Making method of colored toner
A technology of color toner and initiator, which is applied in the field of preparation of color toner for copying and printing, can solve the problems of poor compatibility between resin and pigment, poor control of particle shape, high energy consumption of reaction process, etc., and achieve waste toner rate Low, bright colors, good uniformity of size and shape
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preparation Embodiment 1
[0025] After stirring 1.0 g of polyvinyl alcohol and 100 ml of deionized water at 80° C. for 2 hours, it was cooled to room temperature. Then add 0.066 g of sodium lauryl sulfate, 0.033 g of sodium sulfate, and 0.032 g of hydroquinone to the aqueous solution of polyvinyl alcohol, and stir at room temperature for 3 hours until dissolved to obtain an aqueous phase. The obtained aqueous phase is called aqueous phase A-1 .
preparation Embodiment 2
[0027] After stirring 0.9 g of polyethylene oxide and 100 ml of deionized water at 80° C. for 2 hours, it was cooled to room temperature. Add 0.066 g of dioctyl sodium succinate, 0.033 g of sodium sulfate, and 0.032 g of hydroquinone to the aqueous solution of polyvinyl alcohol, and stir at room temperature for 3 hours to dissolve to obtain an aqueous phase. The obtained aqueous phase is called the aqueous phase. A-2.
[0028] Preparation Example 1 of Oil Phase
[0029] Add 17 g of styrene, 5.9 g of butyl acrylate and 1.03 g of dibenzoyl peroxide into a 100 ml beaker, stir slowly until dissolved, then add 0.96 g of dye solvent yellow 163, 0.5 g of charge regulator, and 1.0 g of wax , continue to stir until dissolved to obtain an oil phase, and the obtained oil phase is called oil phase B-1.
[0030] Preparation Example 2 of Oil Phase
[0031] Add 15 g of styrene, 7.3 g of butyl acrylate and 2.0 g of azobisisobutyronitrile into a 100 ml beaker, stir slowly until dissolved, t...
preparation Embodiment 3
[0039] Preparation of emulsion: Mix water phase A-2 and oil phase B-2, add to membrane emulsifier, and undergo 3 to 5 membrane emulsification operations (pressure control 0.01 to 0.30 MPa) to obtain emulsion.
[0040]Preparation of colored microspheres: Pour the obtained emulsion into a three-necked flask equipped with a stirrer, a thermometer and nitrogen gas, first adjust the rotation speed to 90-100 r / min, and feed nitrogen gas for 30-60 minutes, then stop nitrogen gas flow, and The temperature of the reaction solution was raised to 60-100 oC, the rotational speed was adjusted to 150-160 r / min, and the reaction was carried out for 10-24 hours. Stop the reaction, cool the reaction solution to room temperature, centrifuge with a centrifuge, move the solid to a beaker, wash with ethanol 3 times, and then wash 3 times with deionized water. Dry the solid particles at a temperature of 40-45°C so that the water content is less than 0.5wt%. Finally, add silicon dioxide and mix unif...
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