Silicon dioxide aerogel with high specific surface area and fast preparation method thereof
A high specific surface area, silicon dioxide technology, applied in the direction of silicon dioxide, silicon oxide, chemical instruments and methods, etc., can solve the restrictions on the popularization and use of silicon dioxide airgel, high cost of silicon dioxide airgel, nanometer Problems such as hole collapse and cracking, to achieve fast hydrolysis rate, reduce volatilization, and less solvent volatilization loss
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Embodiment 1
[0027] The method for rapidly preparing high specific surface area silica airgel of the present embodiment comprises the following steps:
[0028] (1) Cool ethyl orthosilicate, absolute ethanol, oxalic acid, ammonia, water, and n-hexane to 5°C;
[0029] (2) Mix ethyl orthosilicate, absolute ethanol, oxalic acid, and water in a constant temperature reactor at 5°C, then add ammonia water and n-hexane to mix, then let the gel stand, record the gel time, and age at 5°C for 8 hours ; The molar ratio of tetraethyl orthosilicate, absolute ethanol, oxalic acid, water, ammonia water and n-hexane is 1:18:0.005:4:0.005:0.2;
[0030] (3) Transfer the aged gel into ethylene glycol dimethyl ether, and change the liquid at 25° C. for 2 hours;
[0031] (4) Perform supercritical drying on the gel after solvent exchange, and dry it with supercritical carbon dioxide at 70° C. and 19 MPa for 6 hours to obtain silica airgel, and measure its specific surface area.
Embodiment 2
[0033] The method for rapidly preparing high specific surface area silica airgel of the present embodiment comprises the following steps:
[0034] (1) Cool ethyl orthosilicate, absolute ethanol, oxalic acid, ammonia, water, and n-hexane to 5°C;
[0035] (2) Mix ethyl orthosilicate, absolute ethanol, oxalic acid, and water in a constant temperature reactor at 5°C, then add ammonia water and n-hexane to mix, then let the gel stand, record the gel time, and age at 5°C for 8 hours ; The molar ratio of tetraethyl orthosilicate, absolute ethanol, oxalic acid, water, ammonia water and n-hexane is 1:18:0.005:4:0.005:0.5;
[0036] (3) Transfer the aged gel into ethylene glycol dimethyl ether, and change the liquid at 25° C. for 2 hours;
[0037] (4) Perform supercritical drying on the gel after solvent exchange, and dry it with supercritical carbon dioxide at 70° C. and 19 MPa for 6 hours to obtain silica airgel, and measure its specific surface area.
Embodiment 3
[0039] The method for rapidly preparing high specific surface area silica airgel of the present embodiment comprises the following steps:
[0040] (1) Cool tetraethyl orthosilicate, methanol, nitric acid, ammonium carbonate buffer, water, and n-hexane to 1°C;
[0041] (2) Mix ethyl orthosilicate, methanol, nitric acid, and water in a constant temperature reactor at 1°C, then add ammonium carbonate buffer and n-hexane to mix, then let the gel stand, record the gel time, and age at 1°C 8h; the molar ratio of ethyl orthosilicate, absolute ethanol, nitric acid, water, ammonium carbonate buffer and n-hexane is 1:20:0.01:2:0.01:0.3;
[0042] (3) Transfer the aged gel into ethylene glycol dimethyl ether, and change the liquid at 15° C. for 3 hours;
[0043] (4) Perform supercritical drying on the gel after solvent exchange, and dry it with supercritical carbon dioxide at 70° C. and 19 MPa for 6 hours to obtain silica airgel, and measure its specific surface area.
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