The invention discloses a cleaning technology for extracting
vanadium from
vanadium containing materials through
sodium salt
roasting.
Sodium chloride is added in the
vanadium containing material orefor uniform mixing and fine
grinding, nodulizing
roasting is conducted, after harmful gases in
roasting smoke are removed through an adsorbent, the roasting
smoke reaches the standard to be exhausted,obtained roasted ore is subjected to water leaching and then subjected to alkaline leaching, and water is added in the roasted ore for leaching; a water leaching solution and water leaching residuesare obtained through
filtration, a
sodium carbonate salt solution is added in the water leaching residues for leaching, and an alkaline leaching solution and leaching residues are obtained through
filtration;
calcium chloride is added in the water leaching solution to deposit enriched vanadium, and
calcium vanadate filter cakes and a
molybdenum precipitation liquid are obtained through
filtration;the
molybdenum precipitation liquid returns to the roasted ore water leaching procedure or vanadium containing material ore mixing or nodulizing procedure to be circularly used, the obtained calciumvanadate filter cakes are decomposed through the alkaline leaching solution, and
calcium carbonate and vanadium enriching liquid are obtained through filtration; after
calcium carbonate is roasted andconverted into
calcium oxide, the
calcium oxide returns to the high-temperature
smoke purification procedure to be continuously used;
ammonium salt is added in the vanadium enriching liquid, vanadiumis separated by
crystallization, and
ammonium metavanadate and
crystallization mother liquor thereof are obtained through filtration, the
ammonium metavanadate is subjected to
pyrolysis, a vanadium
pentoxide product is obtained, the
crystallization mother liquor directly returns to the alkaline leaching procedure, or after calcium is added for vanadium depositing, the crystallization
mother liquor returns to the alkaline leaching procedure to be circularly used. Cyclic utilization of
sodium chloride,
lime,
sodium carbonate salt and water in the technology process is achieved, and the beneficial effects that the technology is simple, the vanadium recycling rate is high, the production cost is low, and cleanliness and environment friendliness are achieved are achieved.