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Wear-proof vibration-resistant polypropylene composite material for inner drum of washing machine and preparation method of wear-proof vibration-resistant polypropylene composite material

The technology of composite material and polypropylene is applied in the field of wear-resistant and vibration-resistant polypropylene composite material for washing machine inner drum and its preparation field, which can solve the problems of poor wear resistance and impact resistance, poor willfulness, decreased rigidity and strength, etc. To achieve the effect of improving impact resistance, improving wear resistance and enhancing vibration resistance

Inactive Publication Date: 2017-01-04
李爱冰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polypropylene has outstanding advantages such as low density, good mechanical balance, chemical corrosion resistance, easy processing, high heat distortion temperature and low price, and has developed rapidly. Its biggest disadvantage is poor willfulness. The development of copolymerization technology, especially the advent of copolymerized polypropylene resin, has expanded the application field of polypropylene, and is widely used in washing machines and other household appliances to make various parts
However, polypropylene material has poor wear resistance and impact resistance, so it needs to be modified when it is used in the inner drum of the washing machine
The traditional modification method is to toughen polypropylene with elastomers, such as ethylene propylene rubber, POE, SBS, etc. The technology is relatively mature, but the main disadvantage is that the flow properties of the material are not good, and the rigidity and strength also decrease.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A wear-resistant and anti-vibration polypropylene composite material for the inner cylinder of a washing machine is characterized in that it is prepared from the following raw materials in parts by weight (kg): polypropylene 90, acrylic acid 20, trifluoroethyl methacrylate 15-25, Lauroyl Peroxide 3, Xylene 8, Acetone 40, PFA Resin 20, Trioctyl Citrate 5, Tricresyl Phosphate 7, N-Methylol Stearamide 4, Zinc Stearate 5, Dibasic Hard Lead fatty acid 2, Fischer-Tropsch wax 6, epoxy linseed oil 8, nano-calcium carbonate 15, hollow glass microspheres 10, graphene airgel 7, fluff powder 5, boron carbide 4, magnesium hydroxide 8, nano-diamond 6 .

[0016] A method for preparing a wear-resistant and anti-vibration polypropylene composite material for an inner cylinder of a washing machine, comprising the following steps:

[0017] (1) Add acrylic acid, trifluoroethyl methacrylate, lauroyl peroxide, xylene, and acetone to the mixer and mix, heat to 40-45°C, and then add polypropy...

Embodiment 2

[0022] A wear-resistant and anti-vibration polypropylene composite material for the inner cylinder of a washing machine, which is prepared from the following raw materials in parts by weight (kg): polypropylene 100, acrylic acid 25, trifluoroethyl methacrylate 20, lauroyl peroxide 4, Xylene 9, acetone 45, PFA resin 22.5, trioctyl citrate 6, tricresyl phosphate 8, N-methylol stearamide 5, zinc stearate 6, dibasic lead stearate 3, fee Carrier wax 7, epoxy linseed oil 9, nano calcium carbonate 17.5, hollow glass microsphere 11, graphene airgel 8, fluff powder 6, boron carbide 5, magnesium hydroxide 9, nano diamond 7.

[0023] The preparation method is the same as in Example 1.

Embodiment 3

[0025] A wear-resistant and anti-vibration polypropylene composite material for the inner cylinder of a washing machine, which is prepared from the following raw materials in parts by weight (kg): polypropylene 110, acrylic acid 30, trifluoroethyl methacrylate 25, lauroyl peroxide 5, Xylene 10, acetone 50, PFA resin 25, trioctyl citrate 7, tricresyl phosphate 9, N-methylol stearamide 6, zinc stearate 7, dibasic lead stearate 4, fee Carrier wax 8, epoxy linseed oil 10, nano calcium carbonate 20, hollow glass microsphere 12, graphene airgel 9, fluff powder 7, boron carbide 6, magnesium hydroxide 10, nano diamond 8.

[0026] The preparation method is the same as in Example 1.

[0027] The performance inspection result of the polypropylene composite material that above-mentioned embodiment 1-3 makes is shown in the table below:

[0028] The performance inspection result of the polypropylene composite material that table 1 embodiment 1-3 makes

[0029] Example 1 Exam...

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PUM

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Abstract

The invention discloses a wear-proof vibration-resistant polypropylene composite material for an inner drum of a washing machine and a preparation method of the wear-proof vibration-resistant polypropylene composite material. The composite material is prepared from, by weight, 90-110 parts of polypropylene, 20-30 parts of acrylic acid, 3-5 parts of lauroyl peroxide, 8-10 parts of dimethyl benzene, 40-50 parts of acetone, 20-25 parts of PFA (polyfluoroalkoxy) resin, 5-7 parts of trioctylcitrate, 7-9 parts of tricresyl phosphate, 4-6 parts of N-hydroxymethyl stearamide, 5-7 parts of zinc stearate, 2-4 parts of dibasic lead stearate, 6-8 parts of Fischer-Tropsch wax, 8-10 parts of epoxy flax oil, 15-20 parts of nano calcium carbonate, 10-12 parts of hollow glass beads and the like. The added PFA resin contains active groups which can react with polypropylene resin to form a network structure and increase part of flexible chains, and accordingly impact resistance of the polypropylene composite material is improved. By adoption of graft modified polypropylene such as the acrylic acid, compatibility of inorganic filler such as boron carbide to organic resin can be improved, and abrasion resistance of the composite material is improved. Due to addition of inorganic filler such as the hollow glass beads and graphene aerogel, vibration resistance of the composite material is enhanced.

Description

technical field [0001] The invention relates to a composite material, in particular to a wear-resistant and anti-vibration polypropylene composite material for an inner barrel of a washing machine and a preparation method thereof. Background technique [0002] Polypropylene has outstanding advantages such as low density, good mechanical balance, chemical corrosion resistance, easy processing, high heat distortion temperature and low price, and has developed rapidly. Its biggest disadvantage is poor willfulness. The development of copolymerization technology, especially the advent of copolymerized polypropylene resin, has expanded the application field of polypropylene, and is widely used in washing machines and other household appliances to make various components. However, polypropylene material has poor wear resistance and impact resistance, so it needs to be modified when it is used in the inner drum of the washing machine. The traditional modification method is to tough...

Claims

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Application Information

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IPC IPC(8): C08L51/06C08L27/18C08L91/00C08L91/06C08K13/04C08K3/26C08K7/28C08K7/24C08K3/38C08K3/22C08K3/04C08K5/11C08K5/523C08F255/02C08F220/06C08F220/22
CPCC08F255/02C08K2201/011C08L51/06C08L2205/02C08L2205/035C08L27/18C08L91/00C08L91/06C08K13/04C08K2003/265C08K7/28C08K7/24C08K3/38C08K2003/2224C08K3/04C08K5/11C08K5/523C08F220/06C08F220/22
Inventor 李爱冰
Owner 李爱冰
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