Sulfonated poly-n-phenylglycine photothermal material and its preparation method and application
A technology of phenylglycine and sulfonated polymers, which can be used in wave energy or particle radiation treatment materials, pharmaceutical formulations, medical preparations containing active ingredients, etc., can solve the problem of single functionalization, achieve simple preparation methods, and improve water solubility. Sexuality, the effect of enhancing the lethality rate
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation Embodiment 1
[0031] (1) Preparation of poly-N-phenylglycine: monomer N-phenylglycine (1.06 g, 7 mmol) and oxidant ammonium persulfate (1.60 g, 7 mmol) were dissolved in 0.1M H 2 SO 4 In an ice bath, keep the temperature at 0-5°C, add the oxidant ammonium persulfate solution dropwise to the monomer solution, and the dropwise addition time is 2h. After the dropwise addition, the reaction was continued in an ice bath for 5 h, raised to room temperature for 24 h, and the reaction was stopped. Filter and wash three times with distilled water. After vacuum drying at 50°C for 48 hours, a dark green solid was obtained, namely poly-N-phenylglycine.
[0032] (2) Preparation of sulfonated poly-N-phenylglycine: Add poly-N-phenylglycine (0.5 g, 0.3 mmol) into (15 mL, 0.189 mol) 1,2-dichloroethane, ultrasonically disperse and mechanically Stir, ultrasonic time is 1 h, frequency is 40KHz; then heated to 80°C to obtain a dispersion system; dilute (0.078 g, 0.7 mmol) chlorosulfonic acid with (1 mL, 0.01...
preparation Embodiment 2
[0034](1) Preparation of poly-N-phenylglycine: The monomer N-phenylglycine (1.06 g, 7 mmol) and the oxidant ammonium persulfate (1.60 g, 7 mmol) were dissolved in 1 M HCl respectively, and ice-bathed , keep the temperature at 0-5°C, add the oxidant ammonium persulfate solution dropwise to the monomer solution, and the dropwise addition time is 2h. After the dropwise addition was completed, the reaction was continued in an ice bath for 10 h, raised to room temperature for 12 h, and the reaction was stopped. Filter and wash three times with distilled water. After vacuum drying at 40°C for 96 hours, a dark green solid was obtained, namely poly-N-phenylglycine.
[0035] (2) Preparation of sulfonated poly-N-phenylglycine: Add poly-N-phenylglycine (0.5 g, 0.3 mmol) into (18 mL, 0.227 mol) 1,2-dichloroethane, ultrasonically disperse and mechanically Stir, ultrasonic time is 2 h, frequency is 30KHz; then heated to 80°C to obtain a dispersion system; dilute (0.052 g, 0.45 mmol) chlor...
preparation Embodiment 3
[0037] (1) Preparation of poly-N-phenylglycine: The monomer N-phenylglycine (1.06 g, 7 mmol) and the oxidant ammonium persulfate (1.60 g, 7 mmol) were dissolved in 1 M HCl respectively, and ice-bathed , keep the temperature at 0-5°C, add the oxidant ammonium persulfate solution dropwise to the monomer solution, and the dropwise addition time is 2h. After the dropwise addition was completed, the reaction was continued in an ice bath for 3 hours, then raised to room temperature for 30 hours, and then the reaction was stopped. Filter and wash three times with distilled water. After vacuum drying at 60°C for 48 hours, a dark green solid was obtained, namely poly-N-phenylglycine.
[0038] (2) Preparation of sulfonated poly-N-phenylglycine: Add poly-N-phenylglycine (0.5 g, 0.3 mmol) into (13 mL, 0.164 mol) 1,2-dichloroethane, ultrasonically disperse and mechanically Stir, ultrasonic time is 0.5h, frequency is 50KHz; then heated to 80°C to obtain a dispersion system; dilute (0.087g...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More