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Praseodymium-neodymium-iron alloy and preparation method thereof

A ferroalloy, praseodymium neodymium iron technology, applied in the field of praseodymium neodymium ferroalloy and its preparation, can solve the problems of high local concentration of rare earth metals, affecting product consistency, high requirements for melting temperature, etc., to achieve broad development and market prospects, low praseodymium neodymium content control, high product quality

Inactive Publication Date: 2017-06-13
BAOTOU RES INST OF RARE EARTHS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is the method commonly used at present, and its process technology is simple, can make multi-element master alloy or application alloy, but also has deficiency: 1) rare earth metal easily local concentration is too high in molten iron, produces segregation; 2) this method The raw materials used are rare earth metals, especially for medium and heavy rare earth metals, the preparation process is complicated and the cost is high; 3) The melting temperature is relatively high. Since rare earth metals and pure iron are used as raw materials, the melting temperature requirements are high
This method has low production cost and simple process, but it also has the following defects: the distribution of rare earth and iron in the alloy fluctuates greatly, it is difficult to control, and the distribution error is as high as 3%-5%, which affects product consistency

Method used

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  • Praseodymium-neodymium-iron alloy and preparation method thereof
  • Praseodymium-neodymium-iron alloy and preparation method thereof

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preparation example Construction

[0036] The preparation process of the praseodymium neodymium iron alloy for producing rare earth steel comprises the following steps:

[0037] Step 1: Graphite is used as the electrolytic cell, the graphite plate is used as the anode, the iron rod is used as the self-consumable cathode, and there is a receiver containing the alloy under the cathode;

[0038] The material of the receiver can be one of iron, rare earth oxide, and boron nitride.

[0039] Step 2: In the fluoride molten salt electrolyte system of praseodymium neodymium fluoride (a mixture of praseodymium fluoride and neodymium fluoride) and lithium fluoride, using praseodymium neodymium oxide (a mixture of praseodymium oxide and neodymium oxide) as the electrolytic raw material, through Enter direct current electrolysis to obtain praseodymium neodymium iron master alloy;

[0040] Step 3: Using the praseodymium-neodymium-iron master alloy and iron as raw materials, a fusion method is used to prepare the praseodymiu...

Embodiment 1

[0047] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The praseodymium and neodymium fluoride in the electrolyte is 85wt%, and the lithium fluoride is 15wt%. The cathode is a 70mm pure iron rod. The average current intensity is 4500A, and the anode current density is 0.8 -1.0A / cm 2, cathode current density 6-9A / cm 2 , the electrolysis temperature is maintained at 900-1000 ℃, continuous electrolysis for 360 hours, 3046 kg of praseodymium neodymium oxide is consumed, and 2710 kg of praseodymium neodymium iron alloy is obtained, the average praseodymium neodymium content is 90.5%, the current efficiency is 85%, and the rare earth yield is 94%. The composition results are shown in Table 1.

[0048] Table 1 Composition analysis results of praseodymium-neodymium-iron master alloy / wt%

[0049] RE Fe C O P S Si mn 90.5 9.25 0.0085 0.0094 <0.01 <0.005 0.011 <0.005

[0050] Using the praseodymium...

Embodiment 2

[0054] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The electrolyte contains 85wt% praseodymium neodymium fluoride and 15wt% lithium fluoride. The cathode is a 70mm pure iron rod. The average current intensity is 4000A and the anode current density is 0.8 -1.2A / cm 2 , cathode current density 5-8A / cm 2 , the electrolysis temperature is maintained at 950-1050 ℃, continuous electrolysis for 240 hours, 1805 kg of praseodymium neodymium oxide is consumed, and 1803 kg of praseodymium neodymium iron alloy is obtained, the average praseodymium neodymium content is 80.6%, the current efficiency is 85%, the rare earth yield is 94%, the alloy composition The results are shown in Table 3.

[0055] Table 3 Composition analysis results of praseodymium-neodymium-iron master alloy / wt%

[0056] RE Fe C O P S Si mn 80.6 19.25 0.0085 0.0094 <0.01 <0.005 0.012 <0.005

[0057] Using the praseodymium-neody...

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Abstract

The invention discloses a praseodymium-neodymium-iron alloy. The praseodymium-neodymium-iron alloy comprises 0-95wt% of praseodymium and neodymium and the balance iron and inevitable impurities of which the total content is less than 0.5wt%, wherein the content of oxygen is less than or equal to 0.01wt%, the content of carbon is less than or equal to 0.01wt%, the content of phosphorus is less than or equal to 0.01wt%, and the content of sulfur is less than or equal to 0.005wt%. The invention further discloses a preparation method of the praseodymium-neodymium-iron alloy. The praseodymium-neodymium-iron alloy prepared through the method is uniform in composition, small in segregation, low in impurity content, high in rare-earth yield, low in cost, and free of pollution; and the praseodymium-neodymium-iron alloy is high in rare-earth yield and remarkable in effect when applied to rare-earth steel, and is suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to a rare earth metal material, in particular to a praseodymium neodymium iron alloy and a preparation method thereof. Background technique [0002] At present, steel is the largest metal structural material and is widely used in construction, energy, transportation, aerospace and other fields. The application and research of rare earths in steel have also developed rapidly. The addition of rare earths to molten steel can desulfurize, deoxidize, change the shape of inclusions, etc., and can improve the plasticity, stamping performance, wear resistance and welding performance of steel. Various rare earth steels such as rare earth steel plates for automobiles, die steels, rails, etc. have been widely used. [0003] The addition method of rare earth in the production process of rare earth steel has always been the focus of scientific research. The existing addition methods include wire feeding method, cored wire, rare earth iron int...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25C3/36C25C7/00C22C38/02C22C38/04C22C33/06C22C28/00C22C1/03
CPCC22C1/03C22C28/00C22C33/06C22C38/005C22C38/02C22C38/04C25C3/36C25C7/005
Inventor 张志宏陈宇昕高日增于兵赵二雄苗旭晨张文灿杨鹏飞刘冉
Owner BAOTOU RES INST OF RARE EARTHS
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