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A kind of preparation method of formaldehyde removal composite fiber membrane

A composite fiber membrane, formaldehyde technology, applied in the direction of fiber chemical characteristics, rayon manufacturing, conjugated synthetic polymer rayon, etc., can solve the problems of affecting service life and antibacterial effect, easy to agglomerate, and difficult to achieve effects, etc. Achieve excellent antibacterial and formaldehyde removal performance, long-term antibacterial activity, and improve the effect of dispersibility

Active Publication Date: 2018-06-08
麦和(广州)实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The silver-loaded nanoparticle / composite fiber membrane prepared by the prior art has poor biocompatibility, and by-products are produced during the preparation process, causing the structure of the fiber membrane to be destroyed, which limits the application of the antibacterial fiber membrane
Moreover, because nano-silver is granular and the particle size is nano-level, it can only be gathered in specific parts of graphene and cannot be evenly distributed on the surface, thereby affecting the antibacterial effect; on the other hand, nano-silver and graphene cannot be tightly combined (especially When the content of nano-silver particles increases, it is easy to agglomerate), and it is easy to fall off during use, thus affecting the service life and antibacterial effect
At the same time, the existing fiber membranes have a single function, and one fiber membrane cannot meet various needs. Often, the fiber membrane materials with multiple functions are superimposed, but it is difficult to achieve the expected effect.

Method used

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  • A kind of preparation method of formaldehyde removal composite fiber membrane
  • A kind of preparation method of formaldehyde removal composite fiber membrane
  • A kind of preparation method of formaldehyde removal composite fiber membrane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030]A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0031] (1) Preparation of graphene quantum dot suspension: weigh 0.5g of C60 powder, measure 50ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, place the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 3g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30~40°C, and react for 8 hours; quickly add 200ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 30 minutes, and the laser irradiat...

Embodiment 2

[0040] A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0041] (1) Preparation of graphene quantum dot suspension: Weigh 0.7g of C60 powder, measure 80ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, place the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 2g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30-40°C, and react for 6 hours; quickly add 200ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 45 minutes, and the laser irradia...

Embodiment 3

[0050] A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0051] (1) Preparation of graphene quantum dot suspension: Weigh 0.8g of C60 powder, measure 100ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, put the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 1g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30-40°C, and react for 5 hours; quickly add 100ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 60 minutes, and the laser irradiat...

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Abstract

The invention discloses a preparation method of a formaldehyde-removing composite fiber film. The method comprises the following steps of 1, preparation of a polymer antimicrobial fiber layer, wherein 80-90 parts of micromolecule solvent is used for dissolving 10-20 parts of polymer A, antimicrobial compound dispersion liquid with the concentration of 0.01-0.1 mol / l is added dropwise under stirring at the speed of 100-300 rpm, the volume ratio of the antimicrobial compound dispersion liquid to the polymer A solution is (8-10):(1-2), stirring is continued for 30-40 min, and antimicrobial nanofibers are prepared; 2, preparation of a polymer formaldehyde-removing fiber film layer, wherein 3-8 parts of kieselguhr / porous carbon, 70-80 parts of polymer B, 0.5-2 parts of antioxidant and 10-15 parts of plasticizer are fully mixed, and formaldehyde-removing composite fibers are prepared; 3, the fiber layer prepared in the step 1 and the fiber layer prepared in the step 2 are composited into the film. According to the method, the antimicrobial fibers and the formaldehyde-removing fibers are prepared separately and then composited into the film, the composite fiber film has excellent antimicrobial and formaldehyde-removing properties under the synergistic effect of an antimicrobial compound and the kieselguhr / porous carbon, the demand for a multifunctional fiber film is met, and application of the film is further expanded.

Description

technical field [0001] The invention relates to the technical field of composite fiber membranes, in particular to a preparation method of a formaldehyde-removing composite fiber membrane. Background technique [0002] Nanofibrous membrane has the advantages of large surface area, high porosity, loose structure, pre-designed composition according to the required function, simulating extracellular matrix, and simple preparation method, and has great application potential in many fields. It has been used in food, medicine, Daily chemicals and other fields have been widely used. In particular, nanofibrous membranes prepared with natural polymers as spinning solutions not only have the above characteristics, but also have excellent biocompatibility, biodegradability and renewability. [0003] The silver-loaded nanoparticle / composite fiber membrane prepared by the prior art has poor biocompatibility, and by-products are produced during the preparation process, which causes the s...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D04H1/4374D04H1/559D04H1/593D04H1/728D01F6/92D01F1/10D01F8/06
CPCD01F1/10D01F1/103D01F6/92D01F8/06D04H1/4374D04H1/559D04H1/593D04H1/728
Inventor 陆庚
Owner 麦和(广州)实业有限公司
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