A kind of solar cell with double-layer perovskite film structure and its preparation method

A double-layer perovskite and solar cell technology, applied in the field of solar cells, can solve the problems of impact, toluene toxicity, etc.

Active Publication Date: 2019-10-11
SOUTH CHINA NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, toluene is highly toxic and has a great impact on the human body and the environment. Therefore, it is advisable to use green solvents to improve the morphology and crystallinity of the film.

Method used

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  • A kind of solar cell with double-layer perovskite film structure and its preparation method
  • A kind of solar cell with double-layer perovskite film structure and its preparation method
  • A kind of solar cell with double-layer perovskite film structure and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0080] like figure 2 As shown, the preparation method of a solar cell with a double-layer perovskite film structure provided in this embodiment includes the following steps:

[0081] (1) The FTO transparent conductive glass is etched into the desired target pattern by laser, and then the etched conductive substrate is ultrasonically cleaned with conventional detergent aqueous solution, deionized water, acetone and isopropanol for 20 minutes, and then Blow dry with nitrogen to obtain a clean conductive substrate for later use;

[0082] (2) Treat the surface with plasma (plasma, using a conventional plasma cleaning machine) for 10 minutes before use to hydrophilize the surface, and put the electron transport material TiO 2 The sol-gel (is the isopropanol solution of two (acetylacetonato) diisopropyl titanate with a mass percentage of 75%, the solution is diluted in n-butanol at a dilution ratio of 1:10 by mass ) at a speed of 2000rpm, spin-coated for 30s, and spin-coated on a...

Embodiment 2

[0090] (1) The FTO transparent conductive glass is etched into the desired target pattern by laser, and then the etched conductive substrate is ultrasonically cleaned with conventional detergent aqueous solution, deionized water, acetone and isopropanol for 20 minutes, and then Blow dry with nitrogen to obtain a clean conductive substrate for later use;

[0091] (2) Treat the surface with plasma (plasma, using a conventional plasma cleaning machine) for 10 minutes before use to hydrophilize the surface, and put the electron transport material TiO 2 The sol-gel (is the isopropanol solution of two (acetylacetonato) diisopropyl titanate with a mass percentage of 75%, the solution is diluted in n-butanol at a dilution ratio of 1:10 by mass ) at a speed of 2000rpm, spin-coated for 30s, and spin-coated on a glass substrate, TiO 2 The thickness is 20-50nm, baked at 125°C for 5 minutes, annealed at 450°C for 15-30 minutes to obtain an electron transport layer;

[0092] (2') After co...

Embodiment 3

[0100] like figure 1 As shown, the preparation method of a solar cell with a double-layer perovskite film structure provided in this embodiment includes the following steps:

[0101] (1) The FTO transparent conductive glass is etched into the required target pattern by laser, and then the etched conductive substrate is ultrasonically cleaned with cleaning agent aqueous solution, deionized water, acetone and isopropanol for 20 minutes respectively, and then Blow dry with nitrogen to obtain the conductive substrate for subsequent use;

[0102] (2) Treat the surface with plasma for 10 minutes before use to hydrophilize the surface, and the TiO 2 The sol-gel (the isopropanol solution of 75% di(acetylacetonato) titanate diisopropyl titanate diluted in n-butanol at a dilution ratio of 1:10 by mass percentage) was spin-coated at a speed of 2000rpm for 30s, spin-coat on a glass substrate with a thickness of 20-50nm, bake at 125°C for 5 minutes, and anneal at 500°C for 30 minutes to ...

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Abstract

The invention discloses a method for preparing a solar cell with a double-layer perovskite film structure, comprising the following steps: (1) selecting a conductive substrate and etching a pattern to obtain an etched conductive substrate; (2) preparing an electron transport layer or hole transport layer; (3) prepare a thin film with double-layer perovskite structure; (4) prepare hole transport layer or electron transport layer; (5) hot-plate gold or electron transport layer on hole transport layer or electron transport layer Silver electrode, obtain n-i-p type or p-i-n type solar cell with double-layer perovskite thin film structure; The present invention also discloses the solar cell prepared by adopting the above method, the preparation method is green and environment-friendly, can Improve the morphology and crystallinity of the perovskite film and the interface, and enhance the optoelectronic performance of the device.

Description

technical field [0001] The invention belongs to the field of solar cells, and in particular relates to a solar cell with a double-layer perovskite film structure and a preparation method thereof. Background technique [0002] With the depletion of fossil fuels, the development of clean energy is an inevitable means for human beings to achieve sustainable development. Solar cells provide inexhaustible clean energy by converting a steady stream of solar energy into electrical energy, which is an important countermeasure for sustainable development. [0003] At present, the commercialized batteries are mainly silicon solar cells and their compound solar cells. The high cost of materials and preparation restricts its development. Therefore, new solar cells with low cost and simple preparation process have become the focus of competing research in various countries. . In particular, the cost of perovskite solar cells is low and the preparation process is simple. In 2009, Miyasa...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/48H01L51/42
CPCH10K71/12H10K30/10Y02E10/549H10K85/50
Inventor 高进伟张文辉丁阳凌桂林
Owner SOUTH CHINA NORMAL UNIVERSITY
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