Anhydrous nano automobile cleaning care agent
A kind of care agent and nano technology, applied in detergent compositions, detergent compounding agents, polishing compositions containing abrasives, etc. The effect of marks, excellent effect
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preparation example Construction
[0072] The preparation route of amino silicone oil:
[0073]
[0074] The preparation method of amino silicone oil:
[0075] Add octamethylcyclotetrasiloxane (D4) into a four-necked flask equipped with a condenser, a separatory funnel, a thermometer and a nitrogen protection device, seal the device, fill it with nitrogen and raise the temperature to 90-95°C, keep it warm for 1 h to remove the reaction moisture contained in the substance. A proper amount of coupling agent N-β-(aminoethyl)-Y-aminopropylmethyldimethoxysilane (N-602) was dropped into the four-necked flask using a constant pressure dropping funnel. After stirring for a certain period of time, a certain mass of KOH catalyst was added. Stir and heat up to 130-140°C, react for 6-8 hours and add end-capping agent hexamethyldisiloxane (MM). After continuing the reaction for 1 h, the temperature was lowered to 60°C, and the small molecular low boilers were distilled off under reduced pressure to obtain transparent ...
Embodiment 1
[0093] Polyhydroxy arylamine modified silicone oil:
[0094] The invention provides a polyhydroxy modified silicone oil, so that the modified anhydrous nano car cleaning and care agent provides a long-term protection function for the car surface in addition to having a strong decontamination function. .
[0095] The synthetic route of polyhydroxy arylamine is as follows:
[0096]
[0097]
[0098] The synthetic method of polyhydroxy arylamine is as follows:
[0099] 1. 2,7-dibromofluorene (1)
[0100] Put fluorene (50kg, 0.3mol) into 200L chloroform, then add 400g iron powder, stir until the organic matter dissolves, cool down to zero, take another liquid bromine (34L, 600mol) and dissolve it in 100L chloroform and slowly add it dropwise with a constant pressure body fluid funnel, Sodium hydroxide aqueous solution is used for tail gas absorption. After reacting for 6 hours, it was raised to room temperature, added 600L saturated aqueous sodium bicarbonate solution fo...
Embodiment 2
[0140] Refer to Example 1 for the synthetic route and synthetic method of polyhydroxyarylamine-modified silicone oil.
[0141] Dissolve 10 g of epoxy quaternary ammonium salt in a certain amount of isopropanol solvent, and drop it into a four-necked flask equipped with 40 g of the above-mentioned amino silicone oil (ammonia value 0.95 mmol / g) using a dropping funnel. Protected by nitrogen, the temperature was raised to 65°C with stirring, and the reaction was carried out for 8 hours. The solvent was distilled off at a vacuum degree of 0.01 MPa to obtain polyhydroxyarylamine-modified silicone oil.
[0142] Put 30g of high-carbon fatty alcohol polyoxyethylene ether into the reaction kettle, start stirring at room temperature, slowly add water under stirring until the surfactant is completely dissolved; add 20g of polyhydroxy arylamine modified silicone oil into the reaction kettle , stir to make it evenly mixed with the surfactant; add 25g of carnauba wax into the reactor, stir...
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