Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of flame-retardant and shock-absorbing EPDM vulcanizate and preparation method thereof

A technology of vulcanized rubber and flame retardant, applied in the field of rubber, can solve the adverse effects of EPDM tensile strength, compression permanent deformation and heat generation performance, affect the dynamic performance and fatigue performance of vibration-damping EPDM products, and the corrosion environment of circuit system switch metal objects and other problems, to achieve good physical and mechanical properties, improved resilience, and reduced compression set

Active Publication Date: 2019-06-28
ZHUZHOU TIMES NEW MATERIALS TECH
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And EPDM (hereinafter referred to as EPDM) is as the commonly used material in the railway industry, although it has good shock absorption and noise reduction performance, it is flammable, and there is a fire hazard unavoidably in the use process. Therefore, to improve The flame retardant performance of EPDM products is imperative
[0003] At present, EPDM materials are mainly improved by adding halogen-containing flame retardants and filling a large amount of inorganic flame retardants to improve their flame-retardant properties. The smoke and toxic and corrosive gases will easily lead to corrosion of circuit system switches and other metal objects and pollution to the environment. It will also cause certain harm to the human respiratory tract and other organs, and even cause people to threaten their lives due to suffocation. ; while inorganic flame retardants are mainly inorganic metal hydroxides, which have low flame retardant efficiency and need to be added in large quantities to achieve good flame retardant and smoke suppression effects, but a large amount of inorganic flame retardants will affect the tensile strength of EPDM. , Compression set, springback and heat generation will have adverse effects, which will affect the dynamic performance and fatigue performance of vibration-damping EPDM products

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of flame-retardant and shock-absorbing EPDM vulcanizate and preparation method thereof
  • A kind of flame-retardant and shock-absorbing EPDM vulcanizate and preparation method thereof
  • A kind of flame-retardant and shock-absorbing EPDM vulcanizate and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] The flame-retardant and shock-absorbing EPDM vulcanizate of this embodiment is mainly prepared from the raw materials in Table 1.

[0043] The preparation method of the flame-retardant and shock-absorbing EPDM vulcanizate of the present embodiment may further comprise the steps:

[0044] (1) According to the weight of raw materials in Table 1, EPDM rubber, zinc oxide, stearic acid, antioxidant MB and other additives were added to the internal mixer and mixed for 2 minutes;

[0045] (2) Add carbon black, pottery clay, aluminum hydroxide, zinc borate, CDP, ammonium octamolybdate to the internal mixer and mix again. When the temperature of the rubber material reaches 150°C, mix for 5 minutes to remove the glue and cool down. Prepare a section of mixed rubber;

[0046] (3) When a section of mixed rubber is cooled to below 60°C, it is added to the internal mixer together with sulfur and accelerators for mixing, but when the rubber material reaches above 105°C, the rubber is d...

Embodiment 2

[0056] The flame-retardant and shock-absorbing EPDM vulcanizate of this embodiment is mainly prepared from the raw materials in Table 3.

[0057] The preparation method of the flame-retardant and shock-absorbing EPDM vulcanizate of the present embodiment may further comprise the steps:

[0058] (1) According to the weight of raw materials in Table 3, EPDM rubber, zinc oxide, stearic acid, antioxidant MB and other additives were added to the internal mixer and mixed for 2 minutes;

[0059] (2) Add carbon black, white carbon black, hydrated aluminum hydroxide, zinc borate, CDP, ammonium octamolybdate, Charmax FS-BZMA to the internal mixer and then mix, when the temperature of the rubber material reaches 150 ° C Mixing for 5 minutes, debinding and cooling, to obtain a section of mixed rubber;

[0060] (3) When a section of mixed rubber is cooled to below 60°C, it is added to the internal mixer together with sulfur and accelerators for mixing, but when the rubber material reaches...

Embodiment 3

[0069] The flame-retardant and shock-absorbing EPDM vulcanizate of this embodiment is mainly prepared from the raw materials in Table 5.

[0070] The preparation method of the flame-retardant and shock-absorbing EPDM vulcanizate of the present embodiment may further comprise the steps:

[0071] (1) According to the weight of raw materials in Table 5, EPDM rubber, zinc oxide, stearic acid, antioxidant MB and other additives were added to the internal mixer and mixed for 2 minutes;

[0072] (2) Add carbon black, white carbon black, pottery clay, aluminum hydroxide, CDP, TOP, molybdenum flame retardant Charmax EXP-17, ammonium octamolybdate to the internal mixer and mix again. When it reaches 150°C, knead for another 5 minutes to remove the glue and cool down to make a mixed rubber;

[0073] (3) When a section of mixed rubber is cooled to below 60°C, it is added to the internal mixer together with sulfur and accelerators for mixing, but when the rubber material reaches above 105...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses flame-retardant shock-absorption EPDM vulcanized rubber. The flame-retardant shock-absorption EPDM vulcanized rubber is mainly prepared from the following raw materials in parts by weight: 100 parts of ethylene propylene diene monomer, 5-40 parts of an organophosphorus ester flame retardant, 20-60 parts of an inorganic flame retardant, 5-40 parts of a smoke suppression agent, 25-45 parts of a reinforcing filling agent, 6-12 parts of an active agent, 0.3-5 parts of a vulcanizing agent and 1.5-4 parts of an accelerant. A preparation method of the flame-retardant shock-absorption EPDM vulcanized rubber comprises the following steps: mixing the ethylene propylene diene monomer, the active agent and an anti-ageing agent; adding the reinforcing filling agent, the inorganic flame retardant, the organophosphorus ester flame retardant and the smoke suppression agent, and mixing to obtain a first-stage rubber compound; mixing the first-stage rubber compound with the vulcanizing agent and the accelerant, and carrying out mill run or / and triangle package hitting, so as to prepare a second-stage rubber compound; and finally vulcanizing the second-stage rubber compound, so as to obtain the flame-retardant shock-absorption EPDM vulcanized rubber. The flame-retardant shock-absorption EPDM vulcanized rubber has good flame retardance and smoke suppression effects and good physical and mechanical properties.

Description

technical field [0001] The invention relates to the field of rubber, in particular to a flame-retardant and shock-absorbing EPDM vulcanized rubber with low smoke and low toxicity and a preparation method thereof. Background technique [0002] With the rapid development of high-speed railways, people's requirements for safety are getting higher and higher, and the railway industry's requirements for train fire protection are becoming more and more stringent. And EPDM (hereinafter referred to as EPDM) is as the commonly used material in the railway industry, although it has good shock absorption and noise reduction performance, it is flammable, and there is a fire hazard unavoidably in the use process. Therefore, to improve The flame retardancy of EPDM products is imperative. [0003] At present, EPDM materials are mainly improved by adding halogen-containing flame retardants and filling a large amount of inorganic flame retardants to improve their flame-retardant properties....

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/16C08L45/02C08K13/02C08K5/09C08K3/22C08K5/523C08K3/38C08K3/24C08K5/521B29B7/28B29C35/02
CPCB29B7/28B29C35/02C08L23/16C08L2201/02C08L2201/14C08L45/02C08K13/02C08K2003/2296C08K5/09C08K2003/2227C08K5/523C08K2003/387C08K3/24C08K5/521
Inventor 谭莲影程志黄良平穆洪帅刘权朱田鑫刘伟肖程远
Owner ZHUZHOU TIMES NEW MATERIALS TECH