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A liquid injection process for polymer soft pack lithium ion battery

A technology of lithium-ion batteries and polymers, applied in secondary batteries, battery pack components, secondary battery manufacturing, etc., can solve the problems of lithium batteries that are difficult to survive, have high environmental requirements, and pollute the environment, and achieve improved production efficiency , Improve the effect of injection efficiency

Active Publication Date: 2020-12-25
ANHUI LIBA POWER LITHIUM BATTERY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional glove box injection method has many disadvantages: 1. Even if a dehumidification system is used for dehumidification, the moisture in the glove box is still above 500ppm, while high-quality lithium batteries require moisture to be controlled at about 10ppm, which is very different, so it is difficult to Preserve high-quality lithium batteries; 2. The dehumidification operation of the glove box consumes a lot of energy and has high environmental requirements for the entire workshop, resulting in high cost of lithium battery injection operations; 3. When performing liquid injection operations in the glove box , the electrolyte is easy to volatilize and is discharged into the air by the return air system to pollute the environment; 4. When injecting liquid in the glove box, the operator has to insert his hands in latex long-arm gloves for a long time, which is easy to cause if the time is too long It causes skin sweating and eczema, etc., and it is extremely inconvenient to wear latex long-arm gloves for liquid injection, which seriously affects the production capacity of the lithium battery liquid injection process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A liquid injection process for a polymer soft-pack lithium-ion battery, comprising the following steps:

[0026] (1) Seal the top and side of the soft-packed battery, then put the soft-packed battery into a vacuum drying oven, control the temperature at 80°C, and vacuum at -0.97Mpa, and dry for 1.5h;

[0027] (2) Seal the side of the air bag of the soft-packed battery cell taken out of the drying box, then use a puncture needle to penetrate the air bag, and use a high-precision numerical control ceramic liquid injection pump to pump electrolyte into the battery cell, and inject the liquid The amount is 110% of the total amount of electrolyte, seal the injection hole with adhesive tape or clips, and let it stand for 35 minutes;

[0028] (3) Use two glass plates to sandwich the soft-packed battery, and then perform formation on the soft-packed battery. The formation process is: charge at a constant current of 0.02C for 60 minutes, then charge at a constant current of 0.05...

Embodiment 2

[0032] A liquid injection process for a polymer soft-pack lithium-ion battery, comprising the following steps:

[0033] (1) Seal the top and side of the soft-packed battery, then put the soft-packed battery into a vacuum drying oven, control the temperature at 70°C, and vacuum at -0.95Mpa, and dry for 2 hours;

[0034] (2) Seal the side of the air bag of the soft-packed battery cell taken out of the drying box, then use a puncture needle to penetrate the air bag, and use a high-precision numerical control ceramic liquid injection pump to pump electrolyte into the battery cell, and inject the liquid The amount is 105% of the total amount of electrolyte, seal the injection hole with adhesive tape or clips, and let it stand for 40 minutes;

[0035] (3) Use two glass plates to clamp the soft-packed battery, and then perform formation on the soft-packed battery. The formation process is: charge at a constant current of 0.02C for 80 minutes, and then charge at a constant current of ...

Embodiment 3

[0039] A liquid injection process for a polymer soft-pack lithium-ion battery, comprising the following steps:

[0040] (1) Seal the top and side of the soft-packed battery, then put the soft-packed battery into a vacuum drying oven, control the temperature at 90°C, and vacuum at -0.98Mpa, and dry for 1h;

[0041] (2) Seal the side of the air bag of the soft-packed battery cell taken out of the drying box, then use a puncture needle to penetrate the air bag, and use a high-precision numerical control ceramic liquid injection pump to pump electrolyte into the battery cell, and inject the liquid The amount is 120% of the total amount of electrolyte, seal the injection hole with adhesive tape or clips, and let it stand for 30 minutes;

[0042](3) Use two glass plates to sandwich the soft-packed battery, and then perform formation on the soft-packed battery. The process of the formation is: charge at a constant current of 0.03C for 100min, then charge at a constant current of 0.08...

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PUM

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Abstract

The invention relates to the field of lithium-ion batteries, in particular to a liquid injection process for polymer soft-pack lithium-ion batteries, comprising the following steps: (1) sealing the top and side of the soft-pack batteries, and putting them into a drying box to dry 1 to 2 hours; (2) Seal the side of the air bag of the soft battery cell taken out of the drying box, and then use a puncture needle to penetrate the air bag and inject electrolyte into the cell. The amount of liquid injected is the total amount of electrolyte 105-120% of the liquid injection hole, seal the liquid injection hole with tape or clips, and let it stand for 30-40 minutes; (3) perform formation on the soft-packed battery; (4) remove the tape or clip from the liquid injection hole after the formation is completed , vacuum through the liquid injection hole, and then perform two seals on the soft-packed battery; (5) remove the air bag to complete the liquid injection; the liquid injection process adopted in the present invention can be completed completely in the workshop environment, without the need for a glove box It significantly improves the liquid injection efficiency of the soft-packed battery cell and increases the production capacity; at the same time, it ensures the liquid injection volume of the battery and avoids the pollution of the ambient air caused by the volatilization and leakage of the electrolyte.

Description

technical field [0001] The invention relates to the field of lithium-ion batteries, in particular to a liquid injection process for polymer soft-pack lithium-ion batteries. Background technique [0002] Lithium-ion battery electrolyte is an organic liquid, including the inorganic salt LiPF 6 And some additives, such as: PC (propylene carbonate), EC (ethylene carbonate), DMC (dimethyl carbonate), DEC (diethyl carbonate), EMC (methyl ethyl carbonate), etc., these substances are mixed as The electrolyte of lithium-ion batteries is used to transport lithium ions to realize intercalation and deintercalation of electrons, due to LiPF 6 When encountering water, a chemical reaction will occur and HF (hydrofluoric acid) will be generated. HF (hydrofluoric acid) will destroy the SEI film, causing secondary film formation, resulting in deterioration of the performance of the lithium battery, such as lithium analysis, lithium battery charging and discharging. When water is electrolyze...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M2/36H01M10/058H01M10/44H01M50/60
CPCH01M10/04H01M10/058H01M10/446H01M50/60Y02E60/10Y02P70/50
Inventor 李学智李明
Owner ANHUI LIBA POWER LITHIUM BATTERY TECH
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