Preparation method of vulcanized glyceryl trioleate and stainless steel tube drawing oil containing vulcanized glyceryl trioleate

A technology of triolein and stainless steel pipes, which is applied in the preparation of organic compounds, carboxylic acid esters, hydrogenated polysulfides/polysulfides, etc., can solve the problem of low surface quality of workpieces, high temperature, and mold High temperature and other problems, to achieve the effect of improving anti-wear and anti-rust performance

Inactive Publication Date: 2018-03-23
SHANDONG YUANGEN PETROLEUM CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In production practice, the drawing process of stainless steel is the most common processing method. Stainless steel is a material that is difficult to process. Compared with ordinary carbon steel, its relative cutting performance ratio is between 0.4-0.6. The toughness of stainless steel is Large, high thermal intensity, low thermal conductivity, serious work hardening, difficult heat dissipation and many other factors, resulting in high mold temperature, severe mold wear, easy to draw, rough or break the workpiece, short mold life and low surface quality of the processed workpiece, etc. Phenomenon
The drawing process is a process with a relatively large amount of deformation, which generates a lot of heat, generally has a large oil viscosity, slow cooling speed, and is prone to high temperatures, which is more difficult than other processes. After analyzing the drawing and breaking problems, it is found that the following factors play a major role: first, the problem of lubrication, the drawing processing temperature is high, and the high temperature lubricity is not good; second, the extreme pressure performance is insufficient, and the local temperature is high during drawing processing , requires extreme pressure antiwear agent with good performance at high temperature

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Embodiment 1 (preparation of sulfurized glycerol trioleate)

[0021] The first step: the synthesis of glycerol trioleate, first add an appropriate amount of glycerin into a 250ml four-necked flask, gradually raise the temperature to 100°C, then add an appropriate amount of oleic acid in batches, fill with N 2 As a protective gas, toluene is used as water-carrying agent, toluenesulfonic acid is used as catalyst, stirring is started, and then the temperature is gradually raised to 130°C, and the reaction is carried out at this temperature for 7 hours, and the heating is stopped when no more water evaporates. After cooling and discharging, a light yellow oily triglyceride liquid was obtained.

[0022] The second step: the synthesis of sulfurized glycerol trioleate, dissolve the weighed sulfur in an appropriate amount of toluene, then add the glycerol trioleate obtained in the first step in a 250ml four-necked flask, start stirring, and fill with N 2 As a protective gas, ...

Embodiment 2

[0023] Example 2 (stainless steel pipe pulling oil containing sulfurized trioleate)

[0024] At room temperature, mix 24.8 parts of 500N base oil and 35 parts of 150BS base oil, turn on the stirring, heat with heat conduction oil, control the temperature at about 50°C, add 10 parts of high alkali value calcium sulfonate, stir for 20 minutes; then add 15 parts The sulfurized glycerol trioleate obtained in Example 1, 10 parts of dialkyl pentasulfide, 5 parts of dialkyl ammonium thiophosphate, 0.2 part of antioxidant; That is, the stainless steel pipe pulling oil product is obtained.

Embodiment 3

[0026] At room temperature, mix 24.8 parts of 500N base oil and 35 parts of 150BS base oil, turn on the stirring, heat with heat transfer oil, control the temperature at about 50°C, add 5 parts of high alkali value calcium sulfonate, stir for 20 minutes; then add 20 parts The sulfurized glycerol trioleate obtained in Example 1, 15 parts of dialkyl pentasulfides, 5 parts of dialkyl ammonium thiophosphate, and 0.2 part of antioxidant; That is, the stainless steel pipe pulling oil product is obtained.

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Abstract

The invention belongs to the field of metal processing production of lubricating oil, and particularly relates to a preparation method of vulcanized glyceryl trioleate and stainless steel tube drawingoil containing the vulcanized glyceryl trioleate. The vulcanized glyceryl trioleate prepared by the invention has excellent abrasion resistance and excellent extreme pressure property, and the requirements on abrasion resistance and extreme pressure property of the drawing oil can be met at the same time; the anti-abrasion stainless steel tube drawing oil is prepared by mixing diakyl pentasulfide, vulcanized triglyceride, calcium alkylbenzene sulfonate with high base number, dialkyl ammonium dithiophosphate, a phenolic antioxidant and an amine antioxidant, has excellent properties and characteristics of abrasion resistance, extreme pressure resistance, good lubricity, die protection and the like, and has a very good promotion and application value.

Description

technical field [0001] The invention belongs to the field of lubricating oil metal processing production, and in particular relates to a preparation method of sulfurized triglyceride oleate and stainless steel pipe pulling oil containing the compound. Background technique [0002] Stainless steel has high tensile strength, yield strength, elongation and impact value in terms of mechanical properties, and its high temperature strength and hardness are also high. In addition, stainless steel also has high corrosion resistance and high temperature resistance. Therefore, it is widely used in machinery, petrochemical, electronic instrumentation, national defense and other industrial sectors. [0003] Drawing processing is one of the most important forms of forming processing, accounting for more than 50% of the total forming process. In production practice, the drawing process of stainless steel is the most common processing method. Stainless steel is a material that is difficul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C323/52C07C319/24C07C67/08C07C69/58C10M135/06C10M169/04C10N30/06C10N30/12C10N40/24
CPCC07C67/08C07C319/24C10M135/06C10M169/045C10M2203/1025C10M2219/024C10M2219/046C10M2219/082C10M2223/063C10N2030/06C10N2030/12C10N2040/24C10N2040/247C07C69/58C07C323/52C10N2010/04C10N2020/02
Inventor 孙建强袁俊洲乔良宋来功纪祥娟
Owner SHANDONG YUANGEN PETROLEUM CHEM
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