20 results about "Fluorocarbon Polymers" patented technology

The invention discloses a Pickering IL emulsion microreactor constructed on the basis of temperature-sensitive double-enzyme Janus spheres and application of the Pickering IL emulsion microreactor to enhanced catalysis of conversion of CO2 into formic acid. A Janus emulsion template method is combined with a photocuring technology to synthesize a nano-scale dual-functional temperature-sensitive Janus sphere, one half of the nano-scale dual-functional temperature-sensitive Janus sphere is a hydrophilic hydrocarbon polymer, the other half of the nano-scale dual-functional temperature-sensitive Janus sphere is a hydrophobic fluorocarbon polymer, and rapid inversion of a Pickering emulsion can be realized by utilizing temperature sensitivity. The method comprises the following steps: preparing a Janus particle hydrophilic / hydrophobic hemisphere, selectively immobilizing formate dehydrogenase FDH and carbonic anhydrase CA on the Janus particle hydrophilic / hydrophobic hemisphere to obtain a temperature-sensitive FDH-Janus-CA composite sphere, introducing a fluorine-functionalized ionic liquid to regulate and control the internal microenvironment of a microreactor, and constructing a Pickering IL emulsion microreactor. The CO2 absorption capacity is increased by 47 times compared with that of a pure water system, the formic acid yield reaches 27.5 mM and is higher than the maximum value 22.8 mM of current enzyme electrocatalysis, the storage and catalysis stability is good, and an efficient and sustainable scheme is provided for CO2 recycling.

The invention discloses low-VOC (volatile organic compound) high-adhesion epoxy finish paint and a preparation method thereof, and relates to the technical field of epoxy paint. The low-VOC high-adhesion epoxy finish paint comprises the following raw materials in parts by weight: 50-70 parts of cationic epoxy resin, 3-8 parts of an adhesion promoter, 0-15 parts of a function enhancing component, 2-5 parts of a photoinitiator, 15-25 parts of a pigment filler and 3-8 parts of a solvent, and the function enhancing component is at least one of polysiloxane micropowder and a reactive fluorocarbon polymer. According to the low-VOC high-adhesion epoxy finish paint and the preparation method thereof, the alicyclic epoxy resin suitable for cation UV curing is selected as a basis, and the adhesion promoter is combined, so that the adhesion of a coating to a base material is remarkably improved on the premise of ensuring the low VOC content; by introducing the polysiloxane micropowder with rich active groups on the surface and the reactive fluorocarbon polymer, the weather resistance, hardness, hydrophobicity and stain resistance of the coating are respectively improved.

This application discloses a ZIF-FCP catalyst for contact electrocatalytic removal of water pollutants, its preparation method, and its application. This ZIF-FCP catalyst, when applied to contact electrocatalytic removal of water pollutants, possesses characteristics of interfacial stability, charge separation capability, and high catalytic activity, enabling efficient degradation of organic pollutants in water. Furthermore, the ZIF-FCP catalyst exhibits good structural stability and can be reused multiple times. The preparation method of the ZIF-FCP catalyst includes the following steps: S1, adding a zeolite imidazole ester framework and a fluorocarbon polymer solution to a container; S2, evacuating the container and then returning it to atmospheric pressure, using a vacuum-assisted loading method to load the fluorocarbon polymer onto the surface of the zeolite imidazole ester framework, thereby obtaining the ZIF-FCP catalyst. The ZIF-FCP catalyst has a three-layer composite structure from the inside out: a zeolite imidazole ester framework, an interfacial anchoring layer, and a fluorocarbon polymer electron-withdrawing layer.

The application relates to a MOFs-mediated normal-temperature and normal-pressure dyeing and synergic construction of anti-ultraviolet and self-cleaning polyester / cotton fabric and a preparation method thereof, and belongs to the technical field of fabric materials. The method for the MOFs-mediated normal-temperature and normal-pressure dyeing and synergic construction of anti-ultraviolet and self-cleaning polyester / cotton fabric comprises the following steps: S1, porous MOFs are in-situ grown on an oxidized polyester / cotton fabric to obtain a modified fabric; S2, normal-temperature and normal-pressure dyeing treatment is conducted on the modified fabric to obtain a dyed MOFs modified polyester / cotton fabric; and S3, PVDF is used to conduct coating treatment on the dyed MOFs modified polyester / cotton fabric to obtain an anti-ultraviolet and self-cleaning polyester / cotton fabric. Through the synchronous construction of controllable coordination of metal organic frameworks and micro-nano rough structures of fluorocarbon polymers, efficient and uniform dyeing of acid dyes on polyester / cotton two phases is realized without damaging the fiber strength, and the fabric is endowed with persistent anti-ultraviolet, high hydrophobicity and excellent self-cleaning performance.

The invention discloses a selective permeation protective clothing material and a preparation method and application thereof, and relates to the technical field of protective materials.The preparation method comprises the following steps that a fluorocarbon high polymer material is dissolved in a polar organic solvent, the weight-average molecular weight of the fluorocarbon high polymer material is 15 * 10 < 4 >, polyethylene glycol and a chain extender are added, and a spinning solution precursor is prepared; regulating the temperature of the prepared spinning solution precursor to 160-230 DEG C, and carrying out melt electrostatic spinning to prepare a fluorine-containing fiber membrane; soaking the fluorine-containing fiber membrane into an alcohol solution containing kaolin, adding 10wt% of perfluorovinyl ether and 0.5 wt% of an initiator, and reacting at 80 DEG C for 8 hours; and taking out the soaked membrane material at a low temperature, and soaking the membrane material in 5wt% of N, N-dimethylacrylamide monomer, an initiator and an accelerator to complete solution replacement so as to prepare the selectively permeable membrane material.

According to the invention, there is provided a method of treating a component of a medicament dispensing device wherein the component is an aluminum can having an interior comprising an inner surface that is in contact with a medicament during storage or use of the device, the method comprising the steps of: placing the aluminum can in a chamber; inserting an electrode into the aluminum pot; performing a plasma cleaning step in which a gaseous atmosphere consisting essentially of oxygen and optionally at least one fluorocarbon is introduced into the chamber and a cleaning plasma is generated in the gaseous atmosphere using the electrode in order to clean the aluminum can, the inner surface of the chamber and the electrode; optionally coating the inner surface of the aluminum can with a coating; and depositing a fluorocarbon polymer layer onto the inner surface of the aluminum can by plasma polymerization, or, if present, onto a coating.

The invention discloses a composite function interface layer on the surface of a metal base material and a preparation method and application thereof, the composite function interface layer is of a porous structure and comprises C, F and O elements, and the thickness of the composite function interface layer is 3-100 nm. The preparation method comprises the following steps: coating a liquid fluorocarbon polymer on the surface of a metal substrate, and drying to form a precursor film; and placing the obtained product in a protective atmosphere, heating and preserving heat, and then cooling to room temperature to form an ultrathin porous composite functional interface layer on the surface of the metal substrate in situ. The liquid fluorocarbon polymer is pyrolyzed on the metal substrate, the carbon-based interface layer with the thickness of only nanoscale can be constructed on the surface of the substrate in situ, the interface layer has the porous characteristic, abundant channels are provided for ion transmission, the ion diffusion path is greatly shortened, the ion migration energy barrier is effectively reduced, and the performance of the device is improved. The ion transmission rate and the deposition / stripping dynamic performance of the electrode are remarkably improved, and the utilization rate and the cycle life of the metal electrode are improved.

This application discloses an integrated etching method, comprising: performing integrated etching to form a groove in a metal layer and a first dielectric layer, the first dielectric layer being formed on a second dielectric layer, and a metal line being formed in the second dielectric layer, with the metal line exposed at the bottom of the groove, the metal line and the metal layer containing different materials; performing post-etching to remove the fluorocarbon polymers generated during the integrated etching, the post-etching comprising three etching stages: in the first etching stage, a reactive gas including carbon monoxide and / or carbon dioxide is introduced; in the second etching stage, a reactive gas including hydrogen and an inert gas is introduced; and in the third etching stage, a reactive gas including carbon monoxide and / or carbon dioxide is introduced. By adding an etching stage containing a reactive gas including hydrogen and an inert gas during the post-etching process of integrated etching, this application can reduce the formation of residual metal fluoride compounds, thereby improving the reliability and yield of the device product.

The invention discloses a long-acting protective water-based fluorocarbon paint and a preparation method thereof. The water-based fluorocarbon paint mainly comprises a component A and a component B, the component A mainly comprises the following raw materials in parts by weight: 50-70 parts of a self-emulsifying fluorocarbon emulsion, 3-8 parts of polycarbonate diol, 3-7 parts of a cosolvent, 15-23 parts of a filler, 5-7 parts of functional fluorocarbon resin, 5-15 parts of deionized water, 0.5-4 parts of an auxiliary agent and 0.5-4 parts of a modified fluorocarbon polymer; and the component B comprises the following components in parts by weight: 40-60 parts of an HDI curing agent and 40-60 parts of a solvent. According to the fluorocarbon paint disclosed by the invention, the water-based property, efficient film forming, long-term weather resistance and strong adhesive force of the fluorocarbon paint are realized through the cooperation of the self-emulsifying fluorocarbon dispersoid, the functional fluorocarbon resin and the modified fluorocarbon polymer; a hydrophilic modified HDI tripolymer is used as a curing agent and is combined with a self-emulsifying technology, so that the compatibility of high-fluorine-content resin and a water-based system is realized. Compared with general water-based fluorocarbon paint, the fluorocarbon paint disclosed by the invention realizes stronger ultraviolet resistance, salt mist resistance, acid and alkali resistance and hydrophobicity, and the adhesive force of a paint film is also remarkably improved; the fluorocarbon paint is long in activation period and suitable for batch use.

The invention relates to a reaction plate for high-throughput screening of low-adsorption nuclear drugs as well as a preparation method and application of the reaction plate, and belongs to the technical field of biological medicines. The reaction plate comprises a substrate with a plurality of micropores in the surface and a coating formed on the inner surfaces of the micropores, the inner surfaces of the micropores are connected with the coating through covalent bonds; the coating is a hydrophilic-hydrophobic binary synergistic patterned coating; a hydrophilic area of the coating is a polyethylene glycol silane layer, and a hydrophobic area of the coating is a fluorocarbon polymer layer. According to the reaction plate disclosed by the invention, through special surface chemical treatment, the non-specific adsorption of ultralow-concentration (picomole to nanomole level) nuclear drug molecules (especially peptides, oligonucleotides and small molecule ligands) on the surface of a container can be remarkably reduced; the key technical problems of signal loss, inaccurate detection, non-repetitive results and the like caused by adsorption in the high-throughput screening process are effectively solved. The invention further provides a preparation method of the reaction plate, and the preparation method is stable in process and suitable for large-scale production.

The invention relates to the technical field of textile auxiliary agents, in particular to an efficient waterproof and oilproof auxiliary agent and a preparation method thereof. The additive comprises the following raw materials in parts by mass: 10-20 parts of modified nano silicon dioxide, 30-50 parts of a fluorocarbon polymer, 3-8 parts of a cross-linking agent, 5-15 parts of an emulsifier and 40-60 parts of deionized water. The auxiliary agent prepared by the invention has excellent waterproof and oil-proof performance, good washability, environmental protection and no toxicity, and is suitable for after-finishing treatment of various textiles.

The utility model discloses a fluorocarbon polymer powder decompression drying device, and relates to the technical field of decompression drying. The fluorocarbon polymer powder decompression drying device comprises a drying barrel and a drainage pipe fixedly arranged on the bottom face of the drying barrel in a penetrating mode, a valve is fixedly arranged at the bottom of the drainage pipe in a penetrating mode, and an air supply adjusting valve is fixedly arranged on the top face of the drying barrel in a penetrating mode and extends into the drying barrel. The drying device has the technical effects that a sealing cover, a sealing ring, an extrusion ring, a mounting frame and bolts are arranged in the placing mechanism, so that external humid air is effectively prevented from entering the drying barrel, and a stable environment is provided for drying; and a pressing plate, an extruding plate, a motor, a threaded rod, a threaded sleeve, a limiting rod and other parts of the extruding part can extrude the fluorocarbon polymer powder in the drying process, internal water is extruded out and discharged through a water discharging pipe, and the drying effect and the product quality are improved.

The invention provides a diaphragm roll and a battery, and particularly relates to the technical field of batteries. The diaphragm roll comprises a diaphragm body and an early warning adhesive layer, the diaphragm body is provided with a head end and a tail end which are oppositely arranged in the length direction of the diaphragm body, and the diaphragm roll with the tail end as a roll core is formed by winding the diaphragm body in the length direction; the early warning adhesive layer is arranged on at least one side of the diaphragm body, and a preset length is formed between the early warning adhesive layer and the tail end; wherein the pre-warning adhesive layer comprises a fluorocarbon polymer and a coloring agent, the RGB of the pre-warning adhesive layer is different from the RGB of the diaphragm body, the pre-warning adhesive layer is analyzed through Fourier transform infrared spectroscopy, the infrared spectrum of the pre-warning adhesive layer has a first absorption peak within the wave number range of 1700-1750 cm <-1 >, and the absorbance of the first absorption peak is 0.01-0.04. The diaphragm roll provided by the invention can effectively avoid the problem of battery performance deterioration caused by tape flying and early warning adhesive layer falling due to untimely roll replacement or continuous roll replacement.

The invention relates to MOFs (Metal-organic Frameworks) mediated normal-temperature and normal-pressure dyeing and synergistically constructed anti-ultraviolet and self-cleaning polyester / cotton fabric and a preparation method thereof, and belongs to the technical field of fabrics. The method for MOFs-mediated normal-temperature and normal-pressure dyeing and collaborative construction of the anti-ultraviolet and self-cleaning polyester / cotton fabric comprises the following steps: S1, growing porous MOFs on an oxidized polyester / cotton fabric in situ to obtain a modified fabric; s2, carrying out normal-temperature and normal-pressure dyeing treatment on the modified fabric to obtain a dyed MOFs modified polyester / cotton fabric; and S3, carrying out coating treatment on the dyed MOFs modified polyester / cotton fabric by using PVDF (Polyvinylidene Fluoride) to obtain the anti-ultraviolet and self-cleaning polyester / cotton fabric. Through controllable coordination of the metal organic framework and synchronous construction of a fluorocarbon polymer micro-nano coarse structure, on the premise that the fiber strength is not damaged, efficient and uniform dyeing of the acid dye on the polyester / cotton two phases is achieved, and the fabric is endowed with lasting ultraviolet resistance, high hydrophobicity and excellent self-cleaning performance.

The invention belongs to the technical field of plastic surface treatment, and particularly relates to a preparation method and application of a plastic surface composite coating structure. The preparation method comprises the following steps: S1, carrying out plasma cleaning treatment on a plastic base material; s2, (1) forming a bottom transition layer I on the surface of the plastic base material through first magnetron sputtering treatment; or (2) forming a bottom transition layer II on the surface of the plastic base material after the organosilane slurry is coated and cured; s3, forming a metal color layer on the bottom transition layer through second magnetron sputtering treatment; s4, forming monatomic silicon on the metal color layer through third magnetron sputtering treatment, forming SiNx or SiO2 through the action of nitrogen plasma or oxygen plasma, and forming a transparent protective layer on the metal color layer; and S5, a fluorocarbon polymer is formed on the transparent protection layer through fourth magnetron sputtering treatment, plasma containing fluorine ions is introduced in the magnetron sputtering process, and an anti-fingerprint layer is formed on the transparent protection layer.

The application discloses a forming method of a semiconductor device, which comprises the following steps: providing a substrate, a surface of the substrate comprises an oxidation layer and a non-oxidation layer arranged around the oxidation layer; bombarding: bombarding the surface of the oxidation layer by using a bombarding ion to form Si-O dangling bonds on the surface; depositing: inputting an etching gas, the etching gas forms a bonding layer on the surface of the oxidation layer and the Si-O dangling bonds, and forms a fluorocarbon polymer layer on the surface of the non-oxidation layer; and cleaning: inputting a bombarding gas, and using the energy provided by the bombarding gas to make the Si-O dangling bonds in the bonding layer react with the precursor of the etching gas to form a volatile gas. The method provided by the application improves the etching selectivity ratio of silicon oxide to silicon nitride and polysilicon, the formed fluorocarbon polymer layer can protect the silicon nitride and the polysilicon from being damaged by ion bombardment, meanwhile, the precise control of the etching morphology is realized, and the method is suitable for etching the silicon oxide at different positions of a 3D NAND memory.

A cathode configured for use in a fuel cell system is provided. The cathode includes a cathode substrate. The cathode also includes a coating disposed on the cathode substrate and including a fluorocarbon polymer additive configured for sintering at a temperature below 200 °C. The fluorocarbon polymer additive can be mixed with a catalyst ink coating or can be applied separately as a topcoat.

The invention provides a diaphragm roll and a battery, and particularly relates to the technical field of batteries. The diaphragm roll comprises a diaphragm body and an early warning adhesive layer, the diaphragm body is provided with a head end and a tail end which are oppositely arranged in the length direction of the diaphragm body, and the diaphragm roll with the tail end as a roll core is formed by winding the diaphragm body in the length direction; the early warning adhesive layer is arranged on at least one side of the diaphragm body, and a preset length is formed between the early warning adhesive layer and the tail end; wherein the early warning adhesive layer comprises an alkene nitrile-carbonyl multipolymer, a fluorocarbon polymer, a carbonyl polymer and a coloring agent. The early warning adhesive layer can be identified by the color sensor and can directly enter the battery without influencing the performance of the battery, and the production efficiency of the battery can be effectively improved through the early warning adhesive layer.

The invention relates to the technical field of semiconductor mask plate cleaning, in particular to a mask plate cleaning method and a mask plate cleaning device.The cleaning method comprises the following steps that S1, a mask plate to be cleaned is placed in a sulfite solution, and the pH of the sulfite solution is 10-14; and S2, under the condition that the sulfite solution is activated through ultraviolet irradiation, the mask plate to be cleaned is cleaned through ultrasonic waves, and the cleaned mask plate is obtained. According to the method, ultraviolet irradiation activation is combined with a sulfite reducing agent, hydration electrons are generated through photolysis in an alkaline environment, the hydration electrons can attack and break C-F bonds with high bond energy, defluorination and degradation of the fluorocarbon polymer are achieved, meanwhile, oxidation of a chromium layer can be inhibited in a reducing environment, and the service life of the fluorocarbon polymer is prolonged. Compared with an existing cleaning method, the cleaning method has the advantages that the cleaning efficiency is improved, so that the cleaning frequency of the mask plate is reduced, and the service life of the mask plate is further prolonged.

The invention discloses a stripping treatment method and a stripping treatment system for a tobacco thick paste method sheet, which comprises the following steps: modifying the surface of a steel belt, depositing a film coating on the surface of the steel belt, the film coating comprises a fluorocarbon polymer coating or a DLC coating, the thickness of the film coating is 50-100nm, the surface contact angle of the steel belt is more than or equal to 120 degrees, and obtaining the modified steel belt, the surface energy of the modified steel belt is reduced to 20 mN / m or below; the tobacco thick slurry method sheet is solidified on the modified steel belt, the interface adhesive force of the tobacco thick slurry method sheet and the modified steel belt is 0.1-0.3 N / cm, the micro airflow array generation module generates airflow forming an included angle of 10-15 degrees with the moving direction of the modified steel belt, and the flow of the airflow is 0.5-1 m / s so that the tobacco thick slurry method sheet and the modified steel belt can be stripped. According to the device, non-contact stripping of the tobacco thick paste method sheet and the steel belt is achieved through the composite airflow field, and the problems that stripped materials are coarse, scraped and the like are completely eradicated.