Hydrocarbon cleaning method and device for preventing copper oxidization

A hydrocarbon cleaning and hydrocarbon cleaning agent technology, which is applied in chemical instruments and methods, cleaning methods and utensils, cleaning methods using liquids, etc., can solve problems such as oxidative discoloration, oxidative discoloration of parts, and non-compliance with environmental protection requirements. Achieve the effects of increasing costs, preventing oxidation and discoloration, and ensuring cleaning quality

Active Publication Date: 2017-11-17
厦门金越电器有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The copper and copper alloy parts cleaned by the touch cover cleaning machine only remove the oil and foreign matter on the surface of the parts. Since there is no anti-copper discoloration treatment, the parts are prone to oxidative discoloration during storage, especially during the rainy season or Parts are more prone to oxidative discoloration when the ambient humidity is high
[0008] ③The original 141B cleaning process cannot meet the quality requirements of various parts:
[0009] The original 141B organic solvent cleaning process cannot meet the cleaning of tin-plated parts such as coil soldering pieces, the solderability requirements of mass production turnover and parts after inventory, and cannot meet the cleaning quality requirements of various parts
[0010] Generally speaking, the 141B organic cleaning agent cleaning process of the touch cover cleaning machine has problems such as not meeting the future environmental protection requirements, and failing to meet the cleaning protection performance and solderability requirements of various parts and components.
[0011] Chinese invention patent application CN105642608A discloses a cleaning process for copper parts, including degassing hydrocarbon ultrasonic cleaning, vacuum hydrocarbon ultrasonic cleaning, vacuum bath washing and drying treatment. After cleaning by this process, parts are easily oxidized again and affect subsequent welding. And the cleaning effect on non-flat workpieces is poor, and it cannot meet the cleaning quality requirements of various parts

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Place a batch of copper-containing lead-out pieces (flat piece parts) in the three-layer drum, and go through the following processes in sequence:

[0039] Degassing hydrocarbon ultrasonic cleaning A: temperature 30°C; time 120S; ultrasonic power 28KHZ; filtration accuracy 50μm;

[0040] Degassing hydrocarbon ultrasonic cleaning B: temperature 30°C; time 120S; ultrasonic power 28KHZ; filtration accuracy 20μm;

[0041] Vacuum hydrocarbon ultrasonic cleaning: temperature 30°C; time 130S; vacuum degree 10kPa~atmospheric pressure changes repeatedly, filtration accuracy 10μm;

[0042] Anti-copper discoloration treatment: trichlorethylene solution of HQ-21 copper passivator with a mass concentration of 1%, treated at room temperature for 120S;

[0043] Vacuum steam treatment: vacuum degree 10kPa; steam temperature 100°C; time 180S;

[0044] Vacuum drying: vacuum degree ≤ 0.3kPa; time is 180S.

[0045] After treatment, the surface dryness and appearance quality of the coppe...

Embodiment 2

[0049] A kind of equipment for anti-copper oxidation hydrocarbon cleaning method, including degassing ultrasonic cleaning tank A, degassing ultrasonic cleaning tank B, vacuum ultrasonic cleaning tank, protective agent tank, vacuum steam cleaning and drying tank, three-layer square basket, three-part roller Barrel, steam generator and distillation regenerator, circulation filter system, specifically, the workpiece to be cleaned is placed in a three-layer square basket or three-compartment drum, degassing ultrasonic cleaning tank A, degassing ultrasonic cleaning tank B, vacuum ultrasonic cleaning Tank, protective agent tank, vacuum steam cleaning and drying tank are connected in sequence, the circulation filter system is respectively connected with the degassing ultrasonic cleaning tank A, degassing ultrasonic cleaning tank B, vacuum ultrasonic cleaning tank, the steam generator and distillation regenerator are connected with the circulation filter system is connected.

[0050] ...

Embodiment 3

[0053] Place a batch of angled copper-containing workpieces in a three-compartment square basket, and go through the following procedures in sequence:

[0054] Degassing hydrocarbon ultrasonic cleaning A: temperature 40°C; time 180S; ultrasonic power 28KHZ; filtration accuracy 50μm;

[0055] Degassing hydrocarbon ultrasonic cleaning B: temperature 40°C; time 180S; ultrasonic power 28KHZ; filtration accuracy 20μm;

[0056] Vacuum hydrocarbon ultrasonic cleaning: temperature 40°C; time 180S; vacuum degree 10kPa~atmospheric pressure changes repeatedly, filtration accuracy 10μm;

[0057] Anti-copper discoloration treatment: Hydrocarbon cleaning agent solution of HQ-21 copper passivator with a mass concentration of 1%, treated at room temperature for 180S;

[0058] Vacuum steam treatment: vacuum degree 15kPa; steam temperature 120°C; time 180S;

[0059] Vacuum drying: vacuum degree ≤ 0.3kPa; time is 180S.

[0060] After treatment, the dryness and appearance quality of the surfac...

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PUM

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Abstract

The invention relates to a hydrocarbon cleaning method and device for preventing copper oxidization. According to the hydrocarbon cleaning method for preventing copper oxidization, a cleaning way that a three-layer square basket is compatible with a three-layer rotary drum is adopted, and degassed hydrocarbon ultrasonic cleaning A, degassed hydrocarbon ultrasonic cleaning B, vacuum hydrocarbon ultrasonic cleaning, copper tarnish prevention treatment, vacuum vapor treatment and vacuum drying are sequentially conducted on a copper-containing workpiece. The hydrocarbon cleaning device comprises a degassed ultrasonic cleaning tank A, a degassed ultrasonic cleaning tank B, a vacuum ultrasonic cleaning tank, a protective agent tank, a vacuum vapor cleaning and drying tank, the three-layer square basket and the three-layer rotary drum. By adoption of the hydrocarbon cleaning method for preventing copper oxidization, blanking oil stains on the surface of a part can be effectively removed, and yellow points/yellow spots are avoided after cleaning; and meanwhile, the requirement for cleaning and protecting flat sheet type parts and angled parts can be met, and the one-time checked qualification rate of the cleaned parts is 97%-98%.

Description

technical field [0001] The invention relates to an industrial cleaning method for copper-containing workpieces, in particular to a method and equipment for preventing copper oxidation and hydrocarbon cleaning. Background technique [0002] The 141B organic solvent cleaning process of the touch cover cleaning machine is used for copper and copper alloy parts. The specific process is: loading → 141B rough cleaning → 141B cleaning → 141B fine cleaning → suction drying → unloading. Among them, 141B organic solvent is HCFC-141B cleaning agent. [0003] There are following problems in above technology: [0004] ①Environmental issues: [0005] The "Agreement on the Phasing Out of ODS in China's Cleaning Industry" stipulates that the use of ODS cleaning agents cannot be increased from 2013, and its use will be banned by 2030. The HCFC-141B used in the touch cover cleaning machine is a transitional cleaning agent, which can damage the atmospheric ozone layer to a certain extent, a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23G5/024C23G5/04B08B3/12
CPCB08B3/12C23G5/024C23G5/04
Inventor 陈仙花林青茂林亚扁
Owner 厦门金越电器有限公司
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