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Bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer and preparation method thereof

An interpenetrating network type and potassium humate technology, which is applied in the field of bone meal and potassium humate-based interpenetrating network type phosphorus-rich potassium water-retaining nutrient fertilizer and its preparation

Inactive Publication Date: 2017-10-10
HEBEI UNIV OF ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, among the products prepared by the current synthesis process, fertilizers that are "rich in phosphorus and potassium, water absorption, and moisture retention" have not been reported yet.

Method used

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  • Bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer and preparation method thereof
  • Bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer and preparation method thereof
  • Bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] According to mass percentage, 40% of bone powder, 8% of potassium humate, 35% of acrylic acid, 15% of acrylamide, 0.5% of initiator ammonium persulfate and 1.5% of crosslinking agent N,N-methylenebisacrylamide are respectively taken. Grind bone meal to 100 mesh, mix with potassium humate, and then prepare a mixed solution with a total solid content of 40% with distilled water, add acrylic acid to the mixed system, adjust the pH to 5.0 with 15% potassium hydroxide solution, and then Add acrylamide into the mixture, stir well to disperse. The initiator and crosslinking agent were added in sequence, the temperature was raised to 55° C., and the crosslinking reaction was carried out for 3 hours to form a crosslinking complex. The cross-linked complex is vacuum-dried at 50° C., crushed, and passed through an 8-mesh sieve to obtain bone powder and potassium humate-based interpenetrating network type phosphorus-rich potassium water-retaining nutrient fertilizer. The specific ...

Embodiment 2

[0044] According to mass percentage, 30% of bone meal, 10% of potassium humate, 40% of acrylic acid, 18% of acrylamide, 0.5% of initiator ammonium persulfate and 1.5% of crosslinking agent N,N-methylenebisacrylamide are respectively taken. Grind bone powder to 80 mesh, mix with potassium humate, and then prepare a mixed solution with a total solid content of 40% with distilled water, add acrylic acid to the mixed system, adjust the pH to 5.0 with 20% potassium hydroxide solution, and then Add acrylamide into the mixture, stir well to disperse. The initiator and crosslinking agent were added in sequence, the temperature was raised to 55° C., and the crosslinking reaction was carried out for 3 hours to form a crosslinking complex. The cross-linked complex is vacuum-dried at 50° C., crushed, and passed through a 12-mesh sieve to obtain bone meal and potassium humate-based interpenetrating network type phosphorus-rich potassium water-retaining nutrient fertilizer.

[0045] After ...

Embodiment 3

[0047] According to the mass percentage, 28% of bone meal, 15% of potassium humate, 40% of acrylic acid, 15% of acrylamide, 1% of initiator ammonium persulfate and 1% of crosslinking agent N,N-methylenebisacrylamide are respectively taken. Grind bone powder to 120 mesh, mix with potassium humate, and then prepare a mixed solution with a total solid content of 40% with distilled water, add acrylic acid to the mixed system, adjust the pH to 6.0 with 20% potassium carbonate, and then add propylene The amide is added into the mixture, fully stirred and dispersed to form a pre-crosslinked system. Add an initiator and a cross-linking agent, raise the temperature to 60° C., and conduct a cross-linking reaction for 3 hours to form a cross-linked complex. The cross-linked complex is vacuum-dried at 50° C., crushed, and passed through a 10-mesh sieve to obtain bone meal and potassium humate-based interpenetrating network type phosphorus-rich potassium water-retaining nutrient fertilizer...

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Abstract

The invention relates to a bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer and a preparation method thereof, belonging to the technical field of agricultural fertilizers. The preparation method comprises the steps of dispersing bone meal and potassium humate into water, adding a polymerization monomer, adjusting the pH to 5.0-7.5, adding an initiator and a cross-linking agent, carrying out cross-linking agent reaction so as to form a compound cross-linked body, and carrying out vacuum drying and crushing, so as to obtain the bone meal and potassium humate based interpenetrating polymer network type phosphorus-potassium-rich water-retention nutritional fertilizer. According to the preparation method, the bone meal and potassium humate are mainly used as matrix raw materials for preparing a product with an interpenetrating polymer network through graft copolymerization by virtue of a solution polymerization method; the product is a brown block particle, the content of total phosphorus (P2O5) is 5.0%-20.0%, the content of total potassium (K2O) is 5.0%-25.0%, and the water absorbing quantity is 80-600g.g<-1>; and the fertilizer has the advantages of multiple functions and stable structure, and the organic entropy preservation is realized.

Description

Technical field: [0001] The invention belongs to the technical field of agricultural fertilizers, and relates to a water-retaining fertilizer and a phosphorus-rich potassium fertilizer in agriculture, in particular to a bone meal and potassium humate-based interpenetrating network type phosphorus- and potassium-rich water-retaining nutrient fertilizer and a preparation method thereof. Background technique: [0002] From the perspective of fertilizers, nitrogen, phosphorus, and potassium are the three major nutrients for plant growth. Among them, phosphorus is an important constituent element of various compounds in plants such as proteins, nucleic acids and enzymes. In addition, phosphorus can promote flowering, improve the quality of many fruits and vegetables, and also help to enhance the plant's disease resistance and drought resistance. On the contrary, when the supply of phosphorus fertilizer is insufficient, the growth of plants will be inhibited, flowering will be sl...

Claims

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Application Information

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IPC IPC(8): C08F289/00C08F292/00C08F220/06C08F220/56C05G3/04C05G3/80
CPCC05B17/00C05G3/80C08F289/00C08F292/00C08F220/06C08F220/56C05F11/02
Inventor 韩帅张丽姣
Owner HEBEI UNIV OF ENG