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Temperature-resistant foam-stabilizing type low interfacial tension foaming agent and preparation method thereof

A technology of interfacial tension and foaming agent, which is applied in chemical instruments and methods, drilling compositions, etc., can solve the problem of reducing oil-water interfacial tension, not being able to withstand high temperature at the same time, and not being able to effectively plug low-permeability layers in high-permeability layers. problems such as layer sweep coefficient, to achieve the effect of reducing oil-water interfacial tension, low cost, and good foam stability

Active Publication Date: 2016-05-04
YANGTZE UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] In summary, none of the existing foaming agents for oil displacement can simultaneously have high temperature resistance (≥80°C), high foam stability (>20min), and effective reduction of oil-water interfacial tension to low interfacial tension (10 -2 The advantages of the category of mN / m order
Therefore, the existing technology still cannot meet the requirements of effectively plugging high-permeability layers, improving the sweep coefficient of medium and low-permeability layers, and greatly reducing the interfacial tension of oil and water during foam flooding at high temperatures.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The invention provides a temperature-resistant and foam-stabilizing foaming agent with low interfacial tension. The raw material components and weight are as follows: fatty acid polyoxyethylene ether sodium sulfate 0.57g, coconut oil fatty acid diethanolamide 0.29g, erucamide propyl sugar beet Alkali 0.14g, mineralized water 249g.

[0022] The present invention also provides a kind of preparation method of above-mentioned foaming agent, comprises the following steps:

[0023] 1) Add 3.71g of sodium chloride, 1.16g of sodium sulfate, 5.0g of sodium bicarbonate, 0.08g of anhydrous calcium chloride, and 0.13g of magnesium chloride hexahydrate into distilled water, stir until completely dissolved, and set the volume to 2L to obtain ore Mineralized water of 5040mg / L.

[0024] 2) At room temperature, sequentially weigh 0.57g of fatty acid polyoxyethylene ether sodium sulfate, 0.29g of coconut oil fatty acid diethanolamide, and 0.14g of erucamide propyl betaine, add mineraliz...

Embodiment 2

[0027] The invention provides a temperature-resistant and foam-stabilizing foaming agent with low interfacial tension. The raw material components and weight are as follows: fatty acid polyoxyethylene ether sodium sulfate 0.54g, polyoxyethylene ether 0.31g, oleic acid amidopropyl betaine 0.15g g, mineralized water 249g.

[0028] The present invention also provides a kind of preparation method of above-mentioned foaming agent, comprises the following steps:

[0029]1) Add 3.71g of sodium chloride, 1.16g of sodium sulfate, 5.0g of sodium bicarbonate, 0.08g of anhydrous calcium chloride, and 0.13g of magnesium chloride hexahydrate into distilled water, stir until completely dissolved, and set the volume to 2L to obtain ore Mineralized water of 5040mg / L.

[0030] 2) At room temperature, sequentially weigh 0.54g of fatty acid polyoxyethylene ether sodium sulfate, 0.31g of polyoxyethylene ether, and 0.15g of oleic acid amidopropyl betaine, add mineralized water to quantify to 250g,...

Embodiment 3

[0033] The invention provides a temperature-resistant and foam-stabilizing foaming agent with low interfacial tension. The raw material components and weight are as follows: fatty alcohol polyoxyethylene ether sulfosuccinic acid monoester disodium salt 0.62g, coconut oil fatty acid diethanolamide 0.25g g, erucamidopropyl betaine 0.13g, mineralized water 249g.

[0034] The present invention also provides a kind of preparation method of above-mentioned foaming agent, comprises the following steps:

[0035] 1) Add 3.71g of sodium chloride, 1.16g of sodium sulfate, 5.0g of sodium bicarbonate, 0.08g of anhydrous calcium chloride, and 0.13g of magnesium chloride hexahydrate into distilled water, stir until completely dissolved, and set the volume to 2L to obtain ore Mineralized water of 5040mg / L.

[0036] 2) At room temperature, weigh 0.62 g of fatty alcohol polyoxyethylene ether sulfosuccinic acid monoester disodium salt, 0.25 g of coconut oil fatty acid diethanolamide, and 0.13 g...

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Abstract

The invention discloses a temperature-resistant foam-stabilizing type low interfacial tension foaming agent and a preparation method thereof. The temperature-resistant foam-stabilizing type low interfacial tension foaming agent comprises the following raw material components by mass percent: 0.18-0.25% of an anionic surfactant, 0.05-0.1% of an amphoteric surfactant, 0.08-0.15% of a nonionic surfactant and 99.2-99.69% of mineralized water, wherein the anionic surfactant is one of fatty acid polyoxyethylene ether sodium sulfate and disodium laureth sulfosuccinate; the amphoteric surfactant is one of erucamidopropyl sultaine and cocoamidopropyl betaine; the nonionic surfactant is one of coconutt diethanol amide and polyoxyethylene ether; the mineralized water is a mixed water solution of sodium chloride, sodium sulfate, sodium hydrogen carbonate, anhydrous calcium chloride and magnesium chloride hexahydrate. The temperature-resistant foam-stabilizing type low interfacial tension foaming agent, disclosed by the invention, has the advantages of high temperature resistance, good foam stability, low interfacial tension and the like.

Description

technical field [0001] The invention relates to the technical field of tertiary oil recovery, in particular to a temperature-resistant and foam-stabilizing foaming agent with low interfacial tension and a preparation method thereof. Background technique [0002] As the oilfield development enters the middle and late stages, the total recovery rate of primary oil recovery and secondary oil recovery is only about 40%, so most of the crude oil remains in the formation, and tertiary oil recovery technology is required to effectively improve the oil recovery rate of the reservoir. [0003] Polymer flooding, as the main measure of tertiary oil recovery, has been popularized and applied in my country and has been implemented. The main purpose of polymer flooding is to increase the viscosity of the injected water liquid phase, reduce the oil-water mobility ratio, increase the swept volume of the injected water or fluid, start the crude oil in the medium and low permeability reservoi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/584
CPCC09K8/584
Inventor 唐善法薛汶举姚逸风周天元赵成洋刘璇崔炎琦杨曦吴浩
Owner YANGTZE UNIVERSITY
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