Ultraviolet-radiation-resistant optical glass high in ultraviolet band transmittance

A technology of ultraviolet band and optical glass, applied in the field of optical glass, can solve the problems of low transmittance of ultraviolet band, decline of transmittance of ultraviolet part, cost waste, etc., achieve excellent ultraviolet anti-aging performance, improve the internal structure of glass, The effect of improving transmittance

Inactive Publication Date: 2017-07-25
GUOGUANG OPTICAL GLASS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. The transmittance in the ultraviolet band is not high, generally around 80%. At present, the peak transmittance of ultraviolet glass in the ultraviolet band is only about 80%, and the current practical application requirements need to reach more than 85%.
[0005] 2. After the ultraviolet glass is exposed to ultraviolet light for a long time, the transmittance of the ultraviolet part will decline
[0006] At present, in view of the above two defects, the general practice of the industry is to minimize the start-up time. Due to the impact of equipment detection accuracy, the UV glass needs to be replaced continuously, resulting in waste of cost.

Method used

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  • Ultraviolet-radiation-resistant optical glass high in ultraviolet band transmittance
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  • Ultraviolet-radiation-resistant optical glass high in ultraviolet band transmittance

Examples

Experimental program
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Effect test

Embodiment 1

[0040] In this embodiment, the optical glass with high transmission in the ultraviolet band and resistant to ultraviolet radiation includes the following components in parts by weight:

[0041] 60 parts of phosphoric acid, 13 parts of boric acid, 8 parts of alumina, 4 parts of barium carbonate, 4 parts of potassium carbonate, 3 parts of calcium carbonate, 1 part of cobalt oxide, 2 parts of nickel oxide, 0.5 parts of tartaric acid, 0.5 parts of cerium oxide, strontium oxide 0.25 servings.

[0042] After the above-mentioned raw materials are mixed uniformly, the feeding temperature is 1230 ° C, the material is fully dissolved, and then the feeding is added for a total of 6 times, and the interval between each feeding is about 30 minutes; after the feeding is completed, the temperature is raised to 1330 ° C, and the heating time is 1 hour; 1330°C for 4 hours. The temperature was lowered from 1330°C to 1160°C, the cooling time was 1 hour, and the discharge temperature was about 1...

Embodiment 2

[0045] In this embodiment, the optical glass with high transmission in the ultraviolet band and resistant to ultraviolet radiation includes the following components in parts by weight:

[0046] 65 parts of phosphoric acid, 14 parts of boric acid, 10 parts of alumina, 5 parts of barium carbonate, 5 parts of potassium carbonate, 4 parts of calcium carbonate, 1.5 parts of cobalt oxide, 2.5 parts of nickel oxide, 0.8 parts of tartaric acid, 0.6 parts of cerium oxide, strontium oxide 0.3 servings.

[0047] After the above-mentioned raw materials are mixed uniformly, the feeding temperature is 1230 ° C, the material is fully dissolved, and then the feeding is added for a total of 6 times, and the interval between each feeding is about 30 minutes; after the feeding is completed, the temperature is raised to 1330 ° C, and the heating time is 1 hour; 1330°C for 4 hours. The temperature was lowered from 1330°C to 1160°C, the cooling time was 1 hour, and the discharge temperature was ab...

Embodiment 3

[0050] In this embodiment, the optical glass with high transmission in the ultraviolet band and resistant to ultraviolet radiation includes the following components in parts by weight:

[0051] 70 parts of phosphoric acid, 15 parts of boric acid, 12 parts of alumina, 6 parts of barium carbonate, 6 parts of potassium carbonate, 5 parts of calcium carbonate, 1.8 parts of cobalt oxide, 2.8 parts of nickel oxide, 1 part of tartaric acid, 0.7 parts of cerium oxide, oxide Strontium 0.3 parts.

[0052] After the above-mentioned raw materials are mixed uniformly, the feeding temperature is 1230 ° C, the material is fully dissolved, and then the feeding is added for a total of 6 times, and the interval between each feeding is about 30 minutes; after the feeding is completed, the temperature is raised to 1330 ° C, and the heating time is 1 hour; 1330°C for 4 hours. The temperature was lowered from 1330°C to 1160°C, the cooling time was 1 hour, and the discharge temperature was about 11...

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Abstract

The invention provides ultraviolet-radiation-resistant optical glass high in ultraviolet band transmittance. The optical glass is prepared from, by weight, 60-70 parts of phosphoric acid, 13-15 parts of boric acid, 8-12 parts of aluminum oxide, 4-6 parts of barium carbonate, 4-6 parts of potassium carbonate, 3-5 parts of calcium carbonate, 1-1.8 parts of a coloring agent A, 2-2.8 parts of a coloring agent B, 0.5-1 part of a reducing agent and 0.5-1 part of a stabilizing agent, wherein the stabilizing agent is composed of cerium oxide and strontium oxide, a ratio of strontium oxide to cerium oxide is 2:1, the coloring agent A refers to cobalt oxide, the coloring agent B refers to nickel oxide, a ratio of nickel oxide to cobalt oxide is 1:2, and tartaric acid serves as the reducing agent. The optical glass has advantages that a great ultraviolet radiation resistance function of the ultraviolet glass is achieved while ultraviolet band transmittance of the ultraviolet glass is increased, and the technical problem that the peak transmittance, which is required to be 85% or above in practical application, of current ultraviolet glass at an ultraviolet band is only about 80% is solved.

Description

technical field [0001] The invention relates to a glass used for medical fluorescence detection equipment, in particular to an optical glass with high transmittance in the ultraviolet band and resistance to ultraviolet radiation. Background technique [0002] Ultraviolet technology has a wide range of applications in medical fluorescence detection. Ultraviolet glass needs to have high pass rates in different ultraviolet bands (254nm; 313nm; 365nm), and at the same time cut off the visible light band. [0003] At present, domestic ultraviolet transmission glass has two defects: [0004] 1. The transmittance in the ultraviolet band is not high, generally about 80%; the current peak transmittance of ultraviolet glass in the ultraviolet band is only about 80%, and the current practical application requirements need to reach more than 85%. [0005] 2. After the UV glass is irradiated by UV optics for a long time, the transmittance of the UV part will decline. This phenomenon i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C4/00C03C3/19
CPCC03C3/19C03C4/0085C03C2204/04
Inventor 沈杰沈强国
Owner GUOGUANG OPTICAL GLASS CO LTD
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