Low-cost warping-free high-flame-retardant polypropylene furniture material and preparation method thereof

A flame-retardant polypropylene, no warping technology, applied in the field of organic polymer nanocomposite materials, can solve the problem of affecting the mechanical properties and appearance of polypropylene systems, difficult to meet high-end polypropylene furniture materials, unable to meet the performance of household materials, etc. problems, to achieve excellent mechanical properties and flame retardant properties, smooth surface without warping, and reduce product costs.

Inactive Publication Date: 2016-06-15
ZHEJIANG SENCHUAN FURNITURE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding other high-performance polymer materials to the polypropylene resin can improve the performance of the polypropylene system, but the cost is often high, and it is difficult to promote in furniture products
Adding inorganic nanoparticles such as glass fiber and calcium carbonate to polypropylene resin (the price is relatively low compared to polypropylene) can improve the mechanical properties of polypropylene material and control its cost to a certain extent, but due to the relative Poor capacity, if the addition amount is large (greater than 30%), it is easy to form phase separation or stress concentration, which will affect the mechanical properties and appearance of the polypropylene system, and cannot meet the performance requirements of household materials
At present, domestic and foreign patents and technologies are difficult to meet the needs of high-end polypropylene furniture materials (good performance, no warping, low cost)

Method used

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  • Low-cost warping-free high-flame-retardant polypropylene furniture material and preparation method thereof
  • Low-cost warping-free high-flame-retardant polypropylene furniture material and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0029] A kind of low-cost non-warp polypropylene furniture material of the present invention is made up of the raw material of following weight portion: polypropylene is 50%, short glass fiber organic masterbatch is 15%, toughening agent POE-g-MAH ( Grafting ratio (2.5%) is 9%, nanometer calcium carbonate is 25%, lubricant heat-resistant type aliphatic hyperbranched polyester mixture (average relative molecular weight is 5200) 1%.

[0030] First, prepare short glass fiber organic masterbatch according to the following steps:

[0031] Step 1: Liquid paraffin and monoalkoxy pyrophosphate coupling agent are diluted and mixed according to the volume ratio of 1:1;

[0032] Step 2: Put the pentaerythritol diphosphate melamine salt in a high-speed mixer, drop into the mixed solution of step 1 with a mass ratio of 2:1 to the pentaerythritol diphosphate melamine salt while stirring, and continue stirring for 10-15 minutes;

[0033] Step 3: Add short glass fibers with a mass ratio of 5...

Embodiment 2

[0037] A kind of low-cost non-warping polypropylene furniture material of the present invention is made up of the raw material of following weight portion: polypropylene is 24%, short glass fiber organic masterbatch is 35%, toughening agent POE-g-MAH ( Graft rate (2.5%) is 5.4%, nanometer calcium carbonate is 35%, lubricant heat-resistant type aliphatic hyperbranched polyester mixture (average relative molecular weight is 11500) 0.6%.

[0038] The preparation method of the short glass fiber organic masterbatch and the polypropylene furniture material of this embodiment is the same as that of Embodiment 1, and will not be repeated here.

Embodiment 3

[0040]A kind of low-cost non-warp polypropylene furniture material of the present invention is made up of the raw material of following weight portion: polypropylene is 35%, short glass fiber organic masterbatch is 25%, toughening agent POE-g-MAH ( Grafting ratio (2.5%) is 8.5%, nano calcium carbonate is 31%, lubricant heat-resistant type aliphatic hyperbranched polyester mixture (average relative molecular weight is 10000) 0.5%.

[0041] The preparation method of short glass fiber organic masterbatch and polypropylene furniture material of this embodiment is the same as that of Embodiment 1.

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Abstract

The invention discloses a low-cost warping-free high-flame-retardant polypropylene furniture material, prepared from the following components according to a weight ratio: 20-50 percent of polypropylene, 15-35 percent of short glass fiber organic masterbatch, 5-10 percent of flexibilizer, 25-35 percent of nano calcium carbonate and 0.1-1 percent of lubricant; the short glass fiber organic masterbatch is formed by short glass fiber, intumescent flame retardants, a coupling agent of organic titanate and polyethylene wax. Organized modification is performed on the short glass fiber, the surface of the short glass fiber is coated with the coupling agent, the flame retardants and an organic polymeric membrane, so that the compatibility between the short glass fiber and the interface of polypropylene resin can be effectively improved, the uniform dispersion of the glass fiber and the flame retardants is promoted, the warping problem caused by stress is prevented, the mechanical property and flame retardance are improved, the filling content of the short glass fiber is increased, and the product cost is lowered.

Description

technical field [0001] The invention relates to an organic polymer nanocomposite material, more specifically, to a low-cost, non-warping, high-flame-retardant polypropylene furniture material and a preparation method thereof. Background technique [0002] Plastic furniture is a new kind of furniture, which has occupied a very important position in people's daily life. Compared with other furniture, plastic furniture has the advantages of 1) brilliant colors and smooth lines; 2) diverse and casual and beautiful shapes; 3) light, compact and easy to take; 4) various varieties and wide application; 5) easy to clean and easy to protect; 6) cheap And so on a series of advantages. Because plastic furniture has such obvious advantages, it has rapidly occupied the market share in the furniture field in recent years. But at present, my country's domestic plastic furniture mainly occupies the middle and low-end market in the mainstream furniture market. This is not only because of s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L23/06C08L51/06C08L67/00C08K9/10C08K9/04C08K7/14C08K3/26C08K5/521C08J3/22C08J5/08
CPCC08L23/12C08J3/223C08J5/08C08J2323/12C08J2423/06C08K2201/011C08L2201/02C08L2205/02C08L2205/035C08L23/06C08L51/06C08L67/00C08K9/10C08K9/04C08K7/14C08K2003/265C08K5/521
Inventor 胡森川杨晋涛罗万象
Owner ZHEJIANG SENCHUAN FURNITURE
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