High-anti-slippery abrasion-resistant material for shoes and preparation method thereof

A wear-resistant material and anti-slip technology, which is applied in the field of shoes, can solve problems such as increasing the difficulty of production, and achieve the effects of enhancing mechanical properties, improving wear resistance and anti-wet skid performance

Active Publication Date: 2016-07-20
QUANZHOU JIYOU SHOES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN103483634 discloses a kind of non-slip rubber sole material, adding TDI modified nano SiO 2 and other additives, improve the coefficient of friction, but due to SiO

Method used

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  • High-anti-slippery abrasion-resistant material for shoes and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0021] Example 1:

[0022] First send 30 parts of natural rubber, 20 parts of styrene butadiene rubber, 25 parts of butadiene rubber and 25 parts by weight of bromobutyl rubber into the open mill for open milling with a roller pitch of 1 mm and 10 thin passes; The mixed rubber compound after mixing is mixed with 8 parts by weight of zinc oxide, 1 part by weight of tetramethylthiuram monosulfide, 1 part by weight of N-phenyl-1-naphthylamine, 15 parts by weight of rubber oil, and 0.5 parts by weight of stearin Acid, 13 parts by weight of white carbon black and 27 parts by weight of nano-calcium carbonate are put into the banburying secret mixing, the temperature of the banburying machine is 125℃, and the materials are discharged after mixing for 4 minutes; the above mixed rubber is discharged into the designated mold and cooled for 24 Hours; after cooling, add 1 part by weight of sulfur, 4.5 parts by weight of silicon carbide and 4 parts by weight of organic silicon peroxide coupli...

Example Embodiment

[0023] Example 2:

[0024] First, 40 parts of natural rubber, 25 parts of styrene butadiene rubber, 20 parts of butadiene rubber and 23 parts by weight of chlorinated butyl rubber are sent to the open mill for open milling. The mill roll distance is 1mm and the thinning passes 10 times; Afterwards, the mixed rubber material after mixing is mixed with 4 parts by weight of zinc carbonate, 3 parts by weight of dibenzothiazole disulfide, 3 parts by weight of N-phenyl-N'-isopropyl p-phenylenediamine, and 20 parts by weight of rubber oil , 1 part by weight of stearic acid, 17 parts by weight of white carbon black and 23 parts by weight of nano-calcium carbonate are put into the banbury mixing, the temperature of the banbury mixer is 110℃, and the material is discharged after mixing for 4 minutes; the above mixed rubber is discharged In the designated mold, cool for 24 hours; after cooling, add 2 parts by weight of sulfur, 3.5 parts by weight of silicon carbide and 3 parts by weight of ...

Example Embodiment

[0025] Example 3:

[0026] First, 30 parts of natural rubber, 40 parts of styrene butadiene rubber, 25 parts of butadiene rubber and 15 parts by weight of iodinated butyl rubber are sent to the open mill for open milling, with a roll distance of 1 mm and 10 thin passes; Then the mixed rubber material after the smelting was mixed with 3 parts by weight of titanium dioxide, 2 parts by weight of N,N'-bicyclohexyl-2-benzothiazole sulfenamide, 2 parts by weight of 2-mercaptobenzimidazole, 15 parts by weight Parts of rubber oil, 1.5 parts by weight of stearic acid, 20 parts by weight of white carbon black and 20 parts by weight of nano-calcium carbonate are put into the banbury mixing, the temperature of the banbury mixer is 100℃, and the material is discharged after mixing for 5 minutes; The glue is discharged into the designated mold and cooled for 24 hours; after cooling, add 2 parts by weight of sulfur, 3 parts by weight of silicon carbide and 2 parts by weight of long-chain alkyl ...

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Abstract

The invention discloses a high-anti-slippery abrasion-resistant material for shoes and a preparation method thereof.The high-anti-slippery abrasion-resistant material is prepared from, by weight, 20-40 parts of natural rubber, 20-40 parts of styrene-butadiene rubber, 20-40 parts of butadiene rubber, 15-25 parts of halogenated butyl rubber, 20-30 parts of nanometer calcium carbonate, 10-20 parts of rubber oil, 10-20 parts of white carbon black, 3-8 parts of an activator, 3-5 parts of silicon carbide, 2-4 parts of organic siloxane, 1-5 parts of an accelerant, 1-3 parts of an antiager, 1-3 parts of sulfur and 0.5-1.5 parts of stearic acid.The raw materials required by the prepared high-anti-slippery abrasion-resistant material for the shoes are low in price and easy to obtain, the preparation process is simple, the strength is high, the anti-slippery performance is good, the abrasion-resistant performance and processing performance are excellent, the friction coefficient is 1.4-1.6, the friction volume is 304-315/mm<3>, and the material can be used for production of high-anti-slippery abrasion-resistant shoe soles and other auxiliary materials.

Description

technical field [0001] The invention belongs to the field of shoes, and in particular relates to a high anti-slip and wear-resistant material for shoes and a preparation method thereof. Background technique [0002] Generally, the anti-slip (dry) effect of rubber materials under normal conditions is mostly good, but some industries require higher anti-slip effects to meet the needs of operations under harsh working conditions, such as used in wet ground environments (working with water or kitchen) work shoes, etc. At present, the manufacturing process of high anti-skid shoes on the market is complicated, and the material is expensive. Its price is often ten times or even dozens of times that of ordinary footwear, and the applicable environmental conditions are relatively limited. [0003] According to the current research status of the footwear industry, injection-molded shoe soles such as sneakers and injection-molded shoes are heavy and hard, which affects wearing comfort...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L9/06C08L9/00C08L23/28C08K13/02C08K3/34C08K3/26C08K5/09C08K3/36C08K3/22A43B13/04
CPCA43B13/04C08K2201/011C08L7/00C08L9/00C08L9/06C08L2205/02C08L2205/035C08L23/283C08K13/02C08K3/34C08K2003/2296C08K5/09C08K3/36C08K2003/265
Inventor 王勇丁功成
Owner QUANZHOU JIYOU SHOES CO LTD
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