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A kind of heat-resistant iron oxide yellow pigment and preparation method thereof

A technology for iron oxide yellow and pigment, which is applied in the field of heat-resistant iron oxide yellow pigment and its preparation, can solve the problems of poor thermal stability of iron oxide yellow, limitation of coloring application, etc., achieves high industrial application value, simple synthesis method and low cost low effect

Active Publication Date: 2020-10-13
ZHEJIANG HUAYUAN PIGMENT CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the poor thermal stability of iron oxide yellow, it is relatively limited in the application of plastic processing and powder coating coloring

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh 20Kg iron oxide yellow pigment 810#, and evenly disperse iron oxide yellow in 200 L of water under stirring to form a mixed solution with iron oxide yellow content of 10%; weigh 3.35Kg zinc chloride and 2.53Kg sodium hexametaphosphate respectively , 1.64Kg sodium hydroxide, dissolved in 100 L water respectively to form solution A, solution B and solution C; 80°C, and continue to stir for 3 h after adding the solution; after pressure filtration and washing, the filter cake is dried and crushed at 90°C to obtain heat-resistant iron oxide yellow product A.

Embodiment 2

[0023] Take by weighing 10Kg iron oxide yellow pigment 810#, under stirring, iron oxide yellow is uniformly dispersed in 200 L of water to form a mixed solution with iron oxide yellow content of 5%; respectively weigh 4.65Kg zinc nitrate, 1.68Kg sodium hexametaphosphate, 1.31Kg sodium hydroxide, dissolved in 30 L water respectively to form solution A, solution B and solution C; then add solution A, solution B and solution C to the iron oxide yellow mixture under stirring, and the reaction temperature is controlled at 70 ℃, and continue to stir for 10 h after adding the solution; after pressure filtration and washing, the filter cake is dried and crushed at 100 ℃ to obtain heat-resistant iron oxide yellow product B.

Embodiment 3

[0025] Take by weighing 30Kg iron oxide yellow pigment 810#, and under stirring, iron oxide yellow is evenly dispersed in 100 L of water to form a mixed solution with iron oxide yellow content of 30%; respectively weigh 3.97Kg zinc sulfate, 2.53Kg sodium hexametaphosphate, 1.64Kg sodium hydroxide was dissolved in 80 L water respectively to form solution A, solution B and solution C; then solution A, solution B and solution C were added to the iron oxide yellow mixture under stirring, and the reaction temperature was controlled at 50 After adding the solution, continue to stir for 18 hours; after pressure filtration and washing, the filter cake is dried and crushed at 80°C to obtain heat-resistant iron oxide yellow product C.

[0026] Heat resistance test: Weigh 2g of the product, put it into a small crucible, heat it in an oven at 270°C for 0.5h, take it out and cool it, and then measure the color difference ΔE of the product on a spectrophotometer. The ΔE of heat-resistant ir...

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Abstract

The invention relates to an iron oxide yellow pigment, and especially relates to a heatproof-type iron oxide yellow pigment and a preparation method thereof. According to the heatproof-type iron oxide yellow pigment, an external layer of the iron oxide yellow is coated with compact zinc phosphate. A composite material formed by coating iron oxide yellow with zinc phosphate increases the hear resistance of iron oxide yellow, and can be used as a colouring agent and an antiseptic during plastic processing and powdery paints application. The heatproof-type iron oxide yellow has the advantages of good heat resistance, simple synthetic method, low cost, and safety and environmental friendliness, and has high industrial application value.

Description

technical field [0001] The invention relates to an iron oxide yellow pigment, in particular to a heat-resistant iron oxide yellow pigment and a preparation method thereof. Background technique [0002] In recent years, China's iron oxide industry has entered a stage of overcapacity and competition. Overcapacity is a major problem facing the entire iron oxide industry. At present, my country's iron oxide industry is still in the extensive development stage, and there is a lack of innovation in products and processes. It is impossible to transform resource advantages into economic and technological advantages. [0003] Iron oxide yellow, referred to as iron yellow, is ferric oxide containing water, and its molecular formula is FeOOH. Iron oxide yellow is a lemon yellow to brown powder. Due to different production methods and operating conditions, its crystal structure and physical properties will vary greatly. big difference. Iron oxide yellow will gradually lose crystal wat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D7/62C09D5/08C09D5/03C08K9/02C08K9/08C08K3/22
CPCC08K3/22C08K9/02C08K9/08C08K2003/2272C09D5/038C09D5/084C09D7/62
Inventor 潘国祥李金花沈辉曹枫竺增林高健敏徐敏虹郭玉华
Owner ZHEJIANG HUAYUAN PIGMENT CO LTD