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Method for preparing aqueous coating with automatic cleaning function

A water-based coating and self-cleaning technology, applied in the direction of coating, etc., can solve the problems of high construction environment requirements, environmental and human hazards, poor self-cleaning effect, etc., so as not to be easily polluted, reduce pollution, and have strong adhesion Effect

Inactive Publication Date: 2017-06-13
DALIAN BETRUST ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the actual application of polyurethane-based coatings, there are a series of problems such as high requirements on the construction environment, easy peeling of the paint film, and serious harm to the environment and human body caused by the necessary benzene-containing substances in the additives. Therefore, at present, the use of water-based coatings is advocated in the coating field. as an alternative to polyurethane-based coatings
In the prior art, the existing self-cleaning water-based paint is coated with nano-titanium dioxide in the polymer by emulsion polymerization, but the water-based paint obtained by this method is hydrophilic after the surface is coated, and the self-cleaning effect is poor.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Mix ammonium fluoride with a concentration of 1wt% and ethylene glycol according to a volume ratio of 1:5 to prepare an electrolyte; a volume concentration of 25vt% orthosilicate ethanol solution and a volume concentration of 15vt% hydrochloric acid solution according to a volume ratio of 1: 1.5 Mix evenly to prepare a modified solution; take high-purity titanium flakes and carry out anodic oxidation in the electrolyte, the oxidation voltage is 65V, oxidize for 10 hours, rinse the titanium flakes with a large amount of deionized water, and put titanium dioxide nanotubes in the modified Soak in the liquid for 2-3 hours, and dry naturally to obtain modified titanium dioxide nanotubes.

Embodiment 2

[0014] The water-based paint is made of the following raw materials by weight: 50g water, 15g polyvinyl alcohol, 20g acrylic resin, 5g dioctyl phthalate, 15g modified titanium dioxide nanotubes, 1g silicone defoamer, 12g triethanolamine, 0.5 g silane coupling agent KH570, 0.1 g sodium lauryl sulfate.

[0015] The preparation method of the water-based paint with automatic cleaning function is: first heat and melt the acrylic resin, slowly add polyvinyl alcohol, and stir for 30 minutes. min, after stirring for 0.5 hours, add silicone defoamer, stir for 0.5 hours, cool down to 50°C, add sodium lauryl sulfate and dioctyl phthalate, continue stirring for 1 hour, stop stirring, Add modified titanium dioxide nanotubes into the reaction kettle, after ultrasonic vibration for 1.5 hours, raise the temperature of the reaction kettle to 75°C for 2 hours, then add triethanolamine and silane coupling agent KH570, keep the temperature for 5 hours, close the reaction kettle to obtain the wate...

Embodiment 3

[0017] The water-based paint is made from the following raw materials by weight: 55g water, 20g polyvinyl alcohol, 21g acrylic resin, 6g dioctyl phthalate, 13g modified titanium dioxide nanotubes, 1.5g silicone defoamer, 11g triethanolamine, 0.3g silane coupling agent KH570, 0.4g sodium lauryl sulfate.

[0018] The preparation method of the water-based paint with automatic cleaning function is as follows: first heat and melt the acrylic resin, slowly add polyvinyl alcohol, stir for 25 minutes, after mixing evenly, add water into the stirring tank and heat to 90°C, the stirring speed is 500r / min, after stirring for 1 hour, add silicone defoamer, stir for 0.5 hours, cool down to 45°C, add sodium lauryl sulfate and dioctyl phthalate, continue stirring for 1 hour, stop stirring, Add modified titanium dioxide nanotubes into the reaction kettle, and after ultrasonic vibration for 1 hour, raise the temperature of the reaction kettle to 75°C for 2 hours, then add triethanolamine and ...

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Abstract

The invention relates to the field of aqueous coatings, and in particular relates to a method for preparing an aqueous coating with an automatic cleaning function. The aqueous coating is prepared from the following raw materials in parts by weight: 50-55 parts of water, 15-25 parts of polyvinyl alcohol, 20-23 parts of acrylic acid resin, 5-8 parts of dioctyl phthalate, 10-15 parts of modified titanium dioxide nanotubes, 1-5 parts of an organic silicon defoaming agent, 10-12 parts of triethanolamine, 0.2-0.5 part of a silane coupling agent KH570 and 0.1-0.5 part of lauryl sodium sulfate. The aqueous coating provided by the invention has a self-cleaning function, is easy to clean, is capable of adsorbing toxic and harmful gases adhered to the surface of the coating under the action of photocatalysis, is high in photocatalysis, long in service life and good in adhesion property, and environment pollution can be reduced. The aqueous coating is only prepared from alcoholic solvents with very low toxicity, process environment conditions can be improved, and the aqueous coating is simple in preparation method, wide in application range and applicable to popularization and large-scale production.

Description

technical field [0001] The invention belongs to the field of water-based paint, and in particular relates to a preparation method of a water-based paint with automatic cleaning function. Background technique [0002] Self-cleaning materials have been widely used in construction, glass, vehicles, fibers and other fields. Due to their good hydrophobic properties, self-cleaning materials can prevent the surface from being contaminated with dirt, and have the advantages of being green and environmentally friendly. Most of the self-cleaning coatings in the prior art are polyurethane-based coatings, and the purpose of self-cleaning is achieved by adding modifiers and anti-ultraviolet UV curing groups in the matrix. However, in the actual application of polyurethane-based coatings, there are a series of problems such as high requirements on the construction environment, easy peeling of the paint film, and serious harm to the environment and human body caused by the necessary benzen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/00C09D129/04C09D7/00C09D7/12
CPCC09D133/00C08K2201/011C09D7/20C09D7/70C09D129/04C08L29/04C08K13/06C08K9/06C08K9/04C08K9/02C08K7/24C08L33/00
Inventor 唐洪林邓金玲
Owner DALIAN BETRUST ENVIRONMENTAL PROTECTION TECH CO LTD