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Admixture for improving marine concrete impervious and anti-cracking performance

A technology of marine concrete and crack resistance, applied in the field of building materials, can solve problems affecting the durability of concrete, degradation of cohesiveness, and aggravation of concrete, so as to improve impermeability and work performance, improve work performance, and improve mechanical properties performance effect

Active Publication Date: 2016-06-15
HAINAN RUIZE NEW BUILDING MATERIAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, some waterproof admixtures containing chloride ions are likely to aggravate the corrosion of steel bars and metal embedded parts inside the concrete; waterproofing agents containing expansion components, if the early maintenance conditions of the concrete are not good, and the early expansion value of the expansion agent is too large, it is easy to cause late concrete corrosion. Cracking affects the anti-corrosion effect; admixtures containing fatty acids can form a hydrophobic layer inside the concrete, and there are hydrophobic substances in the capillary pores of the concrete, but in the case of long-term aggressive solution erosion, the effective components The bond between the concrete matrix and the degradation is easy to be leached by the erosive solution, which affects the durability of concrete

Method used

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  • Admixture for improving marine concrete impervious and anti-cracking performance
  • Admixture for improving marine concrete impervious and anti-cracking performance
  • Admixture for improving marine concrete impervious and anti-cracking performance

Examples

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Embodiment 1

[0044] An admixture for improving the anti-seepage and anti-crack performance of marine concrete. The mass percentage of each raw material is: ammonium stearate emulsion 60%, 3,4,9,10-perylenetetracarboxylic anhydride 3%, nano-dioxide Silicone dispersion 4% (mass concentration 20%), ultra-dispersed shrinkage reducing water reducer 10%, micron modified absorbent cotton cellulose 4%, water 19%.

[0045] In the present embodiment, the preparation method of the ammonium stearate emulsion comprises the following steps: 1) heating water to 60° C., dissolving anhydrous sodium carbonate and potassium hydroxide in water, and maintaining a constant temperature to obtain a mixed solution I; 2) Put stearic acid in a three-necked flask, heat and melt at 58°C, and keep the temperature at a constant temperature after raising the temperature to 65°C to obtain a stearic acid solution; 3) Dissolve the emulsifier fatty acid methyl ester ethoxylate evenly in the mixing solution I, then slowly add...

Embodiment 2

[0059] An admixture for improving the anti-seepage and anti-crack performance of marine concrete. The mass percentage of each raw material is: ammonium stearate emulsion 65%, 3,4,9,10-perylenetetracarboxylic anhydride 3%, nano-dioxide Silicone dispersion 3% (mass concentration 30%), ultra-dispersed shrinkage reducing water reducer 9%, micron modified absorbent cotton cellulose 4%, water 16%.

[0060] In the present embodiment, the preparation method of the ammonium stearate emulsion is roughly the same as that in Example 1, except that the volume percentages of the raw materials in the ammonium stearate emulsion are: water 91%, stearic acid 4% , ammonia 3.5%, anhydrous sodium carbonate 0.2%, potassium hydroxide 0.8%, emulsifier 0.5%.

[0061] The difference between the preparation method of the ultra-dispersed shrinkage-reducing water-reducer and Example 1 is: ultra-disperse slump-preserving polycarboxylate water-reducer A55%, shrinkage-reducing polycarboxylate water-reducer B...

Embodiment 3

[0069] An admixture for improving the anti-seepage and anti-crack performance of marine concrete. The mass percentage of each raw material is: ammonium stearate emulsion 55%, 3,4,9,10-perylenetetracarboxylic anhydride 5%, nanometer dioxide 4% silicon dispersion (mass concentration 20%), 10% ultra-dispersed shrinkage reducing water reducer, 4% micron modified absorbent cotton cellulose, 22% water.

[0070] In the present embodiment, the preparation method of the ammonium stearate emulsion is roughly the same as that in Example 1, the difference being that the volume percentages of the raw materials in the ammonium stearate emulsion are: water 89%, stearic acid 5% , ammonia water 4%, anhydrous sodium carbonate 0.3%, potassium hydroxide 1%, emulsifier 0.7%.

[0071] The difference between the preparation method of the ultra-dispersed shrinkage-reducing water-reducer and Example 1 is: ultra-disperse slump-retaining polycarboxylate water-reducer A50%, shrinkage-reducing polycarboxy...

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Abstract

The invention discloses an admixture for improving marine concrete impervious and anti-cracking performance. The admixture is prepared from an ammonium stearate emulsion, 3, 4, 9, 10-perylenetetracarboxylic acid anhydride (PAT), a nano-silica dispersion solution, an ultra-dispersed shrinkage-reducing type water reducer, micron-sized modified absorbent cotton cellulose and water in proportion. According to the invention, the ammonium stearate emulsion is employed to form a thin complex adsorptive layer of insoluble calcium soap in marine concrete capillary pores to block concrete capillary pores. And a PAT optimized pore structure is utilized to improve the impervious performance and work performance of marine concrete. The nano-silica dispersion solution is employed to enhance the mechanical properties of marine concrete. The ultra-dispersed shrinkage-reducing type water reducer is utilized to reduce concrete shrinkage and improve the work performance. The micron-sized modified absorbent cotton cellulose is utilized to enhance the anti-cracking performance of marine concrete. The admixture provided by the invention does not contain nitrite, chromate and the like, is chlorine-free and environment-friendly, and can greatly enhance the durability of concrete serving in a marine environment.

Description

technical field [0001] The invention belongs to the field of building materials, and in particular relates to an admixture for improving the impermeability and crack resistance of marine concrete. Background technique [0002] In recent years, with the continuous improvement of my country's economic development and international competitiveness, a large number of major basic projects are being constructed or planned in my country's oceans and western regions. However, the climate conditions of these basic projects are harsh, and some high-concentration corrosive media (Mg 2+ , SO 4 2- , Cl - ) can easily lead to internal structural damage of concrete materials, degradation of gelling force, and increased corrosion rate of steel bars, which will cause premature failure of engineering structures, and the service life will not reach the designed service life, resulting in huge economic losses. [0003] To improve the durability of concrete materials, the most important thing...

Claims

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Application Information

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IPC IPC(8): C04B24/32C08F283/06C08F220/10C08F290/06C08F220/06
CPCC04B40/0039C08F283/065C08F290/062C04B24/12C04B24/04C04B22/06C04B16/02C04B24/32C08F220/10C08F220/06
Inventor 丁庆军刘凯陈宏哲毛若卿张海林王登科
Owner HAINAN RUIZE NEW BUILDING MATERIAL
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