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Active carbon electrode material as well as preparation method and application thereof

An activated carbon and electrode technology, which is applied in the field of supercapacitor electrode material preparation to achieve the effects of increasing added value, broad application prospects and large specific surface area

Inactive Publication Date: 2016-07-06
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, this solid product is generally used directly as an adsorbent and soil improver. There is no modification of the solid product at home and abroad to make an activated carbon material that can be directly used to prepare supercapacitors, and there is no direct deoxidation of biomass to liquefy biochar. Related reports on preparation of supercapacitor electrode materials from raw materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] The direct deoxidation liquefaction reaction of corn stalks is carried out to obtain biochar, and the biochar and the activator KOH are mixed and stirred at a mass ratio of 1:3, and then the mixture is dried at 120°C to obtain a mixture; the obtained mixture is placed in In a tubular resistance furnace, the temperature was raised to 700°C for 2 hours under the protection of nitrogen; the activated biochar after cooling was washed with hydrochloric acid and deionized water to neutrality, and the product was vacuum-dried at 60°C to obtain the desired activated carbon material. The obtained activated carbon sample was pulverized to 30 μm, according to the ratio of activated carbon: PTEF: acetylene carbon black = 8:1:1, mixed with solvent, mixed evenly in a mixer, dried, and pressed into 100 μm flakes, and then vacuum-dried at 60°C for 12 hours to obtain the electrode material to be prepared, with a measured specific surface area of ​​550m 2 / g, the specific capacitance is...

Embodiment 2

[0034] The green alga Enteromorpha is directly deoxidized and liquefied to obtain biochar, and the biochar and the activator KOH are mixed and stirred at a mass ratio of 1:4, and then the mixture is dried at 150°C to obtain a mixture; the obtained mixture The raw materials were placed in a tubular resistance furnace, heated to 800°C for 2 hours under nitrogen protection, and activated for 2 hours; the cooled activated biochar was washed with hydrochloric acid and deionized water to neutrality, and the product was vacuum-dried at 80°C to obtain required activated carbon material. The obtained activated carbon sample was crushed to 20 μm, according to the ratio of activated carbon: PTEF: acetylene carbon black = 8:1:1, mixed with a solvent, mixed uniformly in a mixer, dried, and pressed into 150 μm flakes, and then vacuum-dried at 60°C for 15 hours to obtain the electrode material to be prepared, with a measured specific surface area of ​​506 m 2 / g, the specific capacitance is...

Embodiment 3

[0036] Direct deoxidation liquefaction reaction of sawdust to produce biochar, biochar and activator H 3 PO 4 Mix and stir according to the mass ratio of 1:5, and then dry the mixture at 150°C to obtain the mixture; place the obtained mixture in a tubular resistance furnace, and raise the temperature to 900°C under the protection of nitrogen to activate for 2 hours; after cooling The activated biochar was washed with hydrochloric acid and deionized water to neutrality, and the product was vacuum-dried at 80°C to obtain the desired activated carbon material. The obtained activated carbon sample was crushed to 20 μm, according to the ratio of activated carbon: PTEF: acetylene carbon black = 8:1:1, mixed with a solvent, mixed uniformly in a mixer, dried, and pressed into 150 μm flakes, and then vacuum-dried at 60°C for 10 hours to obtain the electrode material to be prepared, with a measured specific surface area of ​​727m 2 / g, the specific capacitance is up to 351F / g.

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PUM

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Abstract

The invention discloses an activated carbon electrode material and its preparation method and application. 1) Mixed solution preparation: prepare an activator solution, mix and stir with biochar obtained by direct deoxidation and liquefaction of biomass, and then dry the mixed solution to obtain a mixed solution. 2) Activation process: the obtained mixture is placed in a tubular resistance furnace and activated under nitrogen protection; 3) pickling process: the cooled activated biochar is washed with hydrochloric acid and deionized water to neutrality respectively, The product is vacuum-dried to obtain the required activated carbon material; 4) activated carbon electrode preparation: the prepared activated carbon sample is pulverized to 10-30 μm, according to the ratio of activated carbon: PTEF: acetylene carbon black = 7-9: 1: 1, and The solvents are mixed and then dried, pressed into thin slices of 80-150 μm, and then vacuum-dried to obtain the electrode material to be prepared. The prepared porous activated carbon material has a large specific surface area, a large specific capacitance, and good cycle stability, and has broad application prospects in the field of electrode materials for supercapacitors.

Description

technical field [0001] The invention belongs to the technical field of preparation of supercapacitor electrode materials, and in particular relates to an activated carbon electrode material and its preparation method and application. Background technique [0002] With the rapid development of social economy and the increasing shortage of resources, the new energy storage element supercapacitor has been developed rapidly, which well makes up for the shortcomings of batteries and fuel cells, such as low power, poor resistance to high current charge and discharge, and low energy storage density of traditional capacitors. , The application in the fields of new energy vehicles, mobile communications and aerospace has attracted more and more people's attention. Therefore, research on electrochemical capacitors has become a hot spot in the research of new energy storage components, and electrode materials are the key factors that determine the performance of electrochemical capacit...

Claims

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Application Information

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IPC IPC(8): C01B31/12H01G11/34
CPCY02E60/13H01G11/34C01P2006/12
Inventor 李金花王吉萍王宗花王国明
Owner QINGDAO UNIV
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