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Cladding rubber compound for sulfonated graphite reinforced printing rubber roller and preparation method of cladding rubber compound

A printing rubber roller and coating rubber technology, which is applied in the field of printing rubber rollers, can solve the problem of poor comprehensive performance of graphene oxide/polymer composite materials, poor bonding interface between graphene oxide and polymer, and easy Problems such as agglomeration occur, achieving good mechanical properties, low cost, and improving mechanical properties

Inactive Publication Date: 2016-12-07
TONGLING HONGZHENG NETWORK SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it has been found that the main problem in the process of preparing graphene oxide / polymer composites is that graphene oxide is easy to agglomerate, and the dispersion in the polymer is not uniform, and the state of the interface between graphene oxide and polymer Poor, ultimately leading to low comprehensive performance of graphene oxide / polymer composites, which limits its further industrial application

Method used

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Examples

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Effect test

Embodiment Construction

[0022] A sulfonated graphene-reinforced coating rubber compound for printing rubber rollers, which is composed of the following raw materials in parts by weight:

[0023] Toluene diisocyanate 1, graphene oxide 10, N hydroxysuccinimide 6, 1 ethyl (3 dimethylaminopropyl) carbodiimide hydrochloride 10, p-aminobenzenesulfonic acid 7, styrene 30, Potassium persulfate 0.1, lanthanum chloride 0.3, ethylenediaminetetraacetic acid 2, carbon fiber 1.7, 20% ammonia water 50, natural rubber 100, 2,2 dimethylol propionic acid 1, oxidized polyethylene wax 2, hexafluoroacetyl Acetone 0.7, polytetrahydrofuran ether glycol 2, sodium fluorosilicate 1, dodecyltrimethylammonium chloride 1, sulfur 0.8, anti-aging agent NBC 1, anti-aging agent DOD 1, sepiolite powder 11.

[0024] A kind of preparation method of the coated rubber compound of described sulfonated graphene reinforced printing rubber roller, comprises the following steps:

[0025] (1) Add the above graphene oxide to 50 times its weigh...

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PUM

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Abstract

The invention discloses a cladding rubber compound for sulfonated graphite reinforced printing rubber roller. The cladding rubber compound comprises the following raw materials in parts by weight: 1-2 parts of toluene diisocyanate, 10-14 parts of graphene oxide, 6-7 parts of N-hydroxysuccinimide, 10-12 parts of (3-dimethylaminopropyl) carbodiimide hydrochloride, 7-9 parts of p-aminobenzenesulfonic acid, 30-40 parts of styrene, 0.1-0.2 part of potassium persulfate, 0.3-0.4 part of lanthanum chloride, 2-3 parts of ethylenediaminetetraacetic acid, 1.7-2 parts of carbon fiber, 50-67 parts of 20-25% ammonia liquor, 100-130 parts of natural rubber, 1-2 parts of 2, 2-dimethylol propionic acid, 2-3 parts of oxidized polyethylene wax, 0.7-1 part of hexafluoroacetylacetone, 2-3 parts of polytetrahydrofuran ether glycol, 1-2 parts of sodium fluorosilicate,1-2 parts of dodecyl trimethyl ammonium chloride, 0.8-1 part of sulfur, 1-2 parts of an antioxidant NBC,1-2 parts of an antioxidant DOD and 11-16 parts of sepiolite powder. The rubber compound provided by the invention has the advantages of low cost, simple preparation process, good ink resistance and long service life.

Description

technical field [0001] The invention relates to the technical field of printing rubber rollers, in particular to a sulfonated graphene-reinforced coating rubber material for printing rubber rollers and a preparation method thereof. Background technique [0002] Printing rubber roller is a composite of elastic rubber and metal roller core processed by a certain process. It is widely used in various printing industries. At present, there are many problems in the quality of printing rubber rollers, such as poor wear resistance. Abrasion and holes often appear, seriously affecting the printing quality, so how to improve the abrasion resistance and mechanical properties of printing rubber rollers is very necessary; [0003] The raw material of graphene oxide is easy to get and the price is low. It is an ideal filler for polymer nanocomposites. After the discovery of unsupported graphene oxide paper and graphene / polymer conductive nanocomposites, an upsurge in the application of ...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L25/06C08K13/06C08K9/04C08K9/02C08K3/04C08K7/06C08K7/00
CPCC08K2201/011C08L7/00C08L2205/035C08L25/06C08K13/06C08K9/04C08K9/02C08K3/04C08K7/06C08K7/00
Inventor 周正红
Owner TONGLING HONGZHENG NETWORK SCI & TECH CO LTD
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