal profiled fiber with good product quality and low production cost, and a preparation method thereof. The fiber comprises the following components in percentage by weight: 94-99 percent of melt-spun slices, 1-6 percent of bamboo charcoal fine particles, 0.05-0.5 percent of surfactant and 0.1-1 percent of antioxidant, wherein the melt-spun slices are polyester, polyamide, polypropylene, polyethylene and modified polymers of polyester, polyamide, polypropylene and polyethylene; and the bamboo charcoal fine particles are black bamboo charcoal or white bamboo charcoal with the particle sizes of less than 2 mum. The preparation method comprises the following steps of: (1) preparing the bamboo charcoal fine particles according to a certain proportion, adding the surfactant and the antioxidant into a double-screw machine in a mixed conveying way, and directly putting the dried melt-spun slices into the hybrid double-screw machine; (2) melting and extruding the melt-spun slices in the double-screw machine, uniformly mixing the melt-spun slices with the bamboo charcoal fine particles and an aid, and conveying the mixture into a spinning box for direct spinning, by means of connection of a flange bent pipe; (3) spinning a blend melt with a spinning component from a spinneret plate, cooling, blowing and winding to obtain bamboo charcoal profiled nascent fibers; and (4) performing stretching twice and heat setting according to a continuous yarn or short yarn post-processing procedure. The invention is suitable for the bamboo charcoal profiled fiber and preparation thereof.
Owner:浙江三马锦纶科技股份有限公司

Polycarbonate composition for LDS with good thermal stability

The invention discloses a polycarbonate composition for LDS with good thermal stability. The polycarbonate composition is prepared from the following components in parts by weight: 60-90 parts of polycarbonate, 2-30 parts of an LDS additive, 0.1-5 parts of a heat stabilizer and 0.3-3 parts of an antioxidant, wherein the antioxidant is prepared from a hindered phenolic antioxidant and a phosphite antioxidant, and the heat stabilizer is prepared from a metal compound, layered double-metal hydroxide and an ultraviolet absorbent. According to the polycarbonate composition disclosed by the invention, by virtue of optimization treatment on the content of each component, particularly combination use of the metal compound, the layered double-metal hydroxide and the ultraviolet absorbent and further combination use of the hindered phenolic antioxidant, the phosphite antioxidant and the heat stabilizer, the components take synergistic effect, thermal degradation of the polycarbonate composition for the LDS is greatly inhibited, the mechanical properties and the processability of the polycarbonate composition for the LDS are improved, and meanwhile, the polycarbonate composition for the LDS is capable of resisting precipitation, solvent extraction and salinization without influencing chemical plating in the formation process.
Owner:SHENZHEN HALCYON NEW MATERIALS

Preparation method of organic montmorillonite for polyolefin composite material

The invention relates to a preparation method of organic montmorillonite for a polyolefin composite material, and belongs to the deep processing technical field of the montmorillonite. The preparation method is characterized by comprising the steps of modifying montmorillonite by using short-chain organic cation quaternary ammonium salt; carrying out high-speed stirring reaction with nano silicon dioxide at the same time; and finally, centrifuging, drying and crushing, wherein adding amount of the organic cation quaternary ammonium salt is 0.8-1.2 times exchange capacity of the montmorillonite cations, and the adding amount of the silicon dioxide is 5%-20% the weight of the montmorillonite. According to the preparation method, intercalation of the montmorillonite is firstly carried out by using organic cations to change polarity of the organic montmorillonite and increase compatibility with the polyolefin material; meanwhile, the montmorillonite is compounded with nano silicon dioxide, so that interlayer spacing of the montmorillonite is further expanded, thermal degradation of organic cations can be restrained, color requirements of the composite material are satisfied, and therefore, the preparation method can be effectively used for the organic montmorillonite powder of the polyolefin material.
Owner:浙江三鼎科技有限公司

Polycondensation catalyst for polyester synthesis as well as preparation method and application of polycondensation catalyst

The invention discloses a polycondensation catalyst for polyester synthesis and a preparation method and application thereof. The preparation method comprises the following steps: carrying out homogeneous blending on a Ti<3>C<2>T<x>MXene material and a benzoxazine monomer to obtain a blend, then carrying out heating for curing treatment to obtain a Ti<3>C<2>T<x>MXene/benzoxazine resin composite material, and finally, irradiating the Ti<3>C<2>T<x>MXene/benzoxazine resin composite material with laser to prepare the polycondensation catalyst for polyester synthesis. The prepared polycondensation catalyst for polyester synthesis has high catalytic activity, and polyester with higher molecular weight can be obtained through polycondensation polymerization within shorter time, so the tensile modulus, tensile strength and other mechanical properties of polyester are improved. In addition, side reactions such as raw material diacid decarboxylation and thermal degradation of polyester can be inhibited by shorter polymerization time, so the obtained polyester has better hue. Moreover, LIG in the polyester can increase the crystallization rate of the polyester and enhance the conductivity of the polyester, so a polyester product is endowed with antistatic performance.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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