Preparation method of flexible porous carbon fiber

A technology of porous carbon fiber and carbon fiber, which is applied to the chemical characteristics of fibers, textiles and papermaking, etc., can solve the problems of high cost, low specific surface area, and low output, and achieve the effect of good flexibility, high specific surface area, and high degree of graphitization

Inactive Publication Date: 2016-04-06
CHINA UNIV OF PETROLEUM (EAST CHINA)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current porous carbon fibers are mainly prepared by three cumbersome methods. One is to prepare polymer nano or micron wires by electrospinning and other technologies, and then process them at high temperatures to obtain porous carbon fibers. This method takes a long time and has a high yield. Very low, and electrospinning technology requires high voltage
The second is to prepare or purchase carbon nanotubes, graphene, etc., and use dry drawing, wet spinning and other methods to weave porous carbon fibers. This method can prepare porous carbon fibers with a relatively large area, but the required carbon The preparation process of nanotubes, graphene and other materials is complex and costly, and requires professional spin

Method used

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  • Preparation method of flexible porous carbon fiber
  • Preparation method of flexible porous carbon fiber
  • Preparation method of flexible porous carbon fiber

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0040] Example 1:

[0041] A method for preparing flexible porous carbon fiber includes the following steps:

[0042] 1) Wash and dry the cotton thread with a diameter of 20 microns;

[0043] 2) The cotton thread treated in step 1) is heat-treated at 1000 degrees Celsius for 20 minutes in a hydrogen atmosphere with a flow rate of 50 milliliters per minute to obtain flexible porous carbon fibers.

[0044] figure 1 It is a digital photo of the flexible porous carbon fiber prepared in this example. by figure 1 It can be seen that porous carbon fiber is very flexible and can be bent and woven into various shapes at will.

[0045] figure 2 It is a transmission electron microscope (TEM) photograph of the flexible porous carbon fiber prepared in this example. by figure 2 a It can be seen that carbon fiber is a loose structure, which is formed by a large number of layered structures. in figure 2 In the high-resolution electron micrograph of b, many mesoporous hollow structures caused by c...

Example Embodiment

[0047] Example 2:

[0048] A method for preparing flexible porous carbon fiber includes the following steps:

[0049] 1) Wash and dry the twine with a diameter of 500 microns;

[0050] 2) Heat treatment of the twine treated in step 1) in an ammonia atmosphere with a flow rate of 20 milliliters per minute at 1000 degrees Celsius for 60 minutes to obtain flexible porous carbon fibers.

Example Embodiment

[0051] Example 3:

[0052] A method for preparing flexible porous carbon fiber includes the following steps:

[0053] 1) Wash and dry the paper thread with a diameter of 1000 microns;

[0054] 2) The paper thread treated in step 1) is heat-treated at 1000 degrees Celsius for 20 minutes in a steam atmosphere with a flow rate of 30 milliliters per minute to obtain flexible porous carbon fibers.

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Abstract

The invention relates to a preparation method of a flexible porous carbon fiber. The method comprises the following steps that plant cellulose lines with the diameter of 0.1-2000 micrometers are thoroughly cleaned and dried; 2, the plant cellulose lines processed in the step 1 are subjected to heat treatment at 700-1500 DEG C for 1-300 min in the reducing atmosphere, and therefore the flexible porous carbon fiber is obtained. No catalyst or solvent needs to be used, the method is easy to implement and suitable for large-scale continuous production, and the obtained flexible porous carbon fiber has the good flexibility and can be bent by 360 degrees; the internal structure of the flexible porous carbon fiber has the quite high degree of graphitization, a large number of crystal lattice fringes can be seen under high resolution, and the specific surface area is quite high and can reach up to 1362 m<2>/g.

Description

technical field [0001] The invention relates to a method for preparing flexible porous carbon fibers, which belongs to the technical field of inorganic nanometer material preparation. Background technique [0002] Supercapacitors, especially electric double layer supercapacitors based on carbon materials, have ultra-high energy density compared with other capacitors, one to two orders of magnitude higher power density than traditional batteries, and can reach tens of thousands of cycles. It is considered to be an energy storage device that can partially replace or even completely replace traditional batteries in the future, and has broad application prospects in various electronic devices, recyclable energy storage systems, and new energy vehicles. The common supercapacitors are mainly planar structures, which are composed of two layers of metal substrates as current collectors, two layers of thin film electrode materials, one layer of separator and electrolyte. They are us...

Claims

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Application Information

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IPC IPC(8): D01F9/16
CPCD01F9/16
Inventor 代鹏程赵学波李良军顾鑫王颖闫理停
Owner CHINA UNIV OF PETROLEUM (EAST CHINA)
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