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Water-soluble polyurethane modified acrylic acid polymer as well as preparation method and application thereof

A water-soluble polyurethane and acrylic polymer technology, applied in the field of coatings, can solve the problems of short pot life, difficult construction, uneven mixing on the construction site, etc., and achieve the effect of excellent water resistance

Active Publication Date: 2017-12-15
NIPPON PAINT IND COATINGS SHANGHAI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The one-component water-based wine bottle paint prepared by polyurethane water dispersion, water-soluble polyacrylic resin, urethane type and modified acrylic resin has poor molecular weight, alcohol resistance, water resistance and abrasion resistance on the glass substrate. and low hardness
The short pot life of water-based two-component room temperature curing glass paint will cause certain difficulties in construction, and it will also cause problems such as waste of paint and uneven mixing on the construction site.
Especially in the case of high ethanol resistance requirements for water-based wine bottle coatings, it is required that the coatings be soaked in 65% ethanol for more than 6 hours without discoloration and peeling off. The coatings currently on the market basically cannot meet the needs

Method used

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  • Water-soluble polyurethane modified acrylic acid polymer as well as preparation method and application thereof
  • Water-soluble polyurethane modified acrylic acid polymer as well as preparation method and application thereof
  • Water-soluble polyurethane modified acrylic acid polymer as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0067] 1. The formula of water-soluble polyurethane modified acrylic acid polymer is as shown in table 1:

[0068] Table 1

[0069] name

Specification

Weight (parts)

Propylene glycol methyl ether acetate

Industrial products

45

Methacrylate

Industrial products

5

Styrene

Industrial products

16

Methyl methacrylate

Industrial products

2

Hydroxypropyl Methacrylate

Industrial products

15

Hydroxybutyl Acrylate

Industrial products

5

tert-butyl peroxybenzoate

Industrial products

6

Toluene diisocyanate

Industrial products

2

Isopropanol

Industrial products

10

Dimethylethanolamine

Industrial products

7

[0070] 2. the preparation method of water-soluble polyurethane modified acrylic acid polymer comprises the following steps:

[0071] Add 45 parts of propylene glycol methyl ether acetate, stir and heat up to reflux, drop 16 parts...

Embodiment 2

[0076] 1. The formula of water-soluble polyurethane modified acrylic acid polymer is as shown in table 2:

[0077] Table 2

[0078] name

Specification

Weight (parts)

dibasic acid ester

Industrial products

49

acrylic acid

Industrial products

6

Styrene

Industrial products

16

Methyl methacrylate

Industrial products

5

Hydroxyethyl methacrylate

Industrial products

13

Hydroxypropyl Acrylate

Industrial products

7

tert-butyl peroxybenzoate

Industrial products

5

Toluene diisocyanate

Industrial products

3

ethanol

Industrial products

14

Triethylamine

Industrial products

8

[0079] 2. the preparation method of water-soluble polyurethane modified acrylic acid polymer comprises the following steps:

[0080] Put 49 parts of dibasic acid ester, stir and heat up to reflux, drop 16 parts of styrene, 5 parts of methyl methacrylate, 6 pa...

Embodiment 3

[0085] 1. The formula of water-soluble polyurethane modified acrylic acid polymer is as shown in table 3:

[0086] table 3

[0087] name

Specification

Weight (parts)

dibasic acid ester

Industrial products

48

Methacrylate

Industrial products

7

Styrene

Industrial products

16

Isobornyl Methacrylate

Industrial products

5

Hydroxypropyl Methacrylate

Industrial products

15

Hydroxyethyl Acrylate

Industrial products

5

tert-butyl peroxybenzoate

Industrial products

5

Isophorone diisocyanate

Industrial products

3

ethanol

Industrial products

14

Dimethylethanolamine

Industrial products

6

[0088] 2. the preparation method of water-soluble polyurethane modified acrylic acid polymer comprises the following steps:

[0089] Put in 48 parts of dibasic acid ester, stir and heat up to reflux, add dropwise 16 parts of styrene, 5 parts of i...

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Abstract

The invention discloses a water-soluble polyurethane modified acrylic acid polymer. The structure of the polymer is represented by a general formula I which is shown in the description, wherein each substituent group in the formula is defined as the description. The water-soluble polyurethane modified acrylic acid polymer is used for preparing coatings.

Description

technical field [0001] The invention belongs to the technical field of coatings, and in particular relates to a water-soluble polyurethane-modified acrylic acid polymer, a preparation method and its application in water-based wine bottle coatings with high ethanol resistance. Background technique [0002] On January 26, 2015, the Ministry of Finance and the State Administration of Taxation jointly issued the "Notice on Levying Consumption Tax on Coatings": In order to promote energy conservation and environmental protection, with the approval of the State Council, the consumption tax on coatings will be levied on February 1, 2015. , entrusted processing and import links, the applicable tax rate is 4%. At the same time, it is stated that the consumption tax will be exempted for coatings with a volatile organic compound (VOC) content of less than 420 grams per liter (inclusive) in the construction state. It is expected that in the next few years, while the output of coatings ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/62C08F220/20C08F212/08C08F220/06C08F220/14C09D175/04C09D161/20
CPCC08F212/08C08F220/20C08G18/6229C08L2205/025C08L2205/03C09D175/04C08L61/20C08F220/06C08F220/1811
Inventor 施珠容张杰唐晓冬缪青裴江伟
Owner NIPPON PAINT IND COATINGS SHANGHAI
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