Praseodymium-neodymium-iron alloy and preparation method thereof
A ferroalloy, praseodymium neodymium iron technology, applied in the field of praseodymium neodymium ferroalloy and its preparation, can solve the problems of high local concentration of rare earth metals, affecting product consistency, high requirements for melting temperature, etc., to achieve broad development and market prospects, low praseodymium neodymium content control, high product quality
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[0036] The preparation process of the praseodymium neodymium iron alloy for producing rare earth steel comprises the following steps:
[0037] Step 1: Graphite is used as the electrolytic cell, the graphite plate is used as the anode, the iron rod is used as the self-consumable cathode, and there is a receiver containing the alloy under the cathode;
[0038] The material of the receiver can be one of iron, rare earth oxide, and boron nitride.
[0039] Step 2: In the fluoride molten salt electrolyte system of praseodymium neodymium fluoride (a mixture of praseodymium fluoride and neodymium fluoride) and lithium fluoride, using praseodymium neodymium oxide (a mixture of praseodymium oxide and neodymium oxide) as the electrolytic raw material, through Enter direct current electrolysis to obtain praseodymium neodymium iron master alloy;
[0040] Step 3: Using the praseodymium-neodymium-iron master alloy and iron as raw materials, a fusion method is used to prepare the praseodymiu...
Embodiment 1
[0047] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The praseodymium and neodymium fluoride in the electrolyte is 85wt%, and the lithium fluoride is 15wt%. The cathode is a 70mm pure iron rod. The average current intensity is 4500A, and the anode current density is 0.8 -1.0A / cm 2, cathode current density 6-9A / cm 2 , the electrolysis temperature is maintained at 900-1000 ℃, continuous electrolysis for 360 hours, 3046 kg of praseodymium neodymium oxide is consumed, and 2710 kg of praseodymium neodymium iron alloy is obtained, the average praseodymium neodymium content is 90.5%, the current efficiency is 85%, and the rare earth yield is 94%. The composition results are shown in Table 1.
[0048] Table 1 Composition analysis results of praseodymium-neodymium-iron master alloy / wt%
[0049] RE Fe C O P S Si mn 90.5 9.25 0.0085 0.0094 <0.01 <0.005 0.011 <0.005
[0050] Using the praseodymium...
Embodiment 2
[0054] A Φ650mm circular graphite electrolytic cell is used. The anode is composed of four graphite plates. The electrolyte contains 85wt% praseodymium neodymium fluoride and 15wt% lithium fluoride. The cathode is a 70mm pure iron rod. The average current intensity is 4000A and the anode current density is 0.8 -1.2A / cm 2 , cathode current density 5-8A / cm 2 , the electrolysis temperature is maintained at 950-1050 ℃, continuous electrolysis for 240 hours, 1805 kg of praseodymium neodymium oxide is consumed, and 1803 kg of praseodymium neodymium iron alloy is obtained, the average praseodymium neodymium content is 80.6%, the current efficiency is 85%, the rare earth yield is 94%, the alloy composition The results are shown in Table 3.
[0055] Table 3 Composition analysis results of praseodymium-neodymium-iron master alloy / wt%
[0056] RE Fe C O P S Si mn 80.6 19.25 0.0085 0.0094 <0.01 <0.005 0.012 <0.005
[0057] Using the praseodymium-neody...
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