Hydrogen production nano-device, production method thereof, and hydrogen production method

A nano-device and metal nano-particle technology is applied in the field of nano-devices for preparing hydrogen, which can solve the problems of large electricity demand for electrolyzed water, achieve broad market application prospects, solve environmental pollution, and improve the effect of hydrogen yield.

Active Publication Date: 2016-06-22
BEIJING INST OF NANOENERGY & NANOSYST
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The efficiency of these two methods of producing hydrogen is very high, but the method of burning minerals uses non-renewable energy, while the electrolysis of water requires a large amount of electricity, which limits their development, so there is an urgent need for a new high-efficiency, non-polluting and energy-efficient method to produce hydrogen

Method used

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  • Hydrogen production nano-device, production method thereof, and hydrogen production method
  • Hydrogen production nano-device, production method thereof, and hydrogen production method
  • Hydrogen production nano-device, production method thereof, and hydrogen production method

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preparation example Construction

[0034] In the preparation method of the present invention, the solvent is not particularly limited, and can be various solvents commonly used in the art. Preferably, the solvent is water or an organic solvent, and the organic solvent is N,N-dimethylformamide, trifluoro One or more of ethanol, methanol, ethanol, propanol, isopropanol, dimethylsulfoxide and chloroform. The corresponding solvent can be selected according to the amino acid sequence of the α-helical polypeptide, which is known to those skilled in the art and will not be repeated here.

[0035] In the preparation method of the present invention, preferably, based on the self-assembly reaction system, the concentration of metal nanoparticles is 0.5-20 mg / mL, more preferably 1-10 mg / mL; the concentration of α-helical polypeptide is 0.1-20 mg / mL; 10mM, more preferably 0.2-5mM; the molar ratio of α-helical polypeptide to photoelectron donor is 1:1-20, more preferably 1:5-15.

[0036] In the preparation method of the pr...

Embodiment

[0057] The following examples will further illustrate the present invention, but do not limit the present invention thereby.

[0058] In the following preparation examples, examples and comparative examples, unless otherwise specified, all reagents used are commercially available.

[0059] Polypeptide solid-phase synthesizer was purchased from CSBIO company, the model is CS136XT.

[0060] Gold nanoparticles are prepared by sodium citrate reduction method, the specific method includes: 100mL of 0.1% by weight chloroauric acid is heated to boiling with electromagnetic stirring, and then 5mL of 1% by weight of citric acid is added to obtain a 5.5mg / mL gold nanoparticle solution .

[0061] Silver nanoparticles were prepared by the traditional one-step reduction method of sodium citrate. The specific method included: mixing 100mL7.0×10 -3 M sodium citrate solution was added in a 250mL flask, stirred and heated to boiling, and then 1mL of 0.1M silver nitrate was added to obtain a ...

preparation example 1

[0063] This preparation example is used to illustrate the preparation of α-helical polypeptides.

[0064] 0.5 g of Clear-acid resin (Clear-Acid Resin, purchased from Peptide Institute Inc.) and 5 mL of dichloromethane were placed in a polypeptide solid-phase synthesizer and shaken for 24 hours. After washing the resin with N,N-dimethylformamide (DMF), 3 mL of a DMF solution of 0.7 mM Fmoc-leucine (purchased from Peptide Institute Inc.), 0.7 mM N-hydroxy-7-azobenzotriazole Mix 1mL of DMF solution with 1mL of DMF solution of 0.7mM 1,3-diisopropylcarbodiimide, add it to the peptide solid-phase synthesizer, and mix it with the above resin, shake and react for 2 hours, the carboxyl group of leucine and the resin Condensation reaction of the amino group on the above-mentioned resin occurs, and Fmoc-leucine is fixed on the above-mentioned resin. After the reaction was completed, the resin was washed with DMF, and 5 mL of piperidine / DMF mixed solution (volume ratio of piperidine to D...

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Abstract

The invention provides a hydrogen production nano-device, a production method thereof, and a hydrogen production method thereof. The hydrogen production nano-device comprises metal nano-particles, a photoinduced electron donor, alpha-helical peptides and organic metalloenzyme. The hydrogen production nano-device can use renewable solar energy to realize efficient and pollution-free hydrogen generation, all raw materials used in the invention have very good environment endophilicity and no pollution, and the macroscopic dipole moment characteristic of the alpha-helical peptides is used to improve the unidirectional electron delivery efficiency and improve the hydrogen yield, so the problems of environment pollution and energy consumption of present hydrogen production methods are effectively solved.

Description

technical field [0001] The invention relates to a nano-device for preparing hydrogen, in particular to a hydrogen-producing nano-device, a preparation method thereof, and a hydrogen-producing method. Background technique [0002] Due to the increasingly serious problems of insufficient crude oil supply and environmental pollution in the world, hydrogen, as a kind of green energy, has the advantages of renewable, pollution-free, and high energy release during combustion, and has attracted widespread attention. At present, industrial hydrogen production mostly adopts the method of mineral combustion or electrolysis of water. The efficiency of these two methods of producing hydrogen is very high, but the method of burning minerals uses non-renewable energy, while the electrolysis of water requires a large amount of electricity, which limits their development, so there is an urgent need for a new high-efficiency, non-polluting And energy-saving method to produce hydrogen. Con...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B3/02
CPCY02P20/133
Inventor 王心心李舟江文张亚岚石波璟
Owner BEIJING INST OF NANOENERGY & NANOSYST
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