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Viscous graphene stripping combined solution

A technology of combining liquid and graphene, applied in the field of graphene production, can solve the problems of reducing the service life of equipment, high acid consumption, and graphene is prone to defects, and achieves the effect of reducing requirements and improving conductivity

Inactive Publication Date: 2016-06-29
江苏碳谷二维世界科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this kind of chemical substance intercalation process consumes a lot of acid, and there are harmful gases such as SOx and NOx or pollution of heavy metal ions in the production process. There are sulfur residues in the product, and the final graphene is prone to defects, and it is harmful to equipment during application. There is corrosion, which reduces the service life of the equipment and increases the production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The invention relates to a viscous graphene peeling combination liquid, which comprises: 100 parts by weight of water, 30 parts by weight of ethanol, 50 parts by weight of polyacrylate, and 0.5 parts by weight of lithium fluoride. Wherein, the number average molecular weight of the polyacrylate is greater than 100,000.

Embodiment 2

[0020] The present invention is a viscous graphene stripping combination liquid, the composition of which comprises: 100 parts by weight of water, 40 parts by weight of ethanol, 20 parts by weight of n-propanol, 80 parts by weight of polyurethane modified acrylate, fluorine Sodium chloride 2 parts by weight. Wherein, the number average molecular weight of the polyurethane-modified acrylate is greater than 100,000.

Embodiment 3

[0022] The present invention relates to a viscous graphene stripping combination liquid, the composition of which comprises: 100 parts by weight of water, 40 parts by weight of n-butanol, 40 parts by weight of propylene glycol, 60 parts by weight of polyurethane modified acrylate, chlorine NaCl 4 parts by weight. Wherein, the number average molecular weight of the polyurethane-modified acrylate is greater than 100,000.

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PUM

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Abstract

The invention discloses a viscous graphene stripping combined solution. The combined solution comprises the following components by weight: 100 parts of water, 30-100 parts of an alcoholic solvent, 50-80 parts of polyacrylic ester or polyacrylic ester derivative, and 0.5-5 parts of a water soluble salt. According to the invention, polyacrylic ester or polyacrylic ester derivative with glue adhesiveness is added into the combined solution, the combined solution can be used in coordination with grinding or stirring so as to reduce the requirement for grinding or stirring speed, and stripping of graphene can be realized without ultra high-speed shearing to a flake graphite layer. In addition, the water soluble salt added into the system can improve the conductivity of the system, superimposition of stripped graphene together again due to static electricity can be avoided, and a disperse state after stripping can be maintained. The combined solution can strip graphene, and at the same time has no corrosion to equipment and causes no damage to the graphene structure.

Description

technical field [0001] The invention relates to the technical field of graphene production, in particular to a combination liquid for exfoliating graphite into graphene. Background technique [0002] Graphene is a two-dimensional material with good flexibility and electrical properties. What needs to be added is that, strictly speaking, graphene is a single-layer sheet; however, due to the difficulty of preparing single-layer graphene, oligolayer graphene with similar properties is generally also classified into the category of graphene. Inside. [0003] At present, the methods for preparing graphene mainly include: chemical growth method and physical exfoliation method. Compared with the chemical growth method, which is inefficient and not suitable for industrial mass production, the physical exfoliation method mainly uses cheap graphite as a raw material, and applies mechanical force to the graphite crystal to cause the graphite layers to peel off, breaking the van der W...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/04
Inventor 戴加龙
Owner 江苏碳谷二维世界科技有限公司
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