Formula and production method of halogen-free antimony-free flame-retardant high-temperature-resistant heat-shrink pipe material

A high-temperature-resistant technology, applied in the field of halogen-free antimony-free flame-retardant high-temperature heat-shrinkable tubes and its production, to achieve excellent environmental performance, excellent high-temperature resistance, and excellent flame-retardant effects

Inactive Publication Date: 2018-02-02
SHENZHEN WOER HEAT SHRINKABLE MATERIAL +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Aiming at the existing problems, the present invention provides a halogen-free, antimony-

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0036] Example 1

[0037] 20 parts of metallocene catalyzed ultra-low density polyethylene, 60 parts of ethylene-methacrylate copolymer (methacrylate content of 13%), 20 parts of ethylene-vinyl acetate copolymer (vinyl acetate content of 18%) ), 50 parts of potassium aluminum silicate, 18 parts of microencapsulated red phosphorus, 45 parts of halogen-free composite flame retardant (including 20 parts of magnesium hydroxide, 25 parts of melamine cyanurate (MCA)), 1.2 parts of N'N - Ethylene bis-stearamide (EBS), 2.5 parts silicone, 1.2 parts trimethylolpropane trimethacrylate (TMPTMA), 4.6 parts complex antioxidant (including 2 parts antioxidant 1010 (tetra[beta]) -(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid]pentaerythritol ester), 1 part antioxidant KY-405 (4'4-bis(α,α-dimethylbenzyl)di Aniline), 0.8 part of antioxidant DSTP (distearyl thiodipropionate), 0.8 part of anti-metal ion agent MD-1024) were sequentially put into a two-roll mixer for mixing for 5-10 minutes, an...

Example Embodiment

[0040] Example 2

[0041]35 parts of metallocene catalyzed ultra-low density polyethylene, 35 parts of ethylene-methacrylate copolymer (methacrylate content of 13%), 30 parts of ethylene-vinyl acetate copolymer (vinyl acetate content of 26%) ), 45 parts of potassium aluminum silicate, 20 parts of microencapsulated red phosphorus, 50 parts of halogen-free composite flame retardant (including 30 parts of magnesium hydroxide, 20 parts of melamine cyanurate (MCA)), 1.2 parts of N'N - Ethylene bis-stearamide (EBS), 2.5 parts silicone, 1.2 parts trimethylolpropane trimethacrylate (TMPTMA), 5.6 parts complex antioxidants (including 3 parts antioxidant CPL (p-cresol) and dicyclopentadiene butylated product), 1.5 parts antioxidant KY-405 (4'4-bis(α,α-dimethylbenzyl) diphenylamine), 0.5 part antioxidant DSTP (thiodiphenylamine) Distearyl propionate) and 0.6 part of anti-metal ion agent MD-1024) were sequentially put into a twin-roll mixer and mixed for 5-10 minutes. Extrusion, drawing...

Example Embodiment

[0044] Example 3

[0045] 30 parts of high-density polyethylene, 50 parts of ethylene-methacrylate copolymer (25% methacrylate content), 20 parts of ethylene-vinyl acetate copolymer (18% vinyl acetate content), 50 parts Potassium aluminum silicate, 15 parts microencapsulated red phosphorus, 55 parts halogen-free composite flame retardant (including 35 parts aluminum hydroxide, 20 parts melamine cyanurate (MCA)), 1.5 parts zinc stearate, 3.0 parts Silicone, 1.5 parts triallyl isocyanurate (TAIC), 6.1 parts complex antioxidant (including 2.5 parts antioxidant 1010 (tetra[beta-(3,5-di-tert-butyl-4-hydroxyl) phenyl) propionic acid] pentaerythritol ester), 1.8 parts of antioxidant hindered amine 622, 1.0 part of antioxidant 300 (4'4 thiobis(6-tert-butyl-3-methylphenol)), 0.8 part of antioxidant The metal ion agent MD-1024) is put into the twin-roll mixer in turn and mixed for 5~10 minutes, and then the mixture is force-fed and extruded with a twin-screw extruder in the temperature...

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Abstract

The invention discloses a formula and a production method of a halogen-free antimony-free flame-retardant high-temperature-resistant heat-shrink pipe material. The formula comprises the following components in parts by weight: 10 to 50 parts of polyethylene, 30 to 60 parts of ethylene-methacrylate copolymer, 10 to 35 parts of ethylene-vinyl acetate copolymer, 30 to 80 parts of lithium aluminium silicate, 10 to 30 parts of microencapsulated red phosphorus, 35 to 90 parts of halogen-free composite flame retardant, 0.5 to 2 parts of lubricating agent, 2 to 4 parts of silicone, 0.5 to 1.5 parts ofsensitized crosslinking agent and 3.5 to 6.5 parts of composite antioxidant. The halogen-free antimony-free flame-retardant high-temperature-resistant heat-shrink pipe material has excellent environmental friendliness which can accord with Japan SONY-SS-00259 standard, European Union REACH laws and regulations and RoHS 2.0(2011/65/EU) instruction, and does not contain any halogen such as bromineand chlorine and antimony flame retardants.

Description

technical field [0001] The invention relates to the technical field of heat-shrinkable tube materials, in particular to a halogen-free, antimony-free, flame-retardant, high-temperature-resistant heat-shrinkable tube and a production method thereof. Background technique [0002] Heat shrinkable sleeves are generally used in the connection between various wires and cables, as well as the connection of cable terminals, to identify or protect wires and cables. With the rapid development of the automobile industry, domestic aircraft development projects, high-speed rail transit industry, and the needs of military equipment development, some spare parts and wires and cables required for these equipment need to be used at higher temperatures for a long time, which requires cooperation with The matching heat-shrinkable tubing has good flame retardancy and high temperature resistance; while most of the high-temperature resistant heat-shrinkable tubing currently used is a halogen-cont...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08L83/04C08L23/06C08K13/02C08K3/34C08K3/02C08K3/22C08K5/20C08K5/134C08J7/12C08J3/22
Inventor 魏立东何立乾王宇源冯雪雁康树峰
Owner SHENZHEN WOER HEAT SHRINKABLE MATERIAL
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