Sintered ceramsite and method prepared from phosphorus tailings as main raw material

A technology of main raw material, phosphorus tailings, applied in the field of building materials, can solve the problem of small proportion of solid waste ceramsite, and achieve the effects of avoiding energy consumption, good water resistance, and avoiding dust pollution

Active Publication Date: 2019-11-08
HUBEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the currently disclosed technical solutions, the main raw materials for preparing ceramsite are mostly diatomite (Zhang Ruoyu, 2004), glass waste, red mud, boron mud, quartz sand tailings, etc. (Yin Guoxun, 2008, Xu Xiaohong, 2003, Wu Shengbiao, 2004 , Jin Yiying, 2009), but the proportion of solid waste ceramsite is relatively small at present, and there is an urgent need to develop a large amount of solid waste ceramsite production and application, and there are few reports on the use of phosphorus tailings to prepare sintered ceramsite, which is environmentally friendly and sustainable. The meaning of development

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1) Raw material pretreatment: crush 60 parts by mass of phosphorus tailings and 20 parts of steel slag to 5-20 mm, add 10 parts of fly ash, and then add 40 parts of water for wet grinding until the median particle size is less than 5 μm slurry;

[0033] 2) Forming and granulation: put the wet grinding slurry obtained in step 1) into a granulator with 5 parts by mass of clay and 5 parts by mass of carbon powder to obtain raw meal balls;

[0034] 3) Naturally dry the raw meal balls obtained in step 2) at room temperature for 6-8 hours, and then place the naturally-dried raw meal balls in an electric constant temperature blast drying oven at a constant temperature of 100-120°C for 8-10 hours, Get semi-finished balls;

[0035] 4) Place the semi-finished balls dried and aged in step 3) under the preheating zone of the rotary kiln, the temperature gradient of the preheating and drying zone is 600-650°C, and the preheating and drying gradual time is 40 minutes to obtain finis...

Embodiment 2

[0039] Embodiment 2, with embodiment 1, the difference is,

[0040] 1) Raw material pretreatment: crush 50 parts by mass of phosphorus tailings and 17 parts of steel slag to 5-20 mm, add 20 parts of fly ash, and then add 34 parts of water for wet grinding until the median particle size is less than 5 μm slurry;

[0041] 2) Forming and granulation: put the wet grinding slurry obtained in step 1) into a granulator with 5 parts by mass of shale and 8 parts by mass of carbon powder to obtain raw pellets;

[0042] 4) Place the semi-finished balls dried and aged in step 3) under the preheating zone of the rotary kiln, the temperature gradient of the preheating drying zone is 660-710°C, and the preheating and drying gradual time is 38 minutes to obtain finished balls;

[0043] 5) The finished ball obtained in step 4) is placed in the high temperature zone of the rotary kiln for calcination, the temperature gradient of the high temperature zone is 1170-1200° C., and the holding time ...

Embodiment 3

[0045] Embodiment 3, with embodiment 1, the difference is,

[0046] 1) Raw material pretreatment: crush 50 parts by mass of phosphorus tailings and 23 parts of steel slag to 5-20 mm, add 15 parts of fly ash, and then add 36 parts of water for wet grinding until the median particle size is less than 5 μm slurry;

[0047] 2) Forming and granulation: Put the wet grinding slurry obtained in step 1) into the granulator to obtain raw pellets by adding 2 parts by mass of clay, 3 parts of shale, and 7 parts of carbon powder;

[0048] 4) Place the semi-finished balls dried and aged in step 3) under the preheating zone of the rotary kiln, the temperature gradient of the preheating drying zone is 710-750°C, and the preheating and drying gradual time is 36 minutes to obtain finished balls;

[0049] 5) The finished ball obtained in step 4) is calcined in a high temperature zone of a rotary kiln, the temperature gradient of the high temperature zone is 1190-1210° C., and the holding time i...

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Abstract

The invention discloses a method for preparing sintered ceramsite by using phosphate tailings as a main raw material. The method comprises the following steps of crushing the phosphate tailings and steel slag, then adding pulverized fuel ash into an obtained first mixture, and afterwards, adding water into an obtained second mixture to carry out wet grinding, so as to obtain slurry of which the median particle size is less than 5 microns; adding a binder and carbon powder into the slurry, putting an obtained third mixture into a granulator to obtain a raw-material ball; naturally drying the raw-material ball for 6h to 8h at a room temperature, placing the raw-material ball in an electric heating constant-temperature blast drying box, and carrying out constant-temperature drying and aging for 8h to 10h, so as to obtain a semi-finished-product ball; placing the semi-finished-product ball at a preheating zone of a rotary kiln, and preheating the semi-finished-product ball for 30min to 40min at 600 to 850 DEG C, so as to obtain a finished-product ball; placing the finished-product ball at a high-temperature zone of the rotary kiln, calcining the finished-product ball at 1,140 to 1,250 DEG C for 40min to 80min, and then naturally cooling the finished-product ball to the room temperature to subsequently obtain the sintered ceramsite. According to the sintered ceramsite and the method, the potential activity of raw materials is sufficiently excited by adopting the wet grinding; the mill-dust pollution generated during oven drying and dry drying is avoided; the environmental pollution and the resource waste of the stockpiling of the phosphate tailing are reduced to a great extent; the sintered ceramsite prepared by the method has water resistance, high strength, heat resistance and fire resistance, and can be widely used for building structure and landscape.

Description

technical field [0001] The invention belongs to the technical field of building materials, and in particular relates to a method for preparing sintered ceramsite with phosphorus tailings as the main raw material. Background technique [0002] Phosphate rock flotation produces a large amount of tailings, which need to occupy a large amount of land. Due to the large amount of these tailings, when the tailings are corroded or the migratable elements in the tailings undergo chemical migration, they will have a negative impact on the atmosphere and Water and soil cause serious pollution, and lead to soil degradation, vegetation destruction and even a direct threat to the lives of humans and animals. Tailings ponds include tailings dams, reservoir areas, etc., and are the main part of tailings facilities. In the construction of mine production facilities, the investment in tailings facilities is relatively large, generally accounting for about 5% to 10% of the total investment in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B38/06C04B33/132C04B33/138C04B33/135C04B33/04
CPCC04B33/04C04B33/132C04B33/1352C04B33/138C04B38/068C04B2235/77C04B2235/96Y02P40/60
Inventor 苏英邱慧琼贺行洋王迎斌叶青兰蒙刘雨轩王庭苇郑正旗
Owner HUBEI UNIV OF TECH
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