Resin for polyurethane shoe sole, preparation method and application

A polyurethane resin and polyurethane technology are applied in the fields of polyurethane sole resin and preparation and application, and can solve the problem of high production cost

Active Publication Date: 2021-07-06
ZHEJIANG HUAFON NEW MATERIALS CO LTD
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For polyurethane shoe sole manufacturers, it is necessary to be equipped with raw materials of different types and specifications to meet the production of soles with different performance requirements, and each time the raw materials are replaced, the proofing machine and the material tank need to be cleaned, and the production cost is high.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Resin for polyurethane shoe sole, preparation method and application
  • Resin for polyurethane shoe sole, preparation method and application
  • Resin for polyurethane shoe sole, preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] The polyethylene adipate glycol of 50kg (the number average molecular weight is 1000), the polyethylene adipate diethylene glycol ester glycol of 50kg (the number average molecular weight is 1000), the ethylene glycol of 0.50kg , the 1,4-butanediol of 0.50kg, the ethylene glycol solution of the triethylenediamine of 0.25kg, the double (dimethylaminoethyl) ether of 0.75kg 70wt% and 30wt% dipropylene glycol The solution, 0.10kg of water and 0.30kg of silicone foam stabilizer were reacted at 50°C for 2.5h, cooled to 40°C, and mixed for 1.5h to obtain component A of polyurethane resin.

[0052] With the diphenylmethane diisocyanate of 22.5g, the carbodiimide modified diphenylmethane diisocyanate of 7.45kg, the polyethylene adipate diol (number average molecular weight is 1000) of 0.374kg and 0.0010kg Phosphoric acid was reacted at 65°C for 3 hours to obtain component B1 of polyurethane resin.

[0053] React 2.24kg of diphenylmethane diisocyanate, 1.12kg of polyethylene adi...

Embodiment 2

[0056] The polyethylene adipate glycol of 50kg (the number average molecular weight is 1000), the polyethylene adipate diethylene glycol ester glycol of 50kg (the number average molecular weight is 1000), the ethylene glycol of 0.50kg , the 1,4-butanediol of 0.50kg, the ethylene glycol solution of the triethylenediamine of 0.25kg, the double (dimethylaminoethyl) ether of 0.75kg 70wt% and 30wt% dipropylene glycol The solution, 0.10kg of water and 0.30kg of silicone foam stabilizer were reacted at 50°C for 2.5h, cooled to 40°C, and mixed for 1.5h to obtain component A of polyurethane resin.

[0057] With the diphenylmethane diisocyanate of 3.68kg, the carbodiimide modified diphenylmethane diisocyanate of 1.23kg, the polyethylene adipate diol (number average molecular weight is 1000) of 0.06kg and 0.0002kg Phosphoric acid was reacted at 65°C for 3 hours to obtain component B1 of polyurethane resin.

[0058] React 29.8kg of diphenylmethane diisocyanate, 14.9kg of polyethylene adipa...

Embodiment 3

[0061] The polyethylene adipate glycol of 60kg (the number average molecular weight is 2000), the polyethylene adipate diethylene glycol ester glycol of 40kg (the number average molecular weight is 2000), the ethylene glycol of 5.20kg , 4.80kg of 1,4-butanediol, 0.75kg of triethylenediamine ethylene glycol solution, 0.75kg of 70wt% bis(dimethylaminoethyl) ether and 30wt% dipropylene glycol The solution, 0.50kg of water and 0.70kg of silicone foam stabilizer were reacted at 60°C for 1.5h, then cooled to 45°C and mixed for 1.0h to obtain component A of polyurethane resin.

[0062] With the diphenylmethane diisocyanate of 7.48kg, the carbodiimide modified diphenylmethane diisocyanate of 1.87kg, the polyethylene adipate diethylene glycol ester diol of 1.87kg (the number average molecular weight is 2000 ) and 0.002kg of phosphoric acid were reacted at 75°C for 2 hours to obtain the polyurethane resin component B1.

[0063] React 53.1kg of diphenylmethane diisocyanate, 47.9kg of po...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a resin for polyurethane shoe soles and its preparation method and application. The resin comprises resin A component, resin B1 component and resin B2 component, and the resin A component includes polypolyol A, a crosslinking agent and a catalyst , Foaming agent and foam stabilizer; Resin B1 includes 100 parts of isocyanate B1, 10-40 parts of polypolyol B1, 0.002-0.010 parts of side reaction inhibitor, resin B2 includes 100 parts of isocyanate B2, 50-100 parts of polypolyol B2 Parts, side reaction inhibitor 0.002 ~ 0.010 parts, isocyanate B1 is diphenylmethane diisocyanate, carbodiimide modified diphenylmethane diisocyanate, toluene diisocyanate or naphthalene diisocyanate, polypolyol B1 is polyhexamethylene diisocyanate Acid-based polyester polyol, isocyanate B2 is diphenylmethane diisocyanate, carbodiimide modified diphenylmethane diisocyanate, toluene diisocyanate or naphthalene diisocyanate, polypolyol B2 is polyadipate terephthalate Formic acid polyester polyol. The invention can prepare polyurethane shoe soles with different hardness, and the cost is low.

Description

technical field [0001] The invention relates to a resin for polyurethane shoe soles, a preparation method and application. Background technique [0002] The full name of polyurethane is polyurethane, which is a general term for macromolecular compounds containing repeated urethane groups on the main chain. It is a polymer compound obtained by the interaction of binary or polyvalent organic isocyanates and polyol compounds. The polyurethane sole has the characteristics of light weight and good resilience. [0003] The resin used to produce polyurethane soles is generally a two-component raw material - a polyol mixture and a prepolymer (referred to as AB material / AB component or black and white material). [0004] Polyurethane soles with different performance requirements need to be used with different types of AB materials. For polyurethane sole manufacturers, it is necessary to be equipped with various raw materials of different types and specifications to meet the product...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/42C08G18/66C08G18/76C08G18/32
CPCC08G18/3206C08G18/4202C08G18/4211C08G18/4238C08G18/664C08G18/7671
Inventor 赵叶宝林剑薛晓金何永吴章兴陈一帆
Owner ZHEJIANG HUAFON NEW MATERIALS CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap