Method for determining tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloy through wavelength dispersion X-ray fluorescent spectrometry

A technique of fluorescence spectroscopy and wavelength dispersion, which is applied in the field of alloy composition analysis, achieves the effects of fast analysis, simple spectral lines, and improved work efficiency

Inactive Publication Date: 2016-07-06
国家再生有色金属橡塑材料质量监督检验中心(安徽)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved in the present invention is to provide a method for measuring tin, antimony, arsenic, bismuth, copper, cadmium, calcium, and silver in lead alloys by wavelength dispersive X-ray fluorescence spectrometry, and to solve the problem of instrument conditions when multiple elements are simultaneously measured. The problem of optimization has the advantages of simple spectral lines, fast analysis speed, many measurement elements, and simultaneous analysis of multiple elements to improve work efficiency, reduce the use of chemical reagents and reduce environmental pollution

Method used

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  • Method for determining tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloy through wavelength dispersion X-ray fluorescent spectrometry
  • Method for determining tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloy through wavelength dispersion X-ray fluorescent spectrometry
  • Method for determining tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloy through wavelength dispersion X-ray fluorescent spectrometry

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Experimental program
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Effect test

Embodiment 1

[0074] This embodiment is the determination of standard samples, which is used for selecting instruments and measuring working conditions and establishing a standard curve.

[0075] This embodiment includes the following steps:

[0076] 1) Select standard material for spectral analysis;

[0077] 2) prepare standard samples;

[0078] 3) Select instruments and measuring working conditions;

[0079] 4) Establish element standard curve;

[0080] 5) Optimize element detection limit and method precision;

[0081] 6) Measure the sample to be tested according to the determination method and standard curve established in steps 1) to 5).

[0082] In this embodiment, in step 1), the specific standard samples selected are: 84XBA1, 84XBA20, 85XPSb10, 85XPSb12, 85XPSb3, 85XPSb5, 86XPSS1, 86XPSS2, 86XPSS3, 86XPSS4, 91XS30PR2, 91XS63Bi1, 91XS63PR4, NF44-6, 84XPR823, 8 , 91XS50PR4, NF34-3, 82XPAG2.5R, 82XPAG3.5R, 84XBA21, 84XBA22, 83XPR7, 85XCADL, 85XCADH, the standard samples are importe...

Embodiment 2

[0127] The sample measured in this example is the No. 2 sample.

[0128] In this embodiment, the preparation method of the sample to be tested is as follows: smooth the surface of the standard sample, wipe the surface of the standard sample with absorbent cotton dipped in absolute ethanol, and store the standard sample in a Ф32mm sample cup.

[0129] According to the standard curve in Example 1, the method of the present invention is used to simultaneously test the content of each element in the sample of this example.

Embodiment 3

[0131] The sample measured in this embodiment is sample No. 3.

[0132] In this embodiment, the preparation method of the sample to be tested is as follows: smooth the surface of the standard sample, wipe the surface of the standard sample with absorbent cotton dipped in absolute ethanol, and store the standard sample in a Ф32mm sample cup.

[0133] According to the standard curve in Example 1, the method of the present invention is used to simultaneously test the content of each element in the sample of this example.

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Abstract

The invention relates to a method for determining tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloy through wavelength dispersion X-ray fluorescent spectrometry. The method includes the steps that 1, a spectral analysis standard substance is selected; 2, a standard sample is prepared; 3, an instrument and measurement working conditions are selected; 4, an element standard curve is established; 5, element detection limit and method precision are optimized; 6, six determining steps are performed on the sample to be determined according to the established determining method and standard curve in the step1-5. The method has the advantages that a spectral line is simple, analysis speed is high, many measurement elements are used, and the multiple elements can be analyzed at the same time. The method achieves accurate and rapid detection in the detection process of the lead alloy, working efficiency is improved, using of chemical reagent is reduced, and environmental pollution is reduced.

Description

technical field [0001] The invention relates to the technical field of alloy composition analysis, in particular to a method for measuring tin, antimony, arsenic, bismuth, copper, cadmium, calcium and silver in lead alloys by using wavelength dispersive X-ray fluorescence spectrometry. Background technique [0002] Due to the characteristics of high density, low melting point, good corrosion resistance and radiation protection, lead and lead alloys have a wide range of applications and cannot be replaced by other metals. Lead alloys are used in electrolytic zinc, electrolytic copper and battery industries. As anodes in hydrometallurgical processes, they have the advantages of high hardness, good mechanical properties, excellent casting performance, long service life, and simple production processes. Lead alloys are not easily penetrated by X and gamma rays, and can be used as protective materials for radioactive work. [0003] The elements in lead and lead alloys are mainly...

Claims

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Application Information

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IPC IPC(8): G01N23/223
CPCG01N23/223G01N2223/076
Inventor 鲁仕梅赵杰罗怀邦李彪薛艳王伟胡咏梅谭波涛尚岩岩
Owner 国家再生有色金属橡塑材料质量监督检验中心(安徽)
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