A kind of porous carbon-graphene-metal oxide composite material and its preparation method and application
A composite material and porous material technology, applied in porous carbon-graphene-metal oxide composite material and its preparation and application fields, can solve the problem of reducing the performance and product quality of supercapacitor devices, affecting the conductivity of electrode materials, and the resistance of electrode materials. It can solve the problems of high rate and other problems, so as to maintain the continuity and continuity, solve the discontinuity of specific surface area and structure, and achieve the effect of continuous and complete structure.
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Embodiment 1
[0043] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0044] (1) After cleaning the loofah, freeze-drying at -50°C for 48 hours;
[0045] (2) The configuration concentration is 5 mg. ml -1 The graphene oxide suspension is stirred vigorously to obtain a stable graphene oxide suspension;
[0046] Put the freeze-dried loofah into the graphene oxide solution, soak it for 2 hours, and then dry it at 60°C; repeat the above steps 5 times to ensure that the graphene completely enters the porous material of the loofah and adheres to the porous material surface, forming a porous-graphene oxide composite;
[0047]In the above-mentioned steps, the mass ratio of graphene oxide and loofah is 1:40.
[0048] (3) Put the porous-graphene oxide composite material into a tube furnace for heat treatment, the heat treatment temperature is 900°C, and the treatment time is 2h, carbonize the porous material, reduce gra...
Embodiment 2
[0052] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0053] (1) After the aloe is washed, freeze-drying is carried out at -40° C. for 24 hours;
[0054] (2) The configuration concentration is 10 mg. ml -1 The graphene oxide suspension, vigorously stirred to obtain a stable graphene oxide suspension;
[0055] Put the freeze-dried loofah into the graphene oxide solution, soak it for 4 hours, and then dry it at 100°C; repeat the above steps 10 times to ensure that the graphene completely enters the aloe porous material and adheres to the surface of the porous material , forming a porous-graphene oxide composite;
[0056] In the above steps, the mass ratio of graphene oxide to aloe is 1:30.
[0057] (3) Put the porous-graphene oxide composite material into a tube furnace for heat treatment, the heat treatment temperature is 1000°C, and the treatment time is 4h, carbonize the porous material, reduc...
Embodiment 3
[0061] A method for preparing a porous carbon-graphene-metal oxide composite material, specifically comprising the following steps:
[0062] (1) the shell is first polished off the protein and pearl layer with sandpaper, after cleaning, the shell is decalcified with EDTA decalcification solution, cleaned and dried;
[0063] (2) The configuration concentration is 8 mg. ml -1 The graphene oxide suspension, vigorously stirred to obtain a stable graphene oxide suspension;
[0064] Put the treated shells into the graphene oxide solution, soak them for 3 hours, and then dry them at 70°C; repeat the above steps 8 times to ensure that the graphene completely enters the shell porous material and adheres to the surface of the porous material to form a porous- Graphene oxide composite materials;
[0065] In the above steps, the mass ratio of graphene oxide to shell is 1:50.
[0066] (3) Put the porous-graphene oxide composite material into a tube furnace for heat treatment, the heat ...
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