A kind of silicon-containing reactive flame-retardant nylon resin and preparation method thereof

A reactive flame retardant, nylon resin technology, applied in the field of silicon-containing flame retardant nylon resin and its preparation, can solve the problems of affecting the application range of materials, affecting mechanical properties, low flame retardant efficiency, etc., and achieving good industrial application prospects, Good mechanical properties and high flame retardant efficiency

A reactive flame retardant, nylon resin technology, applied in the field of silicon-containing flame retardant nylon resin and its preparation, can solve the problems of affecting the application range of materials, affecting mechanical properties, low flame retardant efficiency, etc., and achieving good industrial application prospects, Good mechanical properties and high flame retardant efficiency

CN106700067BActive Publication Date: 2019-05-03ZHUZHOU TIMES NEW MATERIALS TECH

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  • A kind of silicon-containing reactive flame-retardant nylon resin and preparation method thereof
  • A kind of silicon-containing reactive flame-retardant nylon resin and preparation method thereof
  • A kind of silicon-containing reactive flame-retardant nylon resin and preparation method thereof

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Embodiment

[0032] A preparation method of the silicon-containing reactive flame-retardant nylon resin of the present invention comprises the following steps:

[0033] (1) The reactive phosphorus-containing flame retardant containing two carboxyl groups is mixed with amino silicone oil in a molar ratio of 1:1;

[0034] (2) Add the mixed reactive phosphorus-containing flame retardant and amino silicone oil into the autoclave, and simultaneously add nylon polymerized monomer and catalyst (the amount of catalyst is 4% of the mass of nylon polymerized monomer), close the feeding cap, Repeat three times to replace the air in the autoclave with nitrogen;

[0035] (3) Heating the high-pressure reactor filled with materials, so that the temperature reaches 200°C-280°C, and the pressure of the kettle is 0.2Mpa-2.0Mpa, and the reaction is 2-6h;

[0036] (4) Open the pressure relief valve, slowly reduce the high-pressure reactor to normal pressure, stop for 30 minutes and then vacuumize for 3 to 15...

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Abstract

Silicon-containing reactive flame retardant nylon resin and a preparation method thereof are disclosed. The preparation method comprises the following steps: a phosphorus-containing reactive flame retardant with two end carboxyl groups is mixed with amino silicone oil to obtain a mixture; the obtained mixture, a nylon monomer and a catalyst are mixed in a certain ratio into a material, and after polymerization reaction of the material, the silicon-containing reactive flame retardant nylon resin can be obtained. The silicon-containing reactive flame retardant nylon resin has permanent flame retardant property, the flame retardant grade reaches to UL94V-0, the oxygen index is 25-45, and the product has the advantages of good mechanical properties, high oxygen index, high flame retardant grade and better adaptability, and the like.

Description

technical field [0001] The invention relates to a flame-retardant nylon resin and a preparation method thereof, in particular to a silicon-containing flame-retardant nylon resin and a preparation method thereof. Background technique [0002] With its excellent mechanical properties, friction resistance, heat resistance, electrical insulation and weather resistance, nylon is widely used in textile fibers, automobiles, electronic appliances, construction machinery and other fields. Compared with general polyolefins, nylon has low melt strength and drips during combustion, which increases the risk of fire transmission and endangers the safety of human production and life. The flame retardant advantage of nylon is that its molecules contain heteroatoms such as nitrogen and oxygen, and its combustion calorific value and flammability are lower than those of polyolefins, and the presence of heteroatoms reacts strongly with phosphorus and silicon-based flame retardants. Can play th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

Patent Timeline
03 May 2019
Publication
CN106700067B
IPC
C08G69/42; C08G69/16; C08G69/08; C08G77/455
Inventors
王文志; 彭军