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Thermoplastic resin composition and adhesive prepared from same, insulation adhesive film used for laminated bus bar and preparation method of insulation adhesive film

A thermoplastic resin, insulating film technology, applied in the direction of adhesives, insulators, adhesive types, etc., can solve the problems of decreased fluidity and wettability, decreased performance of insulating films, decreased yield of finished products, etc., to achieve excellent bonding performance , Excellent high and low temperature bonding performance, the effect of meeting the requirements of low temperature pressing

Inactive Publication Date: 2017-05-24
GUANGDONG SHENGYI SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Adding a curing agent makes the saturated polyester resin form a partially cross-linked network structure, which can certainly improve the high-temperature bonding performance of the saturated polyester adhesive, but the saturated polyester adhesive forms a partially cross-linked network structure before pressing, although the overall retention Thermoplastic, but it has formed a certain three-dimensional network structure, has no obvious melting point, and the fluidity and wettability at high temperatures are also greatly reduced. Generally, it needs to be pressed above 150°C to achieve effective bonding.
An increase in the pressing temperature will not only increase energy consumption, but also cause a decrease in the performance of the insulating film when pressing for a long time at high temperature
In addition, as the structure of laminated busbars becomes more and more complex, in many cases, multiple high-temperature pressing is required to form, and too high pressing temperature will lead to a decrease in the qualified rate of finished products

Method used

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  • Thermoplastic resin composition and adhesive prepared from same, insulation adhesive film used for laminated bus bar and preparation method of insulation adhesive film
  • Thermoplastic resin composition and adhesive prepared from same, insulation adhesive film used for laminated bus bar and preparation method of insulation adhesive film
  • Thermoplastic resin composition and adhesive prepared from same, insulation adhesive film used for laminated bus bar and preparation method of insulation adhesive film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A thermoplastic resin composition, comprising 55 parts of polyester polyurethane calculated in parts by mass, 20 parts of saturated polyester resin (L952), 1 part of reactive compatibilizer, 30 parts of antimony trioxide, decabromodiphenyl 55 parts of ethane, 8 parts of aluminum hydroxide, 0.3 parts of antioxidant.

[0030] The thermoplastic resin composition is applied to an insulating adhesive film for a laminated busbar.

[0031] The preparation method of the insulating adhesive film for laminated busbars containing thermoplastic resin composition: first use acetone to adjust the composition of polyester polyurethane, saturated polyester resin, reactive compatibilizer, antimony trioxide, decabromodiphenyl A liquid dispersion (solid content 35%) composed of ethane, aluminum hydroxide, and an antioxidant is mixed to make an adhesive.

[0032] like figure 1 As shown, the adhesive is coated on one side with a coating machine on a PET insulating film 10 with a thickness...

Embodiment 2

[0036] A thermoplastic resin composition, comprising 63 parts by mass of polyether polyurethane, 13 parts of saturated polyester resin (S1611), 2.4 parts of non-reactive compatibilizer, 21 parts of antimony pentoxide, ethylene bis 40 parts of tetrabromophthalimide, 9 parts of magnesium hydroxide, and 0.6 parts of antioxidant.

[0037] The thermoplastic resin composition is applied to the laminated busbar insulation adhesive film.

[0038] The preparation method of the insulating adhesive film for the laminated busbar containing the thermoplastic resin composition: first use butanone to adjust the polyether polyurethane, saturated polyester resin, non-reactive compatibilizer, antimony pentoxide, ethylene A liquid dispersion (solid content: 48%) composed of bis-tetrabromophthalimide, magnesium hydroxide and an antioxidant is mixed into an adhesive.

[0039] like figure 2 As shown, the adhesive is coated on both sides of the PBT insulating film 10' with a thickness of 175 μm w...

Embodiment 3

[0043] A thermoplastic resin composition, comprising 70 parts by mass of polyether polyurethane, 8 parts of saturated polyester resin (ES120), 7 parts of non-reactive compatibilizer, 18 parts of antimony trioxide, tetrabromobis 38 parts of phenol A, 12 parts of magnesium hydroxide, 0.8 parts of antioxidant.

[0044] The thermoplastic resin composition is used for an insulating adhesive film for a laminated busbar.

[0045] The preparation method of the insulating adhesive film for laminated busbars containing thermoplastic resin composition: first use dimethylformamide to adjust the polyether polyurethane, saturated polyester resin, non-reactive compatibilizer, antimony trioxide , Tetrabromobisphenol A, magnesium hydroxide, and an antioxidant liquid dispersion (solid content is 48%), mixed into an adhesive.

[0046] Then use a coating machine to coat the adhesive on a PEN insulating film with a thickness of 100 μm on one side, and the coating thickness is 40 μm;

[0047] The...

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Abstract

The invention provides a thermoplastic resin composition. The thermoplastic resin composition comprises the following components in parts by mass: 50-85 parts of thermoplastic polyurethane resin, 5-20 parts of saturated polyester resin, 0.5-8 parts of a compatilizer, 0.1-1 part of an antioxidant and 20-100 parts of a flame retardant, wherein the thermoplastic polyurethane resin has excellent flexibility and high and low temperature resistance; and the saturated polyester resin has low melting point, poor high temperature resistance, good aging property and excellent adhesive property with metal and an insulation film. The thermoplastic polyurethane resin and the saturated polyester resin are blended and modified, a small amount of the compatilizer is added, polymer alloy with excellent compatibility can be obtained, and the polymer alloy has good high and low temperature impact property, aging property and adhesive property. The resin composition does not contain a curing agent, has good high temperature liquidity and can meet low temperature lamination requirements. The invention also provides an adhesive made by adopting the thermoplastic resin composition, an insulation adhesive film used for a laminated bus bar and a preparation method of the insulation adhesive film.

Description

technical field [0001] The invention relates to the field of insulating adhesive films for laminated busbars, in particular to a thermoplastic resin composition and an adhesive prepared therefrom, an insulating adhesive film for laminated busbars, and a method for preparing the insulating adhesive film. Background technique [0002] Laminated busbars are also called composite busbars, laminated busbars, composite copper bars, composite busbars, etc., and the English name is Laminated Busbar. It is mainly based on the electromagnetic theory, and the wide and thin copper bar is hot-pressed with a very thin insulating material. The opposite current passes through the adjacent wires, and the magnetic fields cancel each other, which can reduce the parasitic inductance. As the bonding between the conductors in the laminated busbar and the insulating film of the insulating material, its performance has a crucial impact on the safety and reliability of the laminated busbar. The ins...

Claims

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Application Information

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IPC IPC(8): C08L75/06C08L75/08C08L63/00C08L67/00C08K13/02C08K5/03C08K3/22C08K5/3415C08K5/136C09J175/06C09J175/08C09J167/00C09J11/06C09J11/04C09J7/02H01B17/62
CPCC08L75/06C08L75/08C08L2201/02C08L2201/08C08L2203/20C08L2205/03C08L2205/035C08L2205/08C09J7/22C09J7/30C09J11/04C09J11/06C09J175/06C09J175/08C09J2203/326C09J2301/122C09J2301/30C09J2301/408H01B17/62C08L67/00C08K13/02C08K3/2279C08K5/03C08K2003/2227C08K5/3415C08K2003/2224C08K5/136C08L63/00
Inventor 左陈茹敬宏伍宏奎蒋媚媚
Owner GUANGDONG SHENGYI SCI TECH
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