Low-VOC (volatile organic compound) hydroxylated acrylic resin and preparation technology thereof

A technology of hydroxyacrylic acid and resin, applied in the direction of coating, etc., can solve the problems affecting the molecular weight distribution curve, affecting the drying performance of the resin, affecting the viscosity and performance, etc., and achieve the effect of saving construction time, low production cost and low VOC

Active Publication Date: 2016-11-09
WEIFANG FULE NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As people pay more and more attention to environmental protection, coatings with faster drying speed and lower VOC are increasingly becoming the first choice for home decoration or engineering decoration; solvents for coatings with lower VOC, high solid content and low viscosity Type resin is an important part in the production process of coatings; however, the resin with high solid content and low viscosity often slows down the drying due to the low molecular weight of the synthetic resin during the synthesis process; and the resin with high solid content and low viscosity is basically The high boiling point solvent used above is the reaction system, but the high boiling point solvent will affect the release of the solvent and the drying performance of the resin in the later stage, and the lower synthesis temperature and pressure in the production process will affect the molecular weight distribution curve. The molecular weight distribution is too wide, so that small molecular polymers exist, which affects the viscosity and performance; because polyester resins often have poor weather resistance, the viscosity of acrylic resins is often high, although the viscosity of acrylic resins can also be made very low, but often when the viscosity When it is low, the performance cannot meet the requirements due to the low aggregation

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The raw material of the low-VOC hydroxy acrylic resin is composed of the following components: A component, B component, C component and D component;

[0019] The A component includes 9 parts of xylene, 6 parts of butyl acetate, and 20 parts of polyester resin; the B component includes: 0.4 parts of acrylic acid, 0.4 parts of methacrylic acid, 14 parts of butyl acrylate, methacrylic acid hydroxyl 2 parts of ethyl ester, 40 parts of styrene, 2 parts of isobornyl acrylate, 0.3 part of di-tert-amyl peroxide, 1 part of tert-butyl peroxide, 0.3 part of dicumyl peroxide; the C and D groups Parts, all: 0.8 part of butyl acetate, 0.1 part of tert-butyl peroxide.

[0020] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:

[0021] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 160±2°C, the pressure is controlled at 0.18±0.08MPa, and it is stable for 10 minutes;

[0022] 2) Use...

Embodiment 2

[0027] The low-VOC hydroxy acrylic resin is made of the following components by weight: component A, component B, component C and component D; the component A includes 12 parts of xylene, 3 parts of butyl acetate, poly 28 parts of ester resin; the B component includes: 0.8 parts of methacrylic acid, 18 parts of butyl acrylate, 2 parts of hydroxyethyl methacrylate, 32 parts of styrene, 5 parts of isobornyl acrylate, di-tert-amyl peroxide 0.5 parts of base, 1.2 parts of tert-butyl peroxide, and 0.5 parts of dicumyl peroxide; the C and D components are both: 0.8 parts of butyl acetate and 0.1 parts of tert-butyl peroxide.

[0028] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:

[0029] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 155±2°C, the pressure is controlled at 0.16±0.08MPa, and it is stable for 20 minutes;

[0030] 2) Use a diaphragm feeding pump to add component B...

Embodiment 3

[0035] The low-VOC hydroxy acrylic resin is made of the following components by weight: component A, component B, component C and component D; the component A includes 9.5 parts of xylene, 5.5 parts of butyl acetate, poly 25 parts of ester resin; the B component includes: 0.8 parts of acrylic acid, 20 parts of butyl acrylate, 3 parts of hydroxyethyl methacrylate, 32 parts of styrene, 3.5 parts of isobornyl acrylate, 0.6 parts of di-tert-amyl peroxide 1.5 parts, 1.5 parts of tert-butyl peroxide; the C and D components are all: 0.8 parts of butyl acetate, 0.1 parts of tert-butyl peroxide.

[0036] This low-VOC hydroxyl acrylic resin, preparation steps are as follows:

[0037] (1) Put component A into a high-pressure reactor, fill it with nitrogen, and discharge the air. The temperature is controlled at 155±2°C, the pressure is controlled at 0.16±0.08MPa, and it is stable for 20 minutes;

[0038] 2) Use a diaphragm feeding pump to add component B dropwise for 3 hours, and contro...

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PUM

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Abstract

The invention discloses low-VOC (volatile organic compound) hydroxylated acrylic resin and a preparation technology thereof. Raw materials of the hydroxylated acrylic resin comprise a component A, a component B, a component C and a component D in parts by weight, wherein the component A comprises 7-12 parts of xylene, 3-6 parts of butyl acetate and 20-30 parts of polyester resin; the component B comprises 0-1.5 parts of acrylic acid, 0-1.5 parts of methacrylic acid, 8-22 parts of butyl acrylate, 2-4 parts of 2-hydroxyethyl methacrylate, 20-40 parts of styrene, 2-5 parts of isobornyl acrylate, 0-0.8 parts of di-tert-amyl peroxide, 0-2.0 parts of tert-butyl peroxide and 0-0.6 parts of dicumyl peroxide; each of the component C and the component D comprises 0.5-1 part of butyl acetate and 0.1-0.3 parts of tert-butyl peroxide. A product is prepared with a high pressure method. The hydroxylated acrylic resin has higher drying speed and lower VOC, the preparation technology is simple, the production cost is lower, and the application is convenient.

Description

technical field [0001] The invention relates to a hydroxy acrylic resin and a preparation process thereof, in particular to a low-VOC hydroxy acrylic resin and a preparation process thereof. Background technique [0002] As people pay more and more attention to environmental protection, coatings with faster drying speed and lower VOC are increasingly becoming the first choice for home decoration or engineering decoration; solvents for coatings with lower VOC, high solid content and low viscosity Type resin is an important part in the production process of coatings; however, the resin with high solid content and low viscosity often slows down the drying due to the low molecular weight of the synthetic resin during the synthesis process; and the resin with high solid content and low viscosity is basically The high boiling point solvent used above is the reaction system, but the high boiling point solvent will affect the release of the solvent and the drying performance of the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/02C08F220/06C08F220/18C08F220/28C08F212/08C09D151/08
CPCC09D151/08C08F283/02C08F220/281C08F220/1804
Inventor 孟祥治崔忠健张洪元刘见鹏原香锋
Owner WEIFANG FULE NEW MATERIAL CO LTD
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