Low-VOC (volatile organic compound) hydroxylated acrylic resin and preparation technology thereof
A technology of hydroxyacrylic acid and resin, applied in the direction of coating, etc., can solve the problems affecting the molecular weight distribution curve, affecting the drying performance of the resin, affecting the viscosity and performance, etc., and achieve the effect of saving construction time, low production cost and low VOC
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Embodiment 1
[0018] The raw material of the low-VOC hydroxy acrylic resin is composed of the following components: A component, B component, C component and D component;
[0019] The A component includes 9 parts of xylene, 6 parts of butyl acetate, and 20 parts of polyester resin; the B component includes: 0.4 parts of acrylic acid, 0.4 parts of methacrylic acid, 14 parts of butyl acrylate, methacrylic acid hydroxyl 2 parts of ethyl ester, 40 parts of styrene, 2 parts of isobornyl acrylate, 0.3 part of di-tert-amyl peroxide, 1 part of tert-butyl peroxide, 0.3 part of dicumyl peroxide; the C and D groups Parts, all: 0.8 part of butyl acetate, 0.1 part of tert-butyl peroxide.
[0020] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:
[0021] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 160±2°C, the pressure is controlled at 0.18±0.08MPa, and it is stable for 10 minutes;
[0022] 2) Use...
Embodiment 2
[0027] The low-VOC hydroxy acrylic resin is made of the following components by weight: component A, component B, component C and component D; the component A includes 12 parts of xylene, 3 parts of butyl acetate, poly 28 parts of ester resin; the B component includes: 0.8 parts of methacrylic acid, 18 parts of butyl acrylate, 2 parts of hydroxyethyl methacrylate, 32 parts of styrene, 5 parts of isobornyl acrylate, di-tert-amyl peroxide 0.5 parts of base, 1.2 parts of tert-butyl peroxide, and 0.5 parts of dicumyl peroxide; the C and D components are both: 0.8 parts of butyl acetate and 0.1 parts of tert-butyl peroxide.
[0028] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:
[0029] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 155±2°C, the pressure is controlled at 0.16±0.08MPa, and it is stable for 20 minutes;
[0030] 2) Use a diaphragm feeding pump to add component B...
Embodiment 3
[0035] The low-VOC hydroxy acrylic resin is made of the following components by weight: component A, component B, component C and component D; the component A includes 9.5 parts of xylene, 5.5 parts of butyl acetate, poly 25 parts of ester resin; the B component includes: 0.8 parts of acrylic acid, 20 parts of butyl acrylate, 3 parts of hydroxyethyl methacrylate, 32 parts of styrene, 3.5 parts of isobornyl acrylate, 0.6 parts of di-tert-amyl peroxide 1.5 parts, 1.5 parts of tert-butyl peroxide; the C and D components are all: 0.8 parts of butyl acetate, 0.1 parts of tert-butyl peroxide.
[0036] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:
[0037] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 155±2°C, the pressure is controlled at 0.16±0.08MPa, and it is stable for 20 minutes;
[0038] 2) Use a diaphragm feeding pump to add component B dropwise for 3 hours, and contro...
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