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PVC modified material used for antiskid carpets, and preparation method thereof

A modified material, a technology of PVC resin, applied in the field of PVC modified material for non-slip carpet and its preparation, can solve the problems of poor fluidity, easy brittle cracking, poor thermal stability, etc., to improve the bending strength and bending elastic modulus and Heat distortion temperature and dimensional stability, improved compatibility, improved stability

Inactive Publication Date: 2017-07-04
广东祺龙科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has light weight, high strength, insulation, flame retardancy, corrosion resistance, It has the advantages of excellent comprehensive performance, low price and wide source of raw materials; but it also has the following disadvantages: 1. Poor toughness, easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. Large, the lower limit of general PVC products is -15°C, and the lower limit of soft PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C. The melting temperature of PVC is about 210°C; 3. The viscosity of PVC is extremely high and its fluidity is extremely poor, which limits its use to a certain extent.
[0003] However, the existing PVC materials for carpets have defects such as anti-slip, wear-resistant and anti-aging properties, which limit their use to a certain extent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] A PVC modified material for anti-slip carpets, comprising the following raw materials in parts by weight:

[0062] PVC resin 80 parts

[0063] 40 parts plasticizer

[0064] 10 parts of heavy calcium carbonate

[0065] Light calcium carbonate 5 parts

[0066] High compound stabilizer 3 parts

[0067] Chlorinated polyethylene 1 part

[0068] Wear-resistant modifier 1 part

[0069] Anti-slip agent 0.3 parts

[0070] Anti-ultraviolet agent 0.6 parts

[0071] Antioxidant 0.3 parts

[0072] Lubricant 0.3 parts.

[0073] Described PVC resin is the SG-5 type PVC resin of polymerization degree at 1000; Described plasticizer is made of epoxy soybean oil, synthetic vegetable ester and cyclohexane 1,2-diisononyl dicarboxylate in weight ratio 1:0.8:1 mixture.

[0074] The heavy calcium carbonate has a particle size of 100nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size of 10nm and has been treated with a silane coupling...

Embodiment 2

[0094] A PVC modified material for anti-slip carpets, comprising the following raw materials in parts by weight:

[0095] PVC resin 90 parts

[0096] 45 parts plasticizer

[0097] 11 parts of heavy calcium carbonate

[0098] Light calcium carbonate 8 parts

[0099] High compound stabilizer 4 parts

[0100] Chlorinated polyethylene 1.5 parts

[0101] Wear-resistant modifier 1.5 parts

[0102] Anti-slip agent 0.4 parts

[0103] Anti-ultraviolet agent 0.7 parts

[0104] Antioxidant 0.4 parts

[0105] Lubricant 0.4 parts.

[0106] Described PVC resin is the SG-5 type PVC resin of polymerization degree at 1020; A mixture composed of 1.2:0.9:1.

[0107] The heavy calcium carbonate has a particle size of 200nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size of 30nm and has been treated with a silane coupling agent. Light calcium carbonate.

[0108] The high complex stabilizer is a mixture of calcium stearate, zinc steara...

Embodiment 3

[0127] A PVC modified material for anti-slip carpets, comprising the following raw materials in parts by weight:

[0128] PVC resin 100 parts

[0129] Plasticizer 50 parts

[0130] 12 parts of heavy calcium carbonate

[0131] Light calcium carbonate 10 parts

[0132] High compound stabilizer 5 parts

[0133] Chlorinated polyethylene 2 parts

[0134] Wear-resistant modifier 2 parts

[0135] Anti-slip agent 0.5 parts

[0136] Anti-ultraviolet agent 0.8 part

[0137] Antioxidant 0.5 part

[0138] Lubricant 0.5 part.

[0139] Described PVC resin is the SG-5 type PVC resin of polymerization degree at 1050; Described plasticizer is made of epoxy soybean oil, synthetic vegetable ester and cyclohexane 1,2-diisononyl dicarboxylate in weight ratio 1.5:1:1 composition mixture.

[0140] The heavy calcium carbonate has a particle size of 300nm and has been modified by maleic anhydride grafting; the light calcium carbonate has a particle size of 50nm and has been treated with a si...

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Abstract

The invention relates to the technical field of PVC materials, and concretely to a PVC modified material used for antiskid carpets, and a preparation method thereof. The PVC modified material used for anti-skid carpets comprises, by weight, 80-120 parts of PVC resin, 40-60 parts of a plasticizer, 10-15 parts of heavy calcium carbonate, 5-15 parts of light calcium carbonate, 3-7 parts of a high composite stabilizer, 1-3 parts of chlorinated polyethylene, 1-3 parts of a wear resistant modifier, 0.3-0.7 parts of an antiskid agent, 0.6-1.0 part of an ultraviolet resisting agent, 0.3-0.7 parts of an antioxidant and 0.3-0.7 parts of a lubricant. The PVC modified material used for antiskid carpets has the advantages of good wear resistance, good antiskid and anti-aging effect, environmental protection, excellent resistance to temperature and weather, high strength, excellent impact resistance, good flame retardation effect, excellent processability and excellent comprehensive performances.

Description

technical field [0001] The invention relates to the technical field of PVC materials, in particular to a PVC modified material for anti-slip carpets and a preparation method thereof. Background technique [0002] Polyvinyl chloride (PVC) is one of the earliest industrialized and widely used general-purpose thermoplastics. It has the advantages of light weight, high strength, insulation, flame retardancy, corrosion resistance, excellent comprehensive performance, low price and wide source of raw materials; but also There are the following disadvantages: 1. The toughness is poor, and it is easy to be brittle when impacted, so it cannot be used as a structural material. In addition, the brittleness of polyvinyl chloride is greatly affected by temperature. The lower limit of general PVC products is -15°C. The lower limit of use of PVC is -30°C; 2. Poor thermal stability, it begins to decompose HCl at 100°C, and decomposes more rapidly when it is higher than 150°C, and the meltin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L23/28C08L91/00C08L9/06C08L7/00C08L23/30C08L51/06C08L51/00C08K13/06C08K5/11C08K3/26C08K9/06C08K9/04C08K5/098C08K7/26C08K7/20C08K5/3475C08K5/134C08K5/526C08K5/103C08K5/20C08K9/12C08K3/08C08K3/22C08K3/38
CPCC08L27/06C08L2201/02C08L2201/08C08L2205/02C08L2205/035C08L23/286C08L91/00C08L9/06C08L7/00C08L23/30C08L51/06C08L51/003C08K13/06C08K5/11C08K2003/265C08K9/06C08K9/04C08K5/098C08K7/26C08K7/20C08K5/3475C08K5/1345C08K5/526C08K5/103C08K5/20C08K9/12C08K2003/0806C08K3/2279C08K2003/387C08K2003/2241
Inventor 宁建华
Owner 广东祺龙科技有限公司
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