Unlock instant, AI-driven research and patent intelligence for your innovation.

Ionic palladium activation solution for manufacturing conductor lines on ceramics and preparation method thereof

A conductor line, palladium activation technology, applied in the field of ionic palladium activation solution and its preparation, can solve the problems of uneven conductor line thickness, uneven line, poor line integrity, etc., to achieve good adhesion and reliability, electrical performance testing Stable, good adhesion effect

Inactive Publication Date: 2017-01-04
SHANG RUIYUAN CHEM TECH
View PDF9 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, ceramics mixed with metal oxides cannot be casted well, and post-processing requires lasers with specific wavelengths and high energy, which makes the process unable to be popularized.
There are also technologies such as directly impacting copper-nickel or colloidal palladium on ceramics, but during the production process, there will be adverse conditions such as non-plating, full plating, missing plating, overflow plating, uneven wiring, and wiring bonding, which will lead to the failure of the conductor produced. The circuit has poor electrical performance, poor adhesion, breakage after heating, or even falling off; and when this technology is used, it is difficult to control the potion, so this method cannot be widely used
[0003] For example: the patent CN104561955A mentions the direct impact copper process on the ceramic substrate, which puts forward requirements on the material of the ceramic substrate. For example, ceramics such as zirconia titanate cannot meet the metallization requirements. Plating, and all non-plating, missing plating, overflow plating, resulting in uneven thickness and unevenness of conductor lines and poor bonding
[0004] For example: Patent CN 102776492 B mentions that ceramics contain functional powders, and the physical structure and electrical properties of the ceramics are changed due to the mixing of multiple components of metal oxides or other metal compounds, resulting in poor circuit integrity and affecting the electrical performance and reliability of the circuit.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Ionic palladium activation solution for manufacturing conductor lines on ceramics and preparation method thereof
  • Ionic palladium activation solution for manufacturing conductor lines on ceramics and preparation method thereof
  • Ionic palladium activation solution for manufacturing conductor lines on ceramics and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Configuration of palladium ion activation solution and working solution

[0037] (1) First, dissolve 3g of palladium sulfate in 100ml of sulfuric acid with a volume fraction of 50%, stir at 50°C at a speed of 200r / min for 1h, add deionized water to 800ml, and then add 10-100ml of methyl silane polymer carrier solution , after stirring at 50°C at 10r / min for 30min, add 1-100ml of surfactant naphthalenesulfonate solution, dilute to 1L with deionized water, stir at 50°C at 100r / min for 2-4h, then let stand for 48 The ionic palladium activation solution can be obtained within hours.

[0038] (2) Configuration of the working solution: add 200ml of deionized water to a 1L beaker, add 50ml of analytically pure sulfuric acid, stir and cool to 20°C, add 20ml of the ionic palladium activation solution prepared in step (1), and use deionized water Replenish to 1L, heat to 30°C, stir for 10 minutes, and then use.

Embodiment 2

[0040] Configuration of palladium ion activation solution and working solution

[0041] (1) First, 3g of palladium sulfate is dissolved in 100ml, 50% volume fraction of acetic acid, after stirring for 1h at 50°C with a rotating speed of 200r / min, add deionized water to 800ml, then add 10-100ml gum arabic polymer carrier solution, After stirring at 50°C at 10r / min for 30min, add 1-100ml of surfactant naphthalenesulfonate solution, dilute to 1L with deionized water, stir at 50°C at 100r / min for 2-4h, then let stand for 48 hours That is, the ionic palladium activation solution is obtained.

[0042] (2) Configuration of the working solution: add 200ml of deionized water to a 1L beaker, add 50ml of analytically pure sulfuric acid, stir and cool to 20°C, add 20ml of the ionic palladium activation solution prepared in step (1), and use deionized water Replenish to 1L, heat to 30°C, stir for 10 minutes, and then use.

Embodiment 3

[0044] Configuration of palladium ion activation solution and working solution

[0045] (1) First, dissolve 4g of palladium chloride in 100ml of succinic acid with a volume fraction of 50%, stir at 50°C at 200r / min for 1h, add deionized water to 800ml, and then add 10-100ml of carboxymethyl cellulose Sodium polymer carrier solution, stir at 50°C at 10r / min for 30min, add 1-100ml of surfactant sodium dodecylsulfonate solution, dilute to 1L with deionized water, stir at 50°C at 100r / min After 2-4 hours, let it stand for 48 hours to obtain the ionic palladium activation solution.

[0046] (2) Configuration of the working solution: add 200ml of deionized water to a 1L beaker, add 50ml of analytically pure phosphoric acid, stir and cool to 20°C, add 20ml of the ionic palladium activation solution prepared in step (1), and use deionized water Replenish to 1L, heat to 30°C, stir for 10 minutes, and then use.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
concentrationaaaaaaaaaa
Login to View More

Abstract

The invention discloses an ionic palladium activation solution for manufacturing conductor lines on ceramics and a preparation method thereof. The method comprises the following steps: (1) dissolving a preset mass of palladium salt in 100 parts by volume of pH buffer solution, stirring for 1 hour, and adding deionized water to 800 parts by volume; (2) adding 10-100 parts by volume of high-polymer carrier solution, and stirring for 30 minutes; and (3) adding 1-100 parts by volume of surfactant solution, adding deionized water to 1000 parts by volume, stirring for 2-4 hours, and standing for 48 hours to obtain the ionic palladium activation solution. The ionic palladium activation solution has the characteristics of high selectivity and no special requirements for the ceramic matrix, can be directly used for activating the laser-irradiated ceramics to finally prepare the conductor line, has the advantages of stable tested electric properties and favorable adhesive force, and can not have the problem of coating spillover, plating leakage, bubbles, shedding or the like.

Description

technical field [0001] The invention relates to the technical field of electronic appliance production, in particular to an ionic palladium activation solution for making conductor circuits on ceramics and a preparation method thereof. Background technique [0002] Ceramics not only have good heat resistance and high thermal conductivity, but most importantly, the coefficient of thermal expansion is close to that of Si and SiC. However, when making electronic appliances, ceramics have the problem of no selectivity or poor selectivity. Mask technology is required, and the process is complicated. And the circuit made is generally wider, which is not conducive to the integration of more electronic and electrical components. In the later stage, a method of mixing metal oxides on the basis of ceramics was developed to make special ceramics. However, ceramics mixed with metal oxides cannot be cast and molded well, and post-processing requires lasers with specific wavelengths and ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/18
CPCC23C18/1879
Inventor 桂祥金寿根薛荣富孙中华
Owner SHANG RUIYUAN CHEM TECH