High-heat-resistance low-light-transmittance acrylonitrile-butadiene-styrene composition and preparation method thereof

A technology of acrylonitrile and butadiene, which is applied in the field of acrylonitrile-butadiene-styrene composition and its preparation, can solve the problem of reducing light transmittance, light diffusing agent and light blocking agent without clear selection target and no effective Improve the dispersion effect of light diffusing agent and light blocking agent, and do not completely solve the problems of ABS resin condition range, etc., achieve excellent shading effect, good dispersion effect, and improve the success rate of development

Inactive Publication Date: 2017-08-01
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the low light transmittance of acrylonitrile-butadiene-styrene in the existing technology is mostly from the large amount of ABS (such as the invention patent of Chinese patent application number 201210221191.5), or the narrow optional range of ABS (such as Chinese patent Patent of invention with application number 201310267948.9), or traditional extrusion granulation processing method (such as patent of invention with application number of Chinese patent 201310267948.9) to deal with the problem
At the same time, the prior art only discloses light-shielding explanations for thicker products (for example, the Chinese patent application number 201310267948.9 is a 2 mm thick light-shielding material)
[0007] There are some deficiencies: ①The solution to the low light transmittance of thinner products is not effective; ②The range of conditions for ABS resin selection is not completely resolved; ③Light diffusing agents and light blockers that reduce light transmittance have no clear selection targets; ④ The heat resistance problem of ABS with low light transmittance is not solved; ⑤The traditional extrusion granulation processing method does not effectively improve the dispersion effect of light diffusing agent and light blocking agent in resin

Method used

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  • High-heat-resistance low-light-transmittance acrylonitrile-butadiene-styrene composition and preparation method thereof
  • High-heat-resistance low-light-transmittance acrylonitrile-butadiene-styrene composition and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] 55 parts of Daqing 750, 12 parts of 80HF, 10 parts of HR-15, 15 parts of superfine barium sulfate and fine calcium carbonate mixture (the weight ratio of the two = 2:1), 7 parts of R-760, 0.5 parts of light stabilizer ( 0.3 parts of LA-944, 0.2 parts of UV-360), 0.5 parts of processing aids (0.3 parts of heat stabilizer, 0.2 parts of lubricant) are mixed evenly by high-speed stirring, and the above mixture is sent into the internal mixer machine, and the Under the action of stirring and shearing, it is fully melted and mixed, and then pressed into 2 mm thin slices by a film laminator, and then cut into pellets with a cutter.

[0051] The temperature of the internal mixer is 220° C., and the rotational speed of the rotor of the internal mixer is 70 rpm.

[0052] The prepared material was injection molded into a standard sample bar for testing according to the standard size, and the performance test results are shown in Table 2.

Embodiment 2

[0058] With 64 parts of Daqing 750, 10 parts of HR-15, 13 parts of ultrafine barium sulfate, 12 parts of R-760, 0.5 part of light stabilizer (0.3 part of LA-944, 0.2 part of UV-360), 0.5 part of processing aid ( 0.3 parts of heat stabilizer, 0.2 parts of lubricant) are mixed evenly by high-speed stirring, and the above-mentioned mixture is sent into the internal mixer, fully melted and mixed under the stirring and shearing action of the rotor, and then pressed into 2 mm flakes, and then cut into pellets with a cutter.

[0059] The temperature of the internal mixer is 180° C., and the rotational speed of the rotor of the internal mixer is 70 rpm.

[0060] The prepared material was injection molded into a standard sample bar for testing according to the standard size, and the performance test results are shown in Table 3.

Embodiment 3

[0066] 74 parts of Daqing 750, 10 parts of 80HF, 20 parts of HR-15, 3 parts of ultra-fine barium sulfate, 2 parts of R-760, 0.5 parts of light stabilizer (0.3 parts of LA-944, 0.2 parts of UV-360), processing aids 0.5 parts of agent (0.3 parts of heat stabilizer, 0.2 parts of lubricant) are mixed evenly by high-speed stirring, and the above mixture is sent into the internal mixer, fully melted and mixed under the stirring and shearing action of the rotor, and then pressed into the film Machine pressed into 2 mm thin slices, and then cut into pellets with a cutter.

[0067] The temperature of the internal mixer is 250° C., and the rotational speed of the rotor of the internal mixer is 70 rpm.

[0068] The prepared material was injection molded into a standard sample bar for testing according to the standard size, and the performance test results are shown in Table 4.

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Abstract

The invention belongs to the technical field of high molecular materials and relates to high-heat-resistant low-light-transmittance acrylonitrile-butadiene-styrene composition and a preparation method thereof. The composition is prepared from the following ingredients in parts by weight: 55 to 74 parts of acrylonitrile-butadiene-styrene resin which is chosen from emulsion grafting method production, 0 to 12 parts of acrylonitrile-styrene, 10 to 20 parts of heat-resisting agent, 3 to 15 parts of light diffusion agent, 2 to 15 parts of light blocking agent, 0.5 to 2 parts of light stabilizer and 0.5 to 2 parts of processing aid. All the ingredients are evenly mixed and then sent into an internal mixer to be extruded and mixed, are compressed into 1 to 5-millimeter slices by a laminator and then are cut into a particle material by a cutter. The material has a good and uniform-phase ingredient dispersion effect, has excellent low light transmission in thinner work pieces, further has good heat resistance and is suitable for being applied to optical components in the fields of electric appliances, automobiles, aviation and the like.

Description

[0001] (1) Technical field [0002] The invention belongs to the technical field of polymer materials, and in particular relates to an acrylonitrile-butadiene-styrene composition with the advantages of high heat resistance and low light transmittance and a preparation method thereof. [0003] (2) Background technology [0004] Acrylonitrile-butadiene-styrene composition (ABS for short) is a graft copolymer of three monomers: acrylonitrile, butadiene and styrene. Because of its combination of chemical resistance and high surface hardness of acrylonitrile, toughness of butadiene, coloring and good processability of styrene, it is widely used in appearance parts in household appliances, automobiles, aviation and other fields. [0005] At present, with the continuous development of science and technology, optical products with high added value, such as automotive lampshades, SLR camera hoods, LED lampshades, LED display frames, display frames, and mobile phone frames, have higher a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L33/20C08L25/08C08K13/02C08K3/30C08K3/26C08K3/22
CPCC08L55/02C08K2201/003C08L2201/08C08L2205/03C08L33/20C08L25/08C08K13/02C08K2003/3045C08K2003/265C08K2003/2241
Inventor 杨桂生高军杨莺李术
Owner HEFEI GENIUS NEW MATERIALS
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